Citation: Cui-Xin HUANG, Jia GU, Wan-Ming XIONG, Jin-Zhu CHEN, Xu-Liang NIE, Xin-Chen SHANGGUAN. Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Zn(Ⅱ)/Cd(Ⅱ) Assembled by 4-Carboxymethoxycinnamic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1197-1203. doi: 10.11862/CJIC.2021.153 shu

Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Zn(Ⅱ)/Cd(Ⅱ) Assembled by 4-Carboxymethoxycinnamic Acid Ligand

Cui-Xin HUANG ¹ ,
Jia GU ² ,
Wan-Ming XIONG ^{2, 3} ,
Jin-Zhu CHEN ^{2, 3} ,
Xu-Liang NIE ^{1, 2, 3,,} ,
Xin-Chen SHANGGUAN ⁴

1.
College of Agronomy, Jiangxi Agricultural University, Nanchang 330045, China
2.
College of Science, Jiangxi Agricultural University, Nanchang 330045, China
3.
Key Laboratory of Chemical Utilization of Plant Resources of Nanchang, Nanchang 330045, China
4.
Jiangxi Institute for Drug Control, Nanchang 330029, China

Corresponding author: Xu-Liang NIE, niexuliang1981@163.com
Received Date: 29 December 2020
Revised Date: 10 May 2021

Figures(9)

Two Zn(Ⅱ)/Cd(Ⅱ) complexes, [Zn(CMOPAA)(Phen)(H₂O)]_n (1) and [Cd(CMOPAA)(Phen)]_n (2), (H₂CMOPAA =4-carboxymethoxy-3-phenylpropenoate and Phen=1, 10-phenanthroline) were synthesized with H₂CMOPAA ligand by solvothermal condition and structurally characterized by element analysis, IR, TGA (thermogravimetric analysis) and single crystal X-ray diffraction. Complex 1 crystalizes in the monoclinic system, space group P2₁/n with a= 0.698 84(8) nm, b=1.751 16(19) nm, c=1.655 49(18) nm, β=95.165(10)°, V=2.017 7(4) nm³. The asymmetric unit of complex 1 consists of one Zn(Ⅱ) ion, one CMOPAA^2- ligand, one Phen ligand and one coordinated H₂O. Zn(Ⅱ) ion is a six-coordinated distorted octahedral configuration. The carboxyl group of CMOPAA^2- ligand connects the adjacent zinc ions to form a helical one-dimensional chain. Hydrogen bonds link the adjacent one-dimensional chains to form a two-dimensional network. Complex 2 crystalizes in the triclinic system, space group P1 with a=0.988 28(16) nm, b =1.040 08(17) nm, c=1.096 15(18) nm, α=72.213(2)°, β=74.439(2)°, γ=71.265(2)°, V=0.997 8(3) nm³. The asymmetric unit of complex 2 consists of one Cd(Ⅱ) ion, one CMOPAA^2- ligand and one Phen ligand. Cd(Ⅱ) ion is a seven-coordinated twisted single-cap triangular prism configuration. The carboxyl group of CMOPAA^2- ligand connects the adjacent cadmium ions to form a parallelogram 26-membered large ring structure. The 26-membered large rings are linked to a one-dimensional band-like structure. The thermal stabilities and antibacterial activities of complexes 1 and 2 were studied. CCDC: 2054460, 1; 2068057, 2
- 4-carboxymethoxy-3-phenylpropenoate,
- complex,
- synthesis,
- crystal structure,
- antibacterial activities
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