Citation: Lu LIU, Mei-Ling CHENG, Li-Zhi-Peng TANG, Zheng LIU, Qi LIU. Mn(Ⅱ)/Ni(Ⅱ) Complexes Based on 5-Methyl-1H-pyrazole-3-carboxylic Acid: Syntheses, Structures, Electrochemical and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1449-1456. doi: 10.11862/CJIC.2021.170 shu

Mn(Ⅱ)/Ni(Ⅱ) Complexes Based on 5-Methyl-1H-pyrazole-3-carboxylic Acid: Syntheses, Structures, Electrochemical and Luminescent Properties

Lu LIU ¹ ,
Mei-Ling CHENG ^1,, ,
Li-Zhi-Peng TANG ¹ ,
Zheng LIU ¹ ,
Qi LIU ^{1, 2}

1.
School of Petrochemical Engineering, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, Jiangsu 213164, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: Mei-Ling CHENG, chengmeiling01@163.com
Received Date: 22 February 2021
Revised Date: 19 May 2021

Figures(4)

In the absence/presence of chelating N ancillary ligand, 2, 2'-bipyridine (2, 2'-bpy), treatment of 5-methyl-1H-pyrazole-3-carboxylic acid (H₂MPCA) with corresponding Mn(Ⅱ)/Ni(Ⅱ) metal salts afforded two complexes, [Mn(HMPCA)₂(H₂O)₂] (1) and[Ni(HMPCA)₂(2, 2'-bpy)]·2H₂O (2). In mononuclear complexes 1 and 2, each metal ion locates in a distorted octahedral geometry, and the HMPCA^-ligands in 1 and 2 both act as a N, O-chelating ligand. In 1, by the function of intermolecular N—H…O and O—H…O hydrogen bonds, the independent[Mn(HMPCA)₂ (H₂O)₂] units are packed into a porous 3D supramolecular structure with 1D nanotube. In 2, the mononuclear components[Ni(HMPCA)₂(2, 2'-bpy)] and the lattice water molecules are interlinked via intermolecular O—H…O and N—H…O hydrogen bonds, generating a 1D chainlike structure, which is linked to adjacent ones through intermolecular π … π interactions forming a 3D supramolecular architecture. The electrochemical and luminescent properties of complexes 1 and 2 have also been investigated.
- 5-methyl-1H-pyrazole-3-carboxylic acid,
- synthesis,
- crystal structure,
- electrochemical property,
- luminescent
1. [1]
  Guo J, Bae J, Fang Z W, Li P P, Zhao F, Yu G H. Chem. Rev. , 2020, 120: 7642-7707 doi: 10.1021/acs.chemrev.0c00345
2. [2]
  Xia D Y, Wang P, Ji X F, Khashab N M, Sessler J L, Huang F H. Chem. Rev. , 2020, 120: 6070-6123 doi: 10.1021/acs.chemrev.9b00839
3. [3]
  Xiu M M, Kang Q, Tao M L, Chen Y, Wang Y. J. Mater. Chem. C, 2018, 6: 5926-5936
4. [4]
  Xue J Y, Li C, Li F L, Gu H W, Braunstein P, Lang J P. Nanoscale, 2020, 12: 4816-4825 doi: 10.1039/C9NR10109H
5. [5]
  Zhang M J, Li H X, Young D J, Li HY, Lang J P. Org. Biomol. Chem. , 2019, 17: 3567-3574 doi: 10.1039/C9OB00418A
6. [6]
  Wang B, Lv X L, Feng D W, Xie L H, Zhang J, Li M, Xie Y B, Li J R, Zhou H C. J. Am. Chem. Soc. , 2019, 138: 6204-6216
7. [7]
  Li J, Chen S, Jiang L Y, Wu D P, Li Y S. Inorg. Chem. , 2019, 58: 5410-5413 doi: 10.1021/acs.inorgchem.9b00550
8. [8]
  Rogge M J, Bavykina A, Hajek J, Garcia H, Olivos-Suarez A I, Sepúlveda-Escribano A, Vimont A, Clet G, Bazin P, Kapteijn F, Da-turi M, Ramos-Fernandez E V, Xamena F X L, Speybroeck V V, Gascon J. Chem. Soc. Rev. , 2017, 46: 3134-3184
9. [9]
  Noh T H, Jung O S. Acc. Chem. Res. , 2016, 49: 1835-1843 doi: 10.1021/acs.accounts.6b00291
10. [10]
  Liu j, Wei Y, Li P, Zhao Y L, Zou R. J. Phys. Chem. C, 2017, 121: 13249-13255 doi: 10.1021/acs.jpcc.7b04465
11. [11]
  Tu B B, Pang Q Q, Ning E, Yan W Q, Qi Y, Wu D F, Li Q W. J. Am. Chem. Soc. , 2015, 137: 13456-13459 doi: 10.1021/jacs.5b07687
12. [12]
  Jacobsen J, Reinsch H, Stock N. Inorg. Chem. , 2018, 57: 12820-12826 doi: 10.1021/acs.inorgchem.8b02019
13. [13]
  Kongpatpanich K, Horike S, Sugimoto M, Fukushima T, Umeyama D, Tsutsumi Y, Kitagawa S. Inorg. Chem. , 2014, 53: 9870-9875 doi: 10.1021/ic501459m
14. [14]
  Cheng M L, Qin M N, Sun L, Liu L, Liu Q, Tang X Y. Dalton. Trans. , 2020, 49: 7758-7765 doi: 10.1039/C9DT04927D
15. [15]
  Liu J, Cheng M L, Yu L L, Chen S C, Shao Y L, Liu Q, Zhai C W, Yin F X. RSC Adv. , 2016, 6: 52040-52047 doi: 10.1039/C6RA10989F
16. [16]
  Cheng M L, Bao J T, Wu Y J, Yang B X, Wang Q H, Sun L, Liu Q. ChemistrySelect, 2018, 3: 4811-4817 doi: 10.1002/slct.201800258
17. [17]
  Chen S, Cheng M L, Ren Y H, Tang Y Z P, Liu X X, Zhai C W, Liu Q. Z. Anorg. Allg. Chem. , 2015, 641: 610-616 doi: 10.1002/zaac.201400484
18. [18]
  Cheng M L, Wang Q H, Bao J T, Wu Y J, Sun L, Yang B X, Liu Q. New J. Chem. , 2017, 41: 5151-5160 doi: 10.1039/C7NJ00835J
19. [19]
  Cheng M L, Sun L, Han W, Wang S, Liu Q, Sun X Q, Xi H T. New J. Chem. , 2016, 40: 10504-10511 doi: 10.1039/C6NJ02338J
20. [20]
  An C X, Lu Y C, Shang Z F, Zhang Z H. Inorg. Chim. Acta, 2008, 361: 2721-2730 doi: 10.1016/j.ica.2008.01.043
21. [21]
  HAN W, CHENG M L, LIU Q, WANG L D, WU Y J. Chinese J. Inorg. Chem. , 2012, 28: 1997-2004
22. [22]
  Hu F L, Yin X H, Mi Y, Zhang J L, Zhuang Y, Dai X Z. Inorg. Chem. Commun. , 2009, 12: 628-631 doi: 10.1016/j.inoche.2009.05.007
23. [23]
  Hu F L, Yin X H, Mi Y, Zhuang Y, Zhang S S, Huang Z J, Wang J. J. Coord. Chem. , 2009, 62: 3613-3620 doi: 10.1080/00958970903156566
24. [24]
  TANG L Z P, YANG M W, CHENG M L, LIU Q. Chinese J. Inorg. Chem. , 2015, 31(3): 603-610
25. [25]
  BAO J T, CHENG M L, LIU Q, HAN W, JI Y Z, ZHAI C W, HONG J, SUN X Q. Chinese J. Inorg. Chem. , 2013, 29(7): 1504-1512
26. [26]
  REN Y Q, HAN W, CHENG M L, YANG Y, LIU Q. Chinese J. Inorg. Chem. , 2014, 30(11): 2635-2644
27. [27]
  ZHAI C W, CHENG M L, HAN W, LIU Q. Chinese J. Inorg. Chem. , 2015, 31(7): 1409-1416
28. [28]
  Cheng M L, Han W, Liu Q, Bao J T, Li Z F, Chen L T, Sun X Q, Xi H T. J. Coord. Chem. , 2014, 67: 215-226 doi: 10.1080/00958972.2013.879983
29. [29]
  Yuan D Y, Wang J, Qian X, Li B L, Li Y. J. Mol. Struct. , 2011, 998: 233-239 doi: 10.1016/j.molstruc.2011.05.038
30. [30]
  Qin S N, Hu J R, Chen Z L, Liang F P. J. Coord. Chem. , 2011, 64: 3718-3728 doi: 10.1080/00958972.2011.630072
31. [31]
  Crane J D, Fox O D, Sinn E. J. Chem. Soc. Dalton. Trans. , 1999, 9: 1461-1466
32. [32]
  Sheldrick G M. SHELXT-2013, University of Göttingen, Germany, 2013.
33. [33]
  Song Y D, Yu L L, Gao Y R, Shi C D, Cheng M L, Wang X M, Liu H J, Liu Q. Inorg. Chem. , 2017, 56: 11603-11609 doi: 10.1021/acs.inorgchem.7b01441
34. [34]
  Cheng M L, Liu L, Sun L, Tao F, Qin M N, Liu Q, Tang X Y. J. Chem. Crystallogr. , 2021, 51: 265-272 doi: 10.1007/s10870-020-00854-1
35. [35]
  Pan Z R, Song Y, Jiao Y, Fang Z J, Li Y Z, Zheng H G. Inorg. Chem. , 2008, 47: 5162-5168 doi: 10.1021/ic702473y
36. [36]
  Zhao J, Wang X L, Shi X, Yang Q H, Li C. Inorg. Chem. , 2011, 50: 3198-3205 doi: 10.1021/ic101112b
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