Citation: Jie-Ni XING, Min SHU, Wen-Yuan WANG, Rui ZHANG, Jian LIU. Synthesis and Properties of Electrochromic Material Based on Phenanthroline Fe(Ⅱ) Complex with Triphenylamine Moiety[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1847-1852. doi: 10.11862/CJIC.2021.212 shu

Synthesis and Properties of Electrochromic Material Based on Phenanthroline Fe(Ⅱ) Complex with Triphenylamine Moiety

Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Key Laboratory of Biomass Energy and Materials, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: Rui ZHANG, liu.jian@njfu.edu.cn Jian LIU, zhangrui@njfu.edu.cn
Received Date: 9 June 2021
Revised Date: 22 July 2021

Figures(6)

A Fe(Ⅱ) complex[Fe(TPAPhen)₃](BF₄)₂ was prepared by coordination reaction between Fe²⁺ ion and the ligand N-(4-(1-methyl-1H-imidazo[4, 5-f] [1,10]phenanthrolin-2-yl)phenyl)-N-phenylbenzenamine (TPAPhen), which was synthesized from the starting materials including 4-(diphenylamino)benzaldehyde and 1, 10-phenanthroline-5, 6- dione through condensation reaction and methylation. Then the electrochromic material poly-Fe(TPAPhen)₃ was deposited on the ITO glass by electropolymerization of[Fe(TPAPhen)₃](BF₄)₂. Poly-Fe(TPAPhen)₃ exhibited multicolor change and good electrochromic performance under external voltage. Especially, a high optical contrast of 86% was achieved at 721 nm with a fast switch speed (coloration time: 2.6 s, bleaching time: 5.3 s) and high coloration efficiency of 971 cm²·C^-1.
- Fe(Ⅱ) complex,
- electrochromic materials,
- triphenylamine,
- phenanthroline
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