Citation: Ming WANG, Yuan-Yuan CAI, Yi YANG, Dian ZHU, Na-Na ZHANG, Mei-Fang WANG, Xiang-Zi LI. Synthesis and Characterization of Ni₂P@CoP₃ Core-Shell Nanospheres for Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1633-1641. doi: 10.11862/CJIC.2021.194 shu

Synthesis and Characterization of Ni₂P@CoP₃ Core-Shell Nanospheres for Supercapacitors

Ming WANG ¹ ,
Yuan-Yuan CAI ¹ ,
Yi YANG ¹ ,
Dian ZHU ¹ ,
Na-Na ZHANG ¹ ,
Mei-Fang WANG ^{1, 2,,} ,
Xiang-Zi LI ^{1, 2,,}

1.
Institute of Synthesis and Application of Medical Materials, College of Pharmacy, Wannan Medical College, Wuhu, Anhui 241000, China
2.
Anhui Laboratory of Molecule-Based Materials, Anhui Normal University, Key Laboratory of Functional Molecular Solids, The Ministry of Education, Wuhu, Anhui 241000, China

Corresponding author: Mei-Fang WANG, zijingyuwinter@163.com Xiang-Zi LI, li-xiang-zi@163.com
Received Date: 16 March 2021
Revised Date: 15 July 2021

Figures(6)

