Citation: Jun-Jie GONG, Jian-Ming WANG. Photodeposition for Preparing Porous Si@CoO_x Composites as High-Performance Anode Material for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1773-1781. doi: 10.11862/CJIC.2021.199 shu

Photodeposition for Preparing Porous Si@CoO_x Composites as High-Performance Anode Material for Lithium-Ion Batteries

Jun-Jie GONG ,
Jian-Ming WANG ^,

Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: Jian-Ming WANG, wjm@zju.edu.cn
Received Date: 21 March 2021
Revised Date: 12 July 2021

Figures(8)

In this work, micron-sized commercial Si-Al alloy powders were used as raw material to in-situ prepare porous silicon/CoO_x composites by acid etching, photochemical deposition and subsequently reduction process. The effects of different photodeposition times on the morphologies and lithium storage properties of pSi@CoO_x materials were explored. The introduction of CoO_x nanosheets improves the electronic conductivity and structural stability of the composites. Even at the current density of 1 A·g^-1, pSi@CoO_x-5 delivered a specific capacity of 774.2 mAh·g^-1 after 200 cycles.
- Si-Al alloy,
- porous silicon,
- photodeposition,
- CoO_x nanosheet,
- lithium-ion battery
1. [1]
  Feng K, Li M, Liu W W, Kashkooli A G, Xiao X C, Cai M, Chen Z W. Small, 2018, 14(8): 1702737 doi: 10.1002/smll.201702737
2. [2]
  SUN L, XIE J, LIU T, HUANG S C, ZHANG L, CHEN Z D, JIANG R Y, JIN Z. Chinese J. Inorg. Chem. , 2020, 36(3): 393-405
3. [3]
  Wu H, Cui Y. Nano Today, 2012, 7(5): 414-429 doi: 10.1016/j.nantod.2012.08.004
4. [4]
  Mcdowell M T, Lee S W, Nix W D, Cui Y. Adv. Mater. , 2013, 25(36): 4966-4985 doi: 10.1002/adma.201301795
5. [5]
  Zhou M, Cai T, Pu F, Chen H, Wang Z, Zhang H Y, Guan S Y. ACS Appl. Mater. Interfaces, 2013, 5(8): 3449-3455 doi: 10.1021/am400521n
6. [6]
  Lv X S, Wei W, Huang B B, Dai Y. J. Mater. Chem. A, 2019, 7(5): 2165-2171 doi: 10.1039/C8TA10936B
7. [7]
  YANG X B, ZHANG L W. Chinese J. Inorg. Chem. , 2019, 35(3): 537-545
8. [8]
  Jiang J, Li Y Y, Liu J P, Huang X T, Yuan C Z, Lou X W. Adv. Mater. , 2012, 24(38): 5166-5180 doi: 10.1002/adma.201202146
9. [9]
  Yao W L, Dai Q N, Liu Y, Zhang Q, Zhong S W, Yan Z Q. ChemElectroChem, 2017, 4(5): 1236-1242 doi: 10.1002/celc.201700096
10. [10]
  Yao W L, Dai Q N, Chen P, Zhong S W, Yan Z Q. RSC Adv. , 2015, 5 (25): 19145-19151 doi: 10.1039/C4RA17192F
11. [11]
  Wang Z F, Zhang X M, Liu X L, Wang Y C, Zhang Y G, Li Y Y, Zhao W M, Qin C L, Mukanova A, Bakenov Z. J. Power Sources, 2020, 449(2020): 227550
12. [12]
  Zhang J Y, Zhang C Q, Wu S M, Liu Z, Zheng J, Zuo Y H, Xue C L, Li C B, Cheng B W. Nanoscale Res. Lett. , 2016, 11(1): 214 doi: 10.1186/s11671-016-1426-5
13. [13]
  Hwa Y, Kim W S, Yu B C, Hong S H, Sohn H J. J. Phys. Chem. C, 2013, 117(14): 7013-7017 doi: 10.1021/jp401333v
14. [14]
  Zhang L Y, Zhong Y, He Z S, Wang J M, Xu J, Cai J, Zhang N, Zhou H, Fan H Q, Shao H B, Zhang J Q, Cao C N. J. Mater. Chem. A, 2013, 1(13): 4277 doi: 10.1039/c3ta00968h
15. [15]
  Zhu S S, Zhuang P P, Chang L, Zhong Y, Wang K, Shao H B, Wang J M, Zhang J Q, Cao C N. Phys. Chem. Chem. Phys. , 2016, 18(12): 8529-8536 doi: 10.1039/C6CP00372A
16. [16]
  Zhang P P, Zhu S S, He Z S, Wang K, Fan H Q, Zhong Y, Chang L, Shao H B, Wang J M, Zhang J Q, Cao C N. J. Alloys Compd. , 2016, 674(2016): 1-8
17. [17]
  Su X, Wu Q L, Li J C, Xiao X C, Lott A, Lu W Q, Sheldon B W, Wu J. Adv. Energy Mater. , 2014, 4(1): 1300882 doi: 10.1002/aenm.201300882
