Citation: Zi-Xi LI, Cong HU, Zhen-Zhou SUN, Xiao-Qi LI, Hong-Liang HAN, Yu-Ping YANG, Xiu-Lan XIN, Qiong-Hua JIN. Syntheses, Spectroscopic Properties and Terahertz Time Domain Spectroscopy of Two Copper(Ⅰ) Complexes Based on Diphosphine Ligands and N-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1504-1512. doi: 10.11862/CJIC.2021.175 shu

Syntheses, Spectroscopic Properties and Terahertz Time Domain Spectroscopy of Two Copper(Ⅰ) Complexes Based on Diphosphine Ligands and N-Donor Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
School of Science, Minzu University of China, Beijing 100081, China
3.
School of Food and Health, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: Qiong-Hua JIN, jinqh@cnu.edu.cn
Received Date: 21 March 2021
Revised Date: 25 June 2021

Figures(12)

Two novel Cu(Ⅰ) complexes, [Cu(dppp) (Bphen)]Cl·1.8CH₃OH (1) and[Cu₂(CN)₂(dppp)(dmp)₂]·2.5CH₃OH(2) (dppp=1, 3-bis(diphenylphosphanyl) propane, Bphen=4, 7-diphenyl-1, 10-diazaphenanthrene, dmp=2, 9-dimethyl-1, 10-phenanthroline), have been synthesized in a mixture of CH₃OH and CH₂Cl₂ and characterized by single-crystal X-ray diffraction, elemental analysis, IR, ¹H NMR and ³¹P NMR spectroscopy, fluorescence spectra and terahertz time-domain spectroscopy (THz-TDS). The single crystal X-ray diffraction shows that complex 1 is a distorted tetrahedral structure with copper as the center, Bphen and dppp as the chelating ligands. Complex 2 is obtained by mixing CuCN, dppp and dmp in a ratio of 2:1:2. The two phosphates of complex 2 form coordination bonds with two Cu(Ⅰ), and each copper coordinates with a cyanogen and a dmp, respectively. The luminescent spectra show that the emission mechanism of complexes 1 and 2 are metal-to-ligand charge transfer (MLCT). The application of THz-TDS also supports to the study of both the complexes.
- copper(Ⅰ) complex,
- diimine,
- diphosphine,
- luminescent spectra,
- terahertz technology
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