Citation: Jian-Yin ZHANG, Hao-Hao LIU, Xiao-Xiao SHI. Preparation of Li₂Ni₂(MoO₄)₃@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1862-1870. doi: 10.11862/CJIC.2021.205 shu

Preparation of Li₂Ni₂(MoO₄)₃@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency

Jian-Yin ZHANG ^{1, 2,,} ,
Hao-Hao LIU ^{1, 2} ,
Xiao-Xiao SHI ^{1, 2}

1.
Modern College of Humanities and Sciences, Shanxi Normal University, Linfen, Shanxi 041000, China
2.
School of Chemical and Material Science, Shanxi Normal University, Linfen, Shanxi 041004, China

Corresponding author: Jian-Yin ZHANG, jyzhang@sxnu.edu.cn
Received Date: 12 March 2021
Revised Date: 8 August 2021

Figures(7)

Herein, Li₂Ni₂(MoO₄)₃@C composite with mass ratio of 23.7% of carbon was prepared using conventional solid-state method combined with mechanical ball milling and first investigated as the new anode of lithium-ion batteries. Compared with pure Li₂Ni₂(MoO₄)₃, Li₂Ni₂(MoO₄)₃@C presented an outstanding electrochemical performance, where a high reversible capacity of 845 mAh·g^-1 can be acquired at a current density of 200 mA·g^-1 after 50 cycles. It's worth noting that Li₂Ni₂(MoO₄)₃@C delivered high initial coulombic efficiency of 85%. Moreover, the lithium intercalation/de-intercalation behavior of Li₂Ni₂(MoO₄)₃@C was preliminarily investigated by cyclic voltammetry.
- Li₂Ni₂(MoO₄)₃,
- solid state synthesis,
- anode material,
- lithium-ion batteries,
- high initial coulombic efficiency
1. [1]
  Lin X T, Qian S S, Yu H X, Yan L, Li P, Wu Y Y, Long N B, Shui M, Shu J. ACS Sustainable Chem. Eng., 2016,4(9):4859-4867 doi: 10.1021/acssuschemeng.6b01137
2. [2]
  Zhang Q B, Chen H X, Luo L L, Zhao B T, Luo H, Han X, Wang J W, Wang C M, Yang Y, Zhu T, Liu M L. Energy Environ. Sci., 2018,11:669-681 doi: 10.1039/C8EE00239H
3. [3]
  Tian F H, Cheng Y Q, Zhang Y J, Zhao Q Z, Shi Q, Zhang Y, Zhou C, Yang S, Song X P. Mater. Lett., 2021,284:129019 doi: 10.1016/j.matlet.2020.129019
4. [4]
  Zhang J Y, Li R L, Chen Q, Zhao G H, Jia J F. Mater. Lett., 2018,233:302-305 doi: 10.1016/j.matlet.2018.09.032
5. [5]
  Ju Z C, Zhang E, Zhao Y L, Xing Z, Zhuang Q C, Qiang Y H, Qian Y T. Small, 2015,11(36):4753-4761 doi: 10.1002/smll.201501294
6. [6]
  Zhang Y, Zhao G G, Ge P, Wu T J, Li L, Cai P, Liu C, Zou G Q, Hou H S, Ji X B. Inorg. Chem., 2019,58:6410-6421 doi: 10.1021/acs.inorgchem.9b00627
7. [7]
  Guo L, Wang Y. J. Mater. Chem. A, 2015,3:15030-15038 doi: 10.1039/C5TA03256C
8. [8]
  Prabaharan S R S, Ramesh S, Michael M S, Begam K M. Mater. Chem. Phys., 2004,87:318-326 doi: 10.1016/j.matchemphys.2004.05.041
9. [9]
  Mikhailova D, Sarapulova A, Voss A, Thomas A, Oswald S, Gruner W, Trots D M, Bramnik N N, Ehrenberg H. Chem. Mater., 2010,22:3165-3173 doi: 10.1021/cm100213a
10. [10]
  Chen S Y, Duan H, Zhou Z Y, Fan Q H, Zhao Y M, Dong Y Z. J. Power Sources, 2020,476:228656 doi: 10.1016/j.jpowsour.2020.228656
11. [11]
  Wang J X, Zhang G B, Liu Z M, Li H K, Liu Y, Wang Z X, Li X H, Shih K, Mai L Q. Nano Energy, 2018,44:272-278 doi: 10.1016/j.nanoen.2017.11.079
12. [12]
  Prabaharana S R S, Fauzib A, Michael M S, Begam K M. Solid State Ionics, 2004,171:157-165 doi: 10.1016/j.ssi.2004.05.001
13. [13]
  Wakayama H, Mizuno J, Fukushima Y, Nagano K, Fukunaga T, Mizutani U. Carbon, 1999,37:947-952 doi: 10.1016/S0008-6223(98)00249-8
14. [14]
  Eom J, Cho Y, Kim S, Han D, Sohn D. J. Alloys Compd., 2017,723:456-461 doi: 10.1016/j.jallcom.2017.06.210
15. [15]
