Citation: Hai-Zhi LIU, Zhi-Hao KONG, Xiao-Yan LIN, Peng-Dong LIU, Fa-Hai DONG, Zhen WANG, Guang-Wu WEN. Effect of La, Ce, Yb Doping on Properties of LiNi_0.5Mn_1.5O₄ High Voltage Cathode Materials[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1782-1792. doi: 10.11862/CJIC.2021.210 shu

Effect of La, Ce, Yb Doping on Properties of LiNi_0.5Mn_1.5O₄ High Voltage Cathode Materials

Hai-Zhi LIU ¹ ,
Zhi-Hao KONG ¹ ,
Xiao-Yan LIN ¹ ,
Peng-Dong LIU ¹ ,
Fa-Hai DONG ¹ ,
Zhen WANG ^{2, 3} ,
Guang-Wu WEN ^{1, 2, 3,,}

1.
School of Materials Science and Engineering, Shandong University of Technology, Zibo, Shandong 255000, China
2.
Shandong Si-Nano Materials Technology Co. Ltd., Zibo, Shandong 255000, China
3.
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: Guang-Wu WEN, g_wen2016@163.com
Received Date: 1 April 2021
Revised Date: 28 July 2021

Figures(8)

High-voltage LiNi_0.5Mn_1.5O₄ cathode materials doped with different rare earth elements were prepared by low temperature combustion method. The effects of different doping ratios (molar ratios of 0.5%, 1%, 2%) and different kinds of rare earth elements (La, Ce, Yb) on the material performance were investigated, and the influence mechanism was explored by X-ray diffraction, Raman spectrum, electron paramagnetic resonance and galvanostatic intermittent titration technique. X-ray diffraction pattern illustrates that rare earth doping can inhibit the generation of Li_xNi_1-xO phase. The inductively coupled plasma spectroscopy illustrates that the doped rare earth elements are basically in accordance with the design proportion. Raman spectrum illustrates that rare earth elements can increase the ordered phase of the material and Ce doped sample has the most ordered phase. In combination with electron paramagnetic resonance oxygen vacancy test, it is found that Ce doped sample induces the increase of the proportion of ordered phase in the material, thus improving the stability of the material. Galvanostatic intermittent titration technique test showed that the diffusion coefficient of Ce-doped LiNi_0.5Mn_1.5O₄ material was about 15 times higher than the undoped sample. In different doping proportion, the material with 1% doping amount had the best performance. Among the samples doping with the best amount of three rare earth elements, Ce doped samples had the best doping performance, and the specific discharge capacity of the first discharge can reach 133.3 mAh·g^-1, which was higher than the undoped group and the first discharge efficiency was increased by 18%. After 200 cycles at 1C, the capacity retention rate was 102%, which was 8% higher than the undoped group.
- LiNi_0.5Mn_1.5O₄,
- low temperature combustion method,
- ordered/disordered regulation,
- oxygen vacancy
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of La, Ce, Yb Doping on Properties of LiNi0.5Mn1.5O4 High Voltage Cathode Materials

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通讯作者: 陈斌, bchen63@163.com

Effect of La, Ce, Yb Doping on Properties of LiNi_0.5Mn_1.5O₄ High Voltage Cathode Materials