Citation: Jiang-Cong ZHOU, Meng-Ting CHEN, Yi-Qing LAI, Chen SHI, De-Wu WU, Quan-Sheng WU. Synthesis and Luminescence Properties of Broadband Emitting Yellow