  Gao H Y, Jiao L F, Peng W X, Liu G, Yang J Q, Zhao Q Q, Qi Z, Si Y C, Wang Y J, Yuan H T. Electrochim. Acta, 2011,56:9961-9967 doi: 10.1016/j.electacta.2011.08.086
16. [16]
  Liu P C, Bian K, Zhu K J, Xu Y, Gao Y F, Luo H J, Lu L, Wang J, Liu J S, Tai G. ACS Appl. Mater. Interfaces, 2017,9:17002-17012 doi: 10.1021/acsami.7b01504
17. [17]
  Wang L, He Y C, Mu Y L, Liu M J, Chen Y F, Zhao Y, Lai X, Bi J, Gao D J. Front. Chem., 2018,6:492 doi: 10.3389/fchem.2018.00492
18. [18]
  Liang H Y, Lin J H, Jia H N, Chen S L, Qi J L, Cao J, Lin T S, Fei W D, Feng J C. J. Power Sources, 2018,378:248-254 doi: 10.1016/j.jpowsour.2017.12.046
19. [19]
  Oh S H, Kim J K, Kang Y C, Cho J S. Nanoscale, 2018,10:18734-18741 doi: 10.1039/C8NR06727A
20. [20]
  Jiang G X, Li L, Xie Z J, Gao B Q. Ceram. Int., 2019, 45:18462-18470 doi: 10.1016/j.ceramint.2019.06.064
21. [21]
  Prabaharan S R S, Michael M S, Ramesh S, Begam K M. J. Electroanal. Chem., 2004,570:107-112 doi: 10.1016/j.jelechem.2004.03.022
22. [22]
  Tan Z, Sun Z H, Wang H H, Guo Q, Su D S. J. Mater. Chem. A, 2013, 1:9462 doi: 10.1039/c3ta10524e
23. [23]
  Li B, Xiao Z J, Zai J T, Chen M, Wang H H, Liu X J, Li G, Qian X F. Mater. Today Energy, 2017,5:299-304 doi: 10.1016/j.mtener.2017.07.006
24. [24]
  Wang F, Fang Z W, Zhang Y. J. Electroanal. Chem., 2016,775:110-115 doi: 10.1016/j.jelechem.2016.05.041
25. [25]
  Liu H, Li C, Cao Q, Wu Y P, Holze R. J. Solid State Electrochem., 2008,12:1017-1020 doi: 10.1007/s10008-007-0480-4
26. [26]
  Amin K, Meng Q H, Ahmad A, Cheng M, Zhang M, Mao L J, Lu K, Wei Z X. Adv. Mater., 2018,30:1703868 doi: 10.1002/adma.201703868
1. [1]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309
2. [2]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
3. [3]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
4. [4]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
5. [5]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
6. [6]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
7. [7]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
8. [8]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
9. [9]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
10. [10]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
11. [11]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
12. [12]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
13. [13]
  Yue Zheng , Tianpeng Huang , Pengxian Han , Jun Ma , Guanglei Cui . Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies. Chinese Journal of Structural Chemistry, 2024, 43(10): 100390-100390. doi: 10.1016/j.cjsc.2024.100390
14. [14]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
15. [15]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
16. [16]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
17. [17]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
18. [18]
  Yang Deng , Yitao Ouyang , Chao Han . Constriction-susceptible makes fast cycling of lithium metal in solid-state batteries: Silicon as an example. Chinese Journal of Structural Chemistry, 2024, 43(7): 100276-100276. doi: 10.1016/j.cjsc.2024.100276
19. [19]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
20. [20]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(602)
HTML views(186)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Li2Ni2(MoO4)3@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Li₂Ni₂(MoO₄)₃@C Composite as High-Performance Anode Material for Lithium-Ion Batteries with High Initial Coulombic Efficiency