Citation: Jin-Wei CHEN, Ying-Fen ZHUANG, Xun-Zhong ZOU, An-Sheng FENG, Yan-Lai ZHANG, Yu LI. Synthesis, Structures and Catalytic Activity in Knoevenagel Condensation Reaction of Cu(Ⅱ)/Co(Ⅱ)/Ni(Ⅱ) Coordination Polymers Based on Ether-Bridged Tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1900-1910. doi: 10.11862/CJIC.2021.208 shu

Synthesis, Structures and Catalytic Activity in Knoevenagel Condensation Reaction of Cu(Ⅱ)/Co(Ⅱ)/Ni(Ⅱ) Coordination Polymers Based on Ether-Bridged Tetracarboxylic Acid

Jin-Wei CHEN ^{1, 2, #} ,
Ying-Fen ZHUANG ^{2, #} ,
Xun-Zhong ZOU ² ,
An-Sheng FENG ² ,
Yan-Lai ZHANG ² ,
Yu LI ^2,,

1.
Fujian Provincial Key Laboratory of Advanced Materials Processing and Application, Fujian University of Technology, Fuzhou 350118, China
2.
School of Light Chemical Engineering/Guangdong Research Center for Special Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: Yu LI, liyuletter@163.com

Received Date: 1 June 2021
Revised Date: 26 June 2021

Figures(10)

Three Cu(Ⅱ)/Co(Ⅱ)/Ni(Ⅱ) coordination polymers, namely {[Cu₂(μ₅-deta)(2, 2'-bipy)₂]·2H₂O}_n (1), [Co₂(μ₄-deta)(2, 2'-bipy)₂(H₂O)₃]_n(2) and {[Ni₂(μ₃-deta)(μ-4, 4'-bipy)_2.5(H₂O)₅]·3H₂O}_n (3), have been constructed hydrothermally using H₄deta (2, 3', 4, 4'-diphenyl ether tetracarboxylic acid), 2, 2'-bipy (2, 2'-bipyridine)/4, 4'-bipy (4, 4'-bipyridine) and CuCl₂·2H₂O, CoCl₂·6H₂O, NiCl₂·6H₂O, respectively, at 160℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses reveal that the three compounds crystallize in the triclinic or monoclinic systems, space groups P1 or P2₁/n. Compound 1 discloses a 2D sheet. Compound 2 features a 1D chain structure. Compound 3 shows a 3D framework. The catalytic activity in the Knoevenagel condensation reaction of these compounds were investigated. Compound 1 exhibited an excellent catalytic activity in the Knoevenagel condensation reaction at room temperature.
- coordination polymer,
- tetracarboxylic acid,
- catalytic properties,
- Knoevenagel condensation reaction
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