Ni nanospheres and Ni@Co(OH)₂ nano-urchin-spheres precursor were successively fabricated with hydrothermal technique, and then the latter were changed into NiO@CoO by high temperature calcination process, and Ni₂P@CoP₃ core-shell nanospheres were finally obtained using sodium hypophoshpite as raw material by high temperature phosphating process. The morphologies, structures and compositions of the as-obtained products were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), high angle annular dark field-scanning transmission electron microscope (HAADF-STEM), X-ray powder diffractometer (XRD), energy dispersive spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). At the same time, the electrochemical performance of the electrodes were investigated by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and cycling stability experiments. The results showed that as-obtained Ni₂P@CoP₃ core-shell nanospheres with diameter of~400 nm were composed of hexagonal Ni₂P nanocore and cubic CoP₃ nanoshell. Compared with pure Ni₂P or CoP₃ nanospheres, Ni₂P@CoP₃ core-shell nanospheres are more conducive to the mass transfer of electrolyte and promote the pseudo capacitive reaction because of its synergistic effect of composite structure, which shows higher specific capacity, stability and longer cycle life.
- Ni₂P@CoP₃ nanospheres,
- hydrothermal technique,
- core-shell structure,
- supercapacitor
1. [1]
  Pandolfo A G, Hollenkamp A F. J. Power Sources, 2006, 157: 11-27 doi: 10.1016/j.jpowsour.2006.02.065
2. [2]
  Hourdakis E, Nassiopoulou A G. Phys. Status Solidi A, 2020, 217: 1900950 doi: 10.1002/pssa.201900950
3. [3]
  Simon P, Gogotsi Y. Nature Mater., 2008, 7: 845-854 doi: 10.1038/nmat2297
4. [4]
  Yao C G, Ni Y H. Chem. Eng. J., 2018, 348: 370-379 doi: 10.1016/j.cej.2018.05.005
5. [5]
  Conway B E, Birss V, Wojtowicz J. J. Power Sources, 1997, 66: 1-14 doi: 10.1016/S0378-7753(96)02474-3
6. [6]
  Kuo C W, Chang J C, Wu B W, Wu T Y. Int. J. Hydrogen Energy, 2020, 45: 22223-22231 doi: 10.1016/j.ijhydene.2019.08.059
7. [7]
  XIN R R, MIAO H J, JIANG W, HU G S. Chinese J. Inorg. Chem., 2019, 35(10): 1781-1790 doi: 10.11862/CJIC.2019.222
8. [8]
  Du Y Q, Xiao P, Yuan J, Chen J W. Coatings, 2020, 10(9): 892 doi: 10.3390/coatings10090892
9. [9]
  Yi F Y, Huang Y L, Gao A M, Zhang F, Shu D, Chen W X, Cheng H H, Zhou X P, Zeng R H. Ionics, 2019, 25: 2393-2399 doi: 10.1007/s11581-018-2698-9
10. [10]
  YANG J L, LIN J X, GUO S Y. Chinese J. Inorg. Chem., 2017, 33(2): 255-261
11. [11]
  Cui D F, Li Y F, Li Y K, Fan Y Y, Chen H M, Xu H Y, Xue C Y. Int. J. Electrochem. Sci., 2020, 15: 2776-2791
12. [12]
  Peng Z Y, Huang J, Wang Y, Yuan K, Tan L C, Chen Y W. J. Mater. Chem. A, 2019, 7: 27313-27322 doi: 10.1039/C9TA10195K
13. [13]
  Yuan C Z, Zhang X G, Hou L R, Shen L F, Li D K, Zhang F, Fan C G, Li J M. J. Mater. Chem., 2010, 20: 10809-10816 doi: 10.1039/c0jm02174a
14. [14]
  Liu L L, Guan T, Fang L, Wu F, Lu Y, Luo H J, Song X F, Zhou M, Hu B S, Wei D P, Shi H F. J. Alloys Compd., 2018, 763: 926-934 doi: 10.1016/j.jallcom.2018.05.358
15. [15]
  Raju T D, Gopalakrishnan A, Badhulika S. J. Alloys Compd., 2020, 845: 156241 doi: 10.1016/j.jallcom.2020.156241
16. [16]
  Ojha G P, Muthurasu A, Tiwari A P, Pant B, Chhetri K, Mukhiya T, Dahal B, Lee M, Park M, Kim H Y. Chem. Eng. J., 2020, 399: 125532 doi: 10.1016/j.cej.2020.125532
17. [17]
  Yang G S, Takei T, Yanagida S, Kumada N. Appl. Surf. Sci., 2019, 498: 143872 doi: 10.1016/j.apsusc.2019.143872
18. [18]
  Wang K B, Li Q Q, Ren Z J, Li C, Chu Y, Wang Z K, Zhang M D, Wu H, Zhang Q C. Small, 2020, 16: 2001987 doi: 10.1002/smll.202001987
19. [19]
  Wang K B, Xun Q, Zhang Q C. EnergyChem, 2020, 2: 100025 doi: 10.1016/j.enchem.2019.100025
20. [20]
  Wang K B, Wang Z K, Liu J D, Li C, Mao F F, Wu H, Zhang Q C. ACS Appl. Mater. Interfaces, 2020, 12: 47482-47489 doi: 10.1021/acsami.0c12830
21. [21]
  Li C, Wang K B, Li J Z, Zhang Q C. ACS Mater. Lett., 2020, 2: 779-797 doi: 10.1021/acsmaterialslett.0c00148
