Citation: You-Qun CHU, Zhang-Kao HUANG, Xin-Hang WANG, Meng-Lei ZHOU, Feng-Ming ZHAO. One-Pot Solvothermal Synthesis of Ag-TiO₂ Microspheres for Electrochemical Detection of Hydrogen Peroxide[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1258-1268. doi: 10.11862/CJIC.2021.149 shu

One-Pot Solvothermal Synthesis of Ag-TiO₂ Microspheres for Electrochemical Detection of Hydrogen Peroxide

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, China

Corresponding author: Feng-Ming ZHAO, zhaofm@zjut.edu.cn
Received Date: 16 October 2020
Revised Date: 26 May 2021

Figures(15)

Herein, finely dispersed silver decorated TiO₂ microspheres have been synthesized by one-pot solvothermal method using tetrabutyl titanate and vitamin C in ethanol. The structure of TiO₂ microsphere and high dispersion of nano silver were regulated by the alcoholysis of tetrabutyl titanate and reducibility of enol in vitamin C. The one-pot method was beneficial to reduce the complex procedures and obtain uniform spherical particles with a diameter of 250 nm. The silver lattice stripes integrated into the surface of microsperes show crystal plane (111) characteristics. The composite electrode exhibited excellent electrocatalytic activity of H₂O₂. The developed sensor allowed the detection of H₂O₂ with the linear range of 0.1~102 μmol·L^-1, sensitivity of 3.13×10^-3 μA·L·μmol^-1·cm^-2 and detection limit of 0.04 μmol·L^-1. The resulting device also had longterm stability, reproducibility and repeatability. The performance could be maintained at 82.1% after a month.
- silver,
- titanium dioxide microsphere,
- hydrogen peroxide,
- electrochemical detection
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沈阳化工大学材料科学与工程学院沈阳 110142

One-Pot Solvothermal Synthesis of Ag-TiO2 Microspheres for Electrochemical Detection of Hydrogen Peroxide

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通讯作者: 陈斌, bchen63@163.com

One-Pot Solvothermal Synthesis of Ag-TiO₂ Microspheres for Electrochemical Detection of Hydrogen Peroxide