Citation: Tong-Ming SUN, Meng-Ke ZHANG, Xu SHI, Run-Sheng XU, Zheng-Yi CHENG, Xing-Yuan QI, Jin WANG, Jin-Li ZHU, Min-Min WANG. Synthesis and Properties of {Ln₂^ⅢCo₆^Ⅱ} Heterometallic Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1177-1183. doi: 10.11862/CJIC.2021.154 shu

Synthesis and Properties of {Ln₂^ⅢCo₆^Ⅱ} Heterometallic Complexes

Tong-Ming SUN ^{1, #} ,
Meng-Ke ZHANG ^{1, #} ,
Xu SHI ^{1, #} ,
Run-Sheng XU ² ,
Zheng-Yi CHENG ¹ ,
Xing-Yuan QI ¹ ,
Jin WANG ^{1, 3,,} ,
Jin-Li ZHU ^{1, 3,,} ,
Min-Min WANG ^1,,

1.
School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China
2.
Xinlin College, Nantong University, Nantong, Jiangsu 226019, China
3.
Nantong Key Laboratory of Intelligent and New Energy Materials, Nantong, Jiangsu 226019, China

Corresponding author: Jin WANG, wangjin110@ntu.edu.cn Jin-Li ZHU, jinlizhu@ntu.edu.cn Min-Min WANG, mmwang0528@ntu.edu.cn
Received Date: 13 January 2021
Revised Date: 15 May 2021

Figures(5)

Using 6-chloro-2-hydropyridine (Hcp) as ligand and pivalic acid (Hpiv) as the auxiliary ligand, five heterometallic complexes {Ln₂^ⅢCo₆^Ⅱ} (Ln=Sm (1), Eu (2), Tb (3), Er (4), Tm (5)) were synthesized. Single-crystal X-ray diffraction analyses reveal that complexes 1~5 are isostructural and belong to triclinic system space group P1. Magnetic susceptibilities revealed antiferromagnetic coupling within complexes 1~5, and complex 1 displayed slow relaxation of magnetization. Medium diffusion method was used to determine the antibacterial activity of complexes 1~5 and their isomorphisms {Ln₂^ⅢCo₆^Ⅱ} (Ln=Dy (6), Ho (7), Gd (8), Y (9)). All complexes possessed antibacterial activity on both escherichia coli (E. coli) and staphylococcus aureus (S. aureus). Thereinto, complex 5 displayed best antibacterial effect on E. coli, while complex 9 exhibited effective antibacterial activities against S. aureus. CCDC: 2022664, 1; 2022665, 2; 2022666, 3;2022667, 4; 2022668, 5.
- rare earth,
- cobalt,
- polynuclear,
- magnetic property,
- antibacterial activity
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Synthesis and Properties of {Ln₂^ⅢCo₆^Ⅱ} Heterometallic Complexes