Citation: Jia-Xiang HUANG, He ZHAO, Shu-Qin LIU, Jian-Jun ZHANG. Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn₂(COO)₄} Second Bulidings Units: Crystal Structure and Detection of Fe³⁺[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1513-1518. doi: 10.11862/CJIC.2021.155 shu

Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn₂(COO)₄} Second Bulidings Units: Crystal Structure and Detection of Fe³⁺

School of Chemical Engineering, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 27 April 2021
Revised Date: 2 June 2021

Figures(5)

A two-dimensional luminescent coordination polymer based on dinuclear {Zn₂(COO)₄} second buildings units, [Zn₂(L)₂(DMSO)₂(DMF)] (1, H₂L=2-(1, 3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl) terephthalic acid, DMSO=dimethyl sulfoxide, DMF=dimethylformamide), was synthesized by hydrothermal reaction using H₂L ligand and Zn²⁺. Topological analysis shows that the dinuclear {Zn₂(COO)₄} unit can be regarded as a 4-linked node and forms a (4, 4) net topology with L^2- linker. 1 also exhibited a selective luminescence quenching type response to Fe³⁺ with detection limit as low as 2.8 μmol·L^-1. 1 has good anti-interference ability for the detection of Fe³⁺, and can be regenerated and recycled for several times by washing with DMF solvent.
- luminescent coordination polymer,
- π-π stacking interaction,
- crystal structure,
- Fe³⁺,
- detection
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Two-Dimensional Luminescent Coordination Polymer Based on Dinuclear {Zn₂(COO)₄} Second Bulidings Units: Crystal Structure and Detection of Fe³⁺