Citation: Gai-Qing ZHANG, Cai-Xia YIN. Application of Fluorescent Probe Based on Dicyanoisophorone in Detection of Thiophenol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1245-1250. doi: 10.11862/CJIC.2021.161 shu

Application of Fluorescent Probe Based on Dicyanoisophorone in Detection of Thiophenol

Gai-Qing ZHANG ^{1, 2} ,
Cai-Xia YIN ^2,,

1.
Department of Chemistry and Chemical Engineering, Lüliang University, Lüliang, Shanxi 033000, China
2.
Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: Cai-Xia YIN, yincx@sxu.edu.cn
Received Date: 18 February 2021
Revised Date: 14 May 2021

Figures(9)

To develop a method with high selectivity and sensitivity to detect thiophenol, based on the excellent optical properties and good membrane permeability of dicyanoisophorone dyes, we chose dicyanoisophorone derivatives as fluorophores and introduced a strong electron-withdrawing 2, 4-dinitrobenzene synthetic fluorescent probe (YC1) for the specific recognition of thiophenol. The probe showed obvious red fluorescence on thiophenol (emission wavelength: 594 nm, excitation wavelength: 420 nm) and had a fluorescence-enhanced (turn-on) property for the recognition of thiophenol. The probe had a good selectivity for the recognition of thiophenol and the detection limit of the probe was 0.65 μmol·L^-1 in PBS/DMSO system (PBS=phosphate buffer saline, DMSO=dimethyl sulfoxide). In addition, the probe has been successfully applied to the fluorescence imaging of 4-methylthiophenol in HeLa cells.
- dicyanoisophorone,
- thiophenol,
- fuorescence enhancement,
- biological imaging
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