22. [22]
  Liu T, Li P, Yao N, Cheng G Z, Chen S L, Luo W, Yin Y D. Angew. Chem. Int. Ed., 2019, 131: 4727-4732 doi: 10.1002/ange.201901409
23. [23]
  Song C, Zhao W W, Liu H B, Ding W, Zhang L L, Wang J, Yao Y W, Yao C. J. Mater. Chem. B, 2020, 8: 7494-7500 doi: 10.1039/D0TB00215A
24. [24]
  Li Y P, Liu J D, Chen C, Zhang X H, Chen J H. ACS Appl. Mater. Interfaces, 2017, 9: 5982-5991 doi: 10.1021/acsami.6b14127
25. [25]
  Jiao G H, Gu Y, Wang J, Wu D J, Tao S, Chu S Q, Liu Y S, Qian B, Chu W S. J. Mater. Sci., 2019, 54: 3273-3283 doi: 10.1007/s10853-018-3064-z
26. [26]
  Zhang X M, Wu A P, Wang X W, Tian C G, An R Y, Fu H G. J. Mater. Chem. A, 2018, 6: 17905-17914 doi: 10.1039/C8TA05551C
27. [27]
  Hong F, Wang M F, Ni Y H. J. Cluster Sci., 2018, 29: 663-672 doi: 10.1007/s10876-018-1379-1
28. [28]
  Zong Q, Yang H, Wang Q Q, Zhang Q L, Xu J, Zhu Y L, Wang H Y, Wang H, Zhang F, Shen Q H. Dalton Trans., 2018, 47: 16320-16328 doi: 10.1039/C8DT03755H
29. [29]
  Zong Q, Yang H, Wang Q Q, Zhang Q L, Zhu Y L, Wang H Y, Shen Q H. Chem. Eng. J., 2019, 361: 1-11 doi: 10.1016/j.cej.2018.12.041
30. [30]
  Dang T, Wang L, Wei D H, Zhang G Q, Li Q G, Zhang X J, Cao Z Y, Zhang G H, Duan H G. Electrochim. Acta, 2019, 299: 346-356 doi: 10.1016/j.electacta.2018.12.176
31. [31]
  Ning W W, Chen L B, Wei W F, Chen Y J, Zhang X Y. Rare Met., 2020, 39(9): 1034-1044 doi: 10.1007/s12598-020-01374-9
32. [32]
  Xu Y Z, Yuan C Z, Liua Z W, Chen X P. Catal. Sci. Technol., 2018, 8: 128-133 doi: 10.1039/C7CY01606A
33. [33]
  Jiang L, Yan M, Sun L, Liu Y, Bai H Y, Shi W D. Inorg. Chem. Front., 2020, 7: 3030-3038 doi: 10.1039/D0QI00024H
34. [34]
  Li X Z, Wu K L, Ye Y, Wei X W. Nanoscale, 2013, 5: 3648-3653 doi: 10.1039/c3nr00411b
35. [35]
  Li X Z, Wu K L, Ye Y, Wei X W. CrystEngComm, 2014, 16: 4406-4413 doi: 10.1039/C4CE00225C
36. [36]
  Wang K W, She X L, Chen S, Liu H L, Li D H, Wang Y, Zhang H W, Yang D J, Yao X D. J. Mater. Chem. A, 2018, 6: 5560-5565 doi: 10.1039/C7TA10902D
37. [37]
  Yang J, Yang N, Xu Q, Pearlie L S, Zhang Y Z, Hong Y, Wang Q, Wang W J, Yan, Q Y, Dong X C. ACS Sustainable Chem. Eng., 2019, 7: 13217-13225 doi: 10.1021/acssuschemeng.9b02478
38. [38]
  Zhang X Y, Guo B Y, Chen Q W, Dong B, Zhang J Q, Qin J F, Xie J Y, Yang M, Wang L, Chai Y M, Liu C G. Int. J. Hydrogen Energy, 2019, 44: 14908-14917 doi: 10.1016/j.ijhydene.2019.04.108
39. [39]
  Jiang J, Li Z P, He X R, Hu Y L, Li F, Huang P, Wang C. Small, 2020, 16: 2000180 doi: 10.1002/smll.202000180
40. [40]
  Mishra I K, Zhou H Q, Sun J Y, Dahal K, Chen S, Ren Z F. Energy Environ. Sci., 2018, 11: 2246-2252 doi: 10.1039/C8EE01270A
41. [41]
  Song W J, Wu J, Wang G J, Tang S C, Chen G, Cui M J, Meng X K. Adv. Funct. Mater., 2018, 28: 1804620 doi: 10.1002/adfm.201804620
42. [42]
  Yan J, Fan Z J, Sun W, Ning G Q, Wei T, Zhang Q, Zhang R F, Zhi L J, Wei F. Adv. Funct. Mater., 2012, 22(12): 2632-2641 doi: 10.1002/adfm.201102839
43. [43]
  Yin H H, Song C Q, Wang Y, Li S C, Zeng M, Zhang Z L, Zhu Z Q, Yu K. Electrochim. Acta, 2013, 111: 762-770 doi: 10.1016/j.electacta.2013.08.005
44. [44]
  Zou Y J, Cai C L, Xiang C L, Huang P R, Chu H L, She Z, Xu F, Sun L X, Kraatz H B. Electrochim. Acta, 2018, 261: 537-547 doi: 10.1016/j.electacta.2017.12.184
45. [45]
  Jiang H, Ma J, Li C Z. Chem. Commun., 2012, 48(37): 4465-4467 doi: 10.1039/c2cc31418e
46. [46]
  Liu R, Ma L N, Huang S, Mei J, Li E Y, Yuan G H. J. Phys. Chem. C, 2016, 120(50): 28480-28488 doi: 10.1021/acs.jpcc.6b10475
47. [47]
  Lu W, Shen J L, Zhang P, Zhong Y J, Hu Y, Lou X W. Angew. Chem. Int. Ed., 2019, 58(43): 15441-15447 doi: 10.1002/anie.201907516
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Synthesis and Characterization of Ni2P@CoP3 Core-Shell Nanospheres for Supercapacitors

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Synthesis and Characterization of Ni₂P@CoP₃ Core-Shell Nanospheres for Supercapacitors