Citation: Qing-Shan QIAO, Sheng ZHANG, Xiao-Ya ZHOU, Li-Bing HU, Hong-Bin LU, Shao-Chun TANG. Preparation of Nickel Foam Supported Fe₂O₃@Ni₃S₂ Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1421-1429. doi: 10.11862/CJIC.2021.162 shu

Preparation of Nickel Foam Supported Fe₂O₃@Ni₃S₂ Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance

1.
National Laboratory of Solid State Microstructures, Jiangsu Key Laboratory of Artificial Functional Materials, College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China
2.
College of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

Corresponding author: Hong-Bin LU, luhb@ntu.edu.cn Shao-Chun TANG, tangsc@nju.edu.cn
Received Date: 6 April 2021
Revised Date: 13 June 2021

Figures(7)

A two-step hydrothermal method was used to prepare nickel foam (NF) supported Fe₂O₃ nanoparticles@Ni₃S₂ nanowires 3D network electrode (Fe₂O₃@Ni₃S₂/NF). The crystal phase and microstructure features of the products were characterized in detail by using some characterization techniques including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and N₂ adsorption-desorption measurement and so on. The in situ surface chemical etching process under hydrothermal conditions leads to the generation of Ni₃S₂ nanowires 3D network that binds to NF firmly with relatively low interfacial resistances. In an aqueous electrolyte of 1 mol·L^-1 KOH, the electrocatalytic oxygen evolution reaction (OER) performance of the obtained electrodes was tested by linear sweep voltammetry (LSV), chronopotentiometry, and electrochemical impedance test (EIS). At a ultrathigh current density of 100 mA·cm^-2, Fe₂O₃@Ni₃S₂/NF electrode showed a low OER overpotential of only 223 mV, which was 285 mV lower than that of Ni₃S₂/NF electrode (before growth of Fe₂O₃). These excellent properties are attributed to the faster reaction kinetics and smaller charge transfer impedance of Fe₂O₃@Ni₃S₂/NF electrode comparing with Ni₃S₂/NF.
- hydrothermal method,
- electrocatalysis,
- oxygen evolution reaction,
- Ni₃S₂ nanowire networks,
- Fe₂O₃ nanoparticles
1. [1]
  Hu E L, Ning J Q, Zhao D, Xu C Y, Lin Y Y, Zhong Y J, Zhang Z Y, Wang Y J, Hu Y. Small, 2018, 14: 1704233 doi: 10.1002/smll.201704233
2. [2]
  Peng Z, Yang S W, Jia D S, Da P M, He P, Al-Enizi A M, Ding G Q, Xie X M, Zheng G F. J. Mater. Chem. A, 2016, 4: 12878-12883 doi: 10.1039/C6TA04426C
3. [3]
  Mi Y Y, Qiu Y, Liu Y F, Peng X Y, Hu M, Zhao S Z, Cao H Q, Zhuo L C, Li H Y, Ren J Q, Liu X J, Luo J. Adv. Funct. Mater. , 2020, 30: 2003438 doi: 10.1002/adfm.202003438
4. [4]
  Chen Y, Guo R J, Peng X Y, Wang X Q, Liu X J, Ren J Q, He J, Zhuo L C, Sun J Q, Liu Y F, Wu Y E, Luo J. ACS Nano, 2020, 14: 6938 doi: 10.1021/acsnano.0c01340
5. [5]
  Xu J, Lai S H, Qi D F, Hu M, Peng X Y, Liu Y F, Liu W, Hu G Z, Xu H, Li F, Li C, He J, Zhuo L C, Sun J Q, Qiu Y, Zhang S S, Luo J, Liu X J. Nano Res. , 2021, 14: 1374 doi: 10.1007/s12274-020-3186-x
6. [6]
  Li H Y, Zhang L H, Li L, Wu C W, Huo Y J, Chen Y, Liu X J, Ke X X, Luo J, Tendeloo G V. Nano Res. , 2019, 12: 33-39 doi: 10.1007/s12274-018-2172-z
7. [7]
  Suen N T, Hung S F, Quan Q, Zhang N, Xu Y J, Chen H M. Chem. Soc. Rev. , 2017, 46(2): 337-365 doi: 10.1039/C6CS00328A
8. [8]
  Zhou Q, Chen Y P, Zhao G Q, Lin Y, Yu Z W, Xu X, Wang X L, Liu H K, Sun W P, Dou S X. ACS Catal. , 2018, 8: 5382-5390 doi: 10.1021/acscatal.8b01332
9. [9]
  Holade Y, Morais C, Servat K, Napporn T W, Kokoh K B. J. Phys. Chem. C, 2016, 120(5): 2562-2573 doi: 10.1021/acs.jpcc.5b11868
10. [10]
  Lee Y, Suntivich J, May K J, Perry E E, Shao-Horn Y. J. Phys. Chem. Lett. , 2012, 3(3): 399-404 doi: 10.1021/jz2016507
11. [11]
  Reier T, Oezaslan M, Strasser P. ACS Catal. , 2012, 2(8): 1765-1772 doi: 10.1021/cs3003098
12. [12]
  Gong M, Dai H A. Nano Res. , 2015, 8(1): 23-39 doi: 10.1007/s12274-014-0591-z
13. [13]
  Guo Y N, Tang J, Wang Z L, Kang Y M, Bando Y, Yamauchi Y. Nano Energy, 2018, 47: 494-502 doi: 10.1016/j.nanoen.2018.03.012
14. [14]
  Yang M, Jiang Y M, Qu M J, Qin Y C, Wang Y, Shen W, He R X, Su W, Li M. Appl. Catal. B, 2020, 269: 118803 doi: 10.1016/j.apcatb.2020.118803
15. [15]
  Tabassum H, Mahmood A, Zhu B J, Liang Z B, Zhong R Q, Guo S J, Zou R Q. Energy Environ. Sci. , 2019, 12: 2924-2956 doi: 10.1039/C9EE00315K
16. [16]
  Tabassum H, Guo W H, Meng W, Mahmood A, Zhao R, Wang Q F, Zou R Q. Adv. Energy Mater. , 2017, 7: 1601671 doi: 10.1002/aenm.201601671
17. [17]
  Zou X X, Wu Y Y, Liu Y P, Liu D P, Li W, Gu L, Liu H, Wang P W, Sun L, Zhang Y. Chem, 2018, 4: 1139-1152 doi: 10.1016/j.chempr.2018.02.023
18. [18]
  Zhu Y P, Chen H C, Hsu C S, Lin T S, Chang C J, Chang S C, Tsai L D, Chen H M. ACS Energy Lett. , 2019, 2: 987-994
19. [19]
  Flak D, Chen Q L, Mun B S, Liu Z, Rękas M, Braun A. Appl. Surf. Sci. , 2018, 455: 1019-1028 doi: 10.1016/j.apsusc.2018.06.002
20. [20]
  Feng J X, Wu J Q, Tong Y X. J. Am. Chem. Soc. , 2020, 142(44): 18997 doi: 10.1021/jacs.0c09673
21. [21]
  Yang Y Q, Zhang K, Lin H L, Li X, Chan H C, Yang L C, Gao Q S. ACS Catal. , 2017, 7: 2357-2366 doi: 10.1021/acscatal.6b03192
22. [22]
  ZHOU Q, OUYANG D K, WANG F, HE J S, LI X B. Chinese J. Inorg. Chem. , 2021, 37(3): 412-420
23. [23]
  Gao Y, Zhang N, Wang C R, Zhao F, Yu Y. ACS Appl. Energy Mater. , 2020, 3: 666-674 doi: 10.1021/acsaem.9b01866
24. [24]
  Qiu F, Shi J H, Guo M M, Chen S, Xia J H, Lu Z H. Inorg. Chem. , 2021, 60(2): 959-966 doi: 10.1021/acs.inorgchem.0c03073
25. [25]
  Xu Q Q, Huo W, Li S S, Fang J H, Li Li, Zhang B Y, Zhang F, Zhang Y X, Li S W. Appl. Surf. Sci. , 2020, 533: 147368 doi: 10.1016/j.apsusc.2020.147368
26. [26]
  Alduhaish O, Ubaidullah M, Al-Enizi A M, Alhokbany N, Alshehri S M, Ahmed J. Sci. Rep. , 2019, 9: 14139 doi: 10.1038/s41598-019-50780-2
27. [27]
  Moi C T, Bhowmick S, Sahu T K, Qureshi M. Electrochim. Acta, 2021, 370: 137726 doi: 10.1016/j.electacta.2021.137726
28. [28]
  Yang Y Y, Zhu C M, Zhang Y, Xie Y D, Lv L W, Chen W L, He Y Y, Hu Z A. J. Phys. Chem. Solids, 2021, 148: 109680 doi: 10.1016/j.jpcs.2020.109680
29. [29]
  Zhao H, Jiang M, Kang Q, Liu L Q, Zhang N, Wang P C, Zhou F M. Catal. Sci. Technol. , 2020, 10: 8305-8310 doi: 10.1039/D0CY01071E
30. [30]
  Guo K L, Wang Y T, Yang S Z, Huang J F, Zou Z H, Pan H R, Shinde P S, Pan S L, Huang J E, Xu C L. Sci. Bull. , 2021, 66: 52-61 doi: 10.1016/j.scib.2020.06.003
31. [31]
  Liu S, Chen T T, Ying H, Li Z H, Hao J C. Adv. Sustainable Syst. , 2020, 4: 2000038 doi: 10.1002/adsu.202000038
32. [32]
  Samanta A, Das S, Jana S. ACS Sustainable Chem. Eng. , 2019, 7: 12117-12124
33. [33]
  Hu Q, Huang X W, Wang Z Y, Li G M, Han Z, Yang H P, Liao P, Ren X Z, Zhang Q L, Liu J H, He C X. Small, 2020, 16: 2002210 doi: 10.1002/smll.202002210
1. [1]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
2. [2]
  Yachao HUANG , Chuanwang ZENG , Guiyong LIU , Jinming ZENG , Chao LIU , Xiaopeng QI . Oxygen vacancies and phosphorus doping enhanced metal-organic framework derived nitrogen-doped carbon-coated Co₃O₄ bifunctional electrocatalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2251-2260. doi: 10.11862/CJIC.20250133
3. [3]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
4. [4]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
5. [5]
  Yajuan Xing , Hui Xue , Jing Sun , Niankun Guo , Tianshan Song , Jiawen Sun , Yi-Ru Hao , Qin Wang . Cu₃P-Induced Charge-Oriented Transfer and Surface Reconstruction of Ni₂P to Achieve Efficient Oxygen Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(3): 2304046-0. doi: 10.3866/PKU.WHXB202304046
6. [6]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
7. [7]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
8. [8]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
9. [9]
  Dingwen CHEN , Siheng YANG , Haiyan FU , Hua CHEN , Xueli ZHENG , Weichao XUE , Jiaqi XU , Ruixiang LI . NiOOH-mediated synthesis of gold nanoaggregates for electrocatalytic performance for selective oxidation of glycerol to glycolate. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2317-2326. doi: 10.11862/CJIC.20250053
10. [10]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
11. [11]
  Shiqian WEI , Xinyu TIAN , Hong LIU , Maoxia CHEN , Fan TANG , Qiang FAN , Weifeng FAN , Yu HU . Oxygen reduction reaction/oxygen evolution reaction catalytic performances of different active sites on nitrogen-doped graphene loaded with iron single atoms. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1776-1788. doi: 10.11862/CJIC.20250102
12. [12]
  Ruige ZHANG , Zhe ZHANG , He ZHENG , Zhan SHI . Recent advances of metal-organic frameworks for alkaline electrocatalytic oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2011-2028. doi: 10.11862/CJIC.20250185
13. [13]
  Wuxin Bai , Qianqian Zhou , Zhenjie Lu , Ye Song , Yongsheng Fu . Co-Ni Bimetallic Zeolitic Imidazolate Frameworks Supported on Carbon Cloth as Free-Standing Electrode for Highly Efficient Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305041-0. doi: 10.3866/PKU.WHXB202305041
14. [14]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
15. [15]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 100024-0. doi: 10.3866/PKU.WHXB202404012
16. [16]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
17. [17]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
18. [18]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
19. [19]
  Anqun LAI , Qiaoyu WU , Qingqing LIANG , Qiyong LI , Guowen DONG , Yongjie DING , Jia′nan CHEN , Qing YAN , Zhonghua PAN , Wangchuan XIAO . Electrocatalytic water oxidation properties of Nd-Co polynuclear complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2527-2535. doi: 10.11862/CJIC.20250151
20. [20]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117

Get Citation

PDF

XML

Metrics

PDF Downloads(46)
Abstract views(5016)
HTML views(1297)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Nickel Foam Supported Fe2O3@Ni3S2 Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Nickel Foam Supported Fe₂O₃@Ni₃S₂ Nanowires Network Electrode and Electrocatalytic Oxygen Evolution Performance