Citation: Shuai-Shuai MA, Jian-Dong GU, Yuan GAO, Yu-Qing ZONG, Jin-Juan XUE, Zhao-Lian YE. Preparation and Photocatalytic Activity of Holey Ultrathin g-C₃N₄ Nanosheets-Supported Pt Composite[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1439-1448. doi: 10.11862/CJIC.2021.164 shu

Preparation and Photocatalytic Activity of Holey Ultrathin g-C₃N₄ Nanosheets-Supported Pt Composite

1.
College of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China
2.
School of Environmental and Safety Engineering, Changzhou University, Changzhou, Jiangsu 213164, China

Corresponding author: Shuai-Shuai MA, machem@163.com Jin-Juan XUE, xuechem@163.com Zhao-Lian YE, bess_ye@jsut.edu.cn
Received Date: 23 January 2021
Revised Date: 12 May 2021

Figures(9)

Holey ultrathin g-C₃N₄ nanosheets (CNHS) were prepared by thermal oxidation etching method with melamine as the precursor, and Pt-CNHS photocatalyst was synthesized via a facile in-situ photochemical reduction of CNHS and K₂PtCl₆. The X-ray diffraction, field emission scanning electron microscope, X-ray photoelectron spectroscopy, transmission electron microscope, UV-Vis diffuse reflection spectroscopy and N₂ adsorption-desorption measurements were used to investigate the structure, morphology, optical absorption characteristics, photoelectrochemical properties and specific surface area of the products. The photocatalytic performance of the catalyst was studied by degrading gaseous toluene under UV and visible light. The results show that the introduction of Pt can effectively enhance the visible light absorption capacity, response range and carrier separation efficiency of the catalyst. Compared with bulk g-C₃N₄ (CNB) and CNHS, the Pt-CNHS composite displayed much higher photocatalytic activities in gaseous toluene degradation under UV-and visible-light irradiation. In addition, a preliminary study was made on the reaction process of Pt-CNHS photocatalyst to degrade gaseous toluene under visible light.
- g-C₃N₄,
- supported catalysts,
- photocatalysis,
- degradation,
- toluene
1. [1]
  Hsu C Y, Chiang H C, Shie R H, Ku C H, Lin T Y, Chen M J, Chen Y C. Environ. Pollut. , 2018, 240: 95-104 doi: 10.1016/j.envpol.2018.04.076
2. [2]
  Li X Y, Li J N, Shi Y, Zhang M M, Fan S Y, Yin Z F, Qin M C, Lian T T, Li X Y. J. Colloid Interface Sci. , 2018, 528: 45-52 doi: 10.1016/j.jcis.2018.05.067
3. [3]
  He X, Chen D R, Wang W N. Chem. Eng. J. , 2020, 382: 122825 doi: 10.1016/j.cej.2019.122825
4. [4]
  Guo Y L, Yang D P, Liu M H, Zhang X Y, Chen Y S, Huang J L, Li Q B, Luque R. J. Mater. Chem. A, 2019, 7: 8832-8844 doi: 10.1039/C8TA10822F
5. [5]
  Haque F, Visscher A De, Sen A. Crit. Rev. Env. Sci. Technol. , 2012, 42: 2648-2692 doi: 10.1080/10643389.2011.592764
6. [6]
  Wen M C, Li G Y, Liu H L, Chen J Y, An T C, Yamashita H. Environ. Sci. : Nano, 2019, 6: 1006-1025 doi: 10.1039/C8EN01167B
7. [7]
  LI S H, LI X Q, HU F T, ZHANG C, YAN X H. Chinese J. Inorg. Chem. , 2019, 35(3): 553-562
8. [8]
  Słomińska M, Król S, Namieśnik J. Crit. Rev. Env. Sci. Technol. , 2013, 43: 1417-1445 doi: 10.1080/10643389.2011.647760
9. [9]
  HOU J H, CAI R, SHEN M, JIANG K. Chinese J. Inorg. Chem. , 2018, 34(3): 467-474
10. [10]
  CHEN Y, LIU H B. Chinese J. Inorg. Chem. , 2017, 33(12): 2255-2261 doi: 10.11862/CJIC.2017.218
11. [11]
  Kang S F, He M F, Chen M Y, Liu Y F, Wang Y T, Wang Y G, Dong M D, Chang X J, Cui L F. ACS Appl. Mater. Interfaces, 2019, 11: 14952-14959 doi: 10.1021/acsami.9b01068
12. [12]
  Shi L, Liang L, Ma J, Wang F. X, Sun J M. Dalton Trans. , 2014, 43: 7236-7244 doi: 10.1039/C4DT00087K
13. [13]
  He F, Chen G, Yu Y G, Hao S, Zhou Y S, Zheng Y. ACS Appl. Mater. Interfaces, 2014, 6: 7171-7179 doi: 10.1021/am500198y
14. [14]
  Xue J J, Ma S S, Zhou Y M, Zhang Z W. ACS Appl. Mater. Interfaces, 2015, 7: 9630-9637 doi: 10.1021/acsami.5b01212
15. [15]
  Yang X F, Wang A Q, Qiao B T, Li J, Liu J Y, Zhang T. Acc. Chem. Res. , 2013, 46: 1740-1748 doi: 10.1021/ar300361m
16. [16]
  Qu M, Wan S P, Zhong Q, Zhang S L, Wang Y N. Int. J. Hydrogen Energy, 2017, 42: 27043-27054 doi: 10.1016/j.ijhydene.2017.09.047
17. [17]
  Xu T Z, Zheng H, Zhang P Y. J. Hazard. Mater. , 2020, 388: 121746 doi: 10.1016/j.jhazmat.2019.121746
18. [18]
  Zeng Z X, Su Y, Quan X, Choi W Y, Zhang G H, Liu N, Kim B, Chen S, Yu H T, Zhang S S. Nano Energy, 2020, 69: 104409 doi: 10.1016/j.nanoen.2019.104409
19. [19]
  Zhang L W, Long R, Zhang Y M, Duan D L, Xiong Y J, Zhang Y J, Bi Y P. Angew. Chem. Int. Ed. , 2020, 59: 6224-6229 doi: 10.1002/anie.201915774
20. [20]
  Hu C G, Han Q, Zhao F, Yuan Z Y, Chen N, Qu L T. Sci. China Mater. , 2015, 58: 21-27 doi: 10.1007/s40843-014-0012-3
21. [21]
  Li Y F, Jin R X, Xing Y, Li J Q, Song S Y, Liu X C, Li M, Jin R C. Adv. Energy Mater. , 2016, 6: 1601273 doi: 10.1002/aenm.201601273
22. [22]
  Wei H H, Huang K, Wang D, Zhang R Y, Ge B H, Ma J Y, Wen B, Zhang S, Li Q Y, Lei M, Zhang C, Irawan J S, Liu L M, Wu H. Nat. Commun. , 2017, 8: 1-8 doi: 10.1038/s41467-016-0009-6
23. [23]
  Liu P X, Zhao Y, Qin R X, Mo S G, Chen G X, Gu L, Chevrier D M, Zhang P, Guo Q, Zang D D, Wu B H, Fu G, Zheng N F. Science, 2016, 352: 797-800 doi: 10.1126/science.aaf5251
24. [24]
  Zhou P, Lv F, Li N, Zhang Y L, Mu Z J, Tang Y H, Lai J P, Chao Y G, Luo M C, Lin F, Zhou J H, Su D, Guo S J. Nano Energy, 2019, 56: 127-137 doi: 10.1016/j.nanoen.2018.11.033
25. [25]
  Li Y F, Jin R X, Xing Y, Li J Q, Song S Y, Liu X C, Li M, Jin R C. Adv. Energy Mater. , 2016, 6: 1601273 doi: 10.1002/aenm.201601273
26. [26]
  Dong G H, Ho W K, Wang C Y. J. Mater. Chem. A, 2015, 3: 23435-23441 doi: 10.1039/C5TA06540B
27. [27]
  Niu P, Zhang L L, Liu G, Cheng H M. Adv. Funct. Mater. , 2012, 22: 4763-4770 doi: 10.1002/adfm.201200922
28. [28]
  Zhao W, Wang J, Yin R, Li B Y, Huang X H, Zhao L L, Qian L. J. Colloid Interface Sci. , 2020, 564: 28-36 doi: 10.1016/j.jcis.2019.12.102
29. [29]
  Chen X, Tadd A R, Schwank J W. J. Catal. , 2007, 251(2): 374-387 doi: 10.1016/j.jcat.2007.07.031
30. [30]
  Li X G, Bi W T, Zhang L, Tao S, Chu W S, Zhang Q, Luo Y, Wu C Z, Xie Y. Adv. Mater. , 2016, 28: 2427 doi: 10.1002/adma.201505281
31. [31]
  Li Y H, Peng C, Yang S, Wang H F, Yang H G. J. Catal. , 2015, 330: 120-128 doi: 10.1016/j.jcat.2015.07.009
32. [32]
  Yu S X, Li J Y, Zhang Y H, Li M, Dong F, Zhang T R, Huang H W. Nano Energy, 2018, 50: 383-392 doi: 10.1016/j.nanoen.2018.05.053
33. [33]
  Kohno H, Berezin A A, Chang J S, Tamura M, Yamamoto T, Shibuya A, Hondo S. IEEE Trans. Ind. Appl. , 1998, 34: 953-966 doi: 10.1109/28.720435
34. [34]
  Huang H B, Ye D Q, Leung D Y C, Feng F D, Guan X J. J. Mol. Catal. A: Chem. , 2011, 336: 87-93 doi: 10.1016/j.molcata.2011.01.002
35. [35]
  Huang R, Lu M J, Wang P T, Chen Y D, Wu J L, Fu M L, Chen L M, Ye D Q. RSC Adv. , 2015, 88: 72113-72120
1. [1]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
2. [2]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
3. [3]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
4. [4]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
5. [5]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
6. [6]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
7. [7]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
8. [8]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
9. [9]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
10. [10]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
11. [11]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
12. [12]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
13. [13]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
14. [14]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
15. [15]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
16. [16]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
17. [17]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
18. [18]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(714)
HTML views(131)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Activity of Holey Ultrathin g-C3N4 Nanosheets-Supported Pt Composite

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Activity of Holey Ultrathin g-C₃N₄ Nanosheets-Supported Pt Composite