18. [18]
  An W L, Gao B, Mei S X, Xiang B, Fu J J, Wang L, Zhang Q B, Chu P K, Huo K F. Nat. Commun. , 2019, 10(1): 1447 doi: 10.1038/s41467-019-09510-5
19. [19]
  Cui M, Wang L, Guo X W, Wang E R, Yang Y B, Wu T H, He D, Liu S Q, Yu H J. J. Mater. Chem. A, 2019, 7(8): 3874-3881 doi: 10.1039/C8TA11684A
20. [20]
  Shen S J, Lin Z P, Song K, Wang Z P, Huang L A, Yan L H, Meng F Q, Zhang Q H, Gu L, Zhong W W. Angew. Chem. Int. Ed. , 2021, 60 (2021): 1-7
21. [21]
  Zhong W W, Wang Z P, Gao N, Huang L A, Lin Z P, Liu Y P, Meng F Q, Deng J, Jin S F, Zhang Q H, Gu L. Angew. Chem. Int. Ed. , 2020, 59(50): 22743-22748 doi: 10.1002/anie.202011378
22. [22]
  Fang W Z, Xing M Y, Zhang J L. Appl. Catal. B, 2014, 160-161 (2014): 240-246
23. [23]
  Chen X B, Liu L, Yu P Y, Mao S S. Science, 2011, 331(6018): 746-750 doi: 10.1126/science.1200448
24. [24]
  Guo S C, Hu X, Hou Y, Wen Z H. ACS Appl. Mater. Interfaces, 2017, 9(48): 42084-42092 doi: 10.1021/acsami.7b13035
25. [25]
  Ren W F, Li J T, Zhang S J, Lin A L, Chen Y H, Gao Z G, Zhou Y, Deng L, Huang L, Sun S G. J. Energy Chem. , 2020, 48(2020): 160-168
26. [26]
  Sheng P, Tao S, Gao X R, Tan Y J, Wu D J, Qian B, Chu P K. J. Mater. Sci. , 2020, 55(26): 12091-12102 doi: 10.1007/s10853-020-04819-9
27. [27]
  Xu L, Jiang Q Q, Xiao Z H, Li X Y, Huo J, Wang S Y, Dai L M. Angew. Chem. Int. Ed. , 2016, 55(17): 5277-5281 doi: 10.1002/anie.201600687
28. [28]
  Zhu S S, Huang L A, He Z S, Wang K, Guo J F, Pei S E, Shao H B, Wang J M. J. Electroanal. Chem. , 2018, 827(2018): 42-50
29. [29]
  Zhang T, Wu M Y, Yan D Y, Mao J, Liu H, Hu W B, Du X W, Ling T, Qiao S Z. Nano Energy, 2018, 43(2018): 103-109
30. [30]
  Tao Y, Wei C L, Fei H F, An Y L, Tian Y, Wei H, Xiong S L, Feng J K. J. Power Sources, 2020, 455(2020): 227967
31. [31]
  ZHANG L, WANG J, TANG Y P, GUO Y Z, HUANG R A. Chinese J. Inorg. Chem. , 2020, 36(5): 893-900
32. [32]
  Wang H X, Song H C, Lin Z X, Jiang X F, Zhang X W, Yu L W, Xu J, Pan L J, Wang J Z, Zheng M B, Shi Y, Chen K J. Nanoscale, 2016, 8(5): 2613-2619 doi: 10.1039/C5NR06985H
33. [33]
  Guo J F, Pei S E, He Z S, Huang L A, Lu T Z, Gong J J, Shao H B, Wang J M. Electrochim. Acta, 2020, 348(2020): 136334
34. [34]
  Huang L A, He Z S, Guo J F, Pei S E, Shao H B, Wang J M. ChemElectroChem, 2019, 6(10): 2698-2706 doi: 10.1002/celc.201900445
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
9. [9]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
10. [10]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
11. [11]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
12. [12]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
13. [13]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
14. [14]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
15. [15]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
16. [16]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
17. [17]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
18. [18]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
19. [19]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
20. [20]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1138)
HTML views(260)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Photodeposition for Preparing Porous Si@CoOx Composites as High-Performance Anode Material for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Photodeposition for Preparing Porous Si@CoO_x Composites as High-Performance Anode Material for Lithium-Ion Batteries