Citation: Li-Qiong LUO, Cong-Jun WANG, Juan SHEN, Bo JIN, Ru-Fang PENG. Synthesis, Characterization and Thermal Behavior of Lanthanide Metal Complexes Based on 1H, 1'H-5, 5'-Bitetrazole-1, 1'-diolate[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1529-1535. doi: 10.11862/CJIC.2021.168 shu

Synthesis, Characterization and Thermal Behavior of Lanthanide Metal Complexes Based on 1H, 1'H-5, 5'-Bitetrazole-1, 1'-diolate

Li-Qiong LUO ^{1, 2} ,
Cong-Jun WANG ² ,
Juan SHEN ² ,
Bo JIN ^1,, ,
Ru-Fang PENG ¹

1.
State Key Laboratory of Environmental-Friendly Energy Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
2.
School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China

Corresponding author: Bo JIN, jinbo0428@163.com
Received Date: 12 April 2021
Revised Date: 13 May 2021

Figures(4)

Five lanthanide metal complexes, [La₂(BTO)₃(H₂O)₈]·2H₂O (1), [Ce₂(BTO)₃(H₂O)₈]·2H₂O (2), [Pr₂(BTO)₃(H₂O)₈]·2H₂O (3), [Sm₂(BTO)₃(H₂O)₈]·2H₂O (4) and[Nd₂(BTO)₃(DMF)₄]·6H₂O (5), were synthesized by solvothermal method with 1H, 1'H-5, 5'-bitetrazole-1, 1'-diolate (H₂BTO) as ligand and lanthanide metal ions as metal centers. The structures of five complexes were characterized by single crystal X-ray diffraction and elemental analysis. The results show that all the complexes belong to monoclinic system, P2₁/n space group. The thermal stability of complexes 1~4 was investigated by differential scanning calorimetry. And their kinetic parameters of thermal decomposition were calculated by Kissinger method and Ozawa method, respectively.
- energetic materials,
- lanthanide metal complexes,
- 1H, 1'H-5, 5'-bitetrazole-1, 1'-diolate,
- crystal structure,
- thermal analysis
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