Citation: Qian ZHANG, Yue-Li WEN, Bin WANG, He-Ming FAN, Chen YANG, Rong-Peng SONG, Wei-Zhong ZHANG, Wei HUANG. Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1390-1398. doi: 10.11862/CJIC.2021.148 shu

Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol

Qian ZHANG ¹ ,
Yue-Li WEN ^1,, ,
Bin WANG ² ,
He-Ming FAN ¹ ,
Chen YANG ¹ ,
Rong-Peng SONG ¹ ,
Wei-Zhong ZHANG ¹ ,
Wei HUANG ^{2, 3,,}

1.
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan 030024, China
3.
Shanxi Taiyuan Coal Conversion Technology Engineering Co., Ltd., Taiyuan 030024, China

Corresponding author: Yue-Li WEN, wenyueli@tyut.edu.cn Wei HUANG, huangwei@tyut.edu.cn
Received Date: 28 January 2021
Revised Date: 25 April 2021

Figures(7)

CuFe@MOFs derived catalysts were synthesized by introducing a second ligand, p-aminobenzoic acid, in the hydrothermal synthesis of MIL-88B(Fe), which was followed by impregnation with Cu species. The physicochemical properties of the catalysts were characterized by X-ray diffraction (XRD), H₂-temperature programmed reduction (H₂-TPR), N₂ adsorption-desorption, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the catalysts for hydrogenation of CO₂ to C₂₊ alcohol (C₂₊OH) was tested in a fixed bed reactor. The results show that the elements of active components were evenly dispersed, and the active species distribution on the catalyst surface can be controlled by adjusting the molar ratio of two ligands (terephthalic acid to p-aminobenzoic acid ligands) in the raw materials. When the molar ratio of terephthalic acid to p-aminobenzoic acid was 5:2, the proportion of low-valence iron of the as-obtained catalyst was the highest (71.27%). Accordingly, this catalyst showed the best performance for CO₂ hydrogenation to C₂₊OH, that the conversion of CO₂ was 8.80%, the selectivity of total alcohol (ROH) was 31.52% and the molar fraction of C₂₊OH was 94.70%. This might be due to the high proportion of low-valence iron species and the well-dispersed active components.
- dual ligand,
- CuFe@MOFs,
- composition control,
- carbon dioxide,
- hydrogenation,
- C₂₊,
- alcohol
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Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO2 Hydrogenation to C2+ Alcohol

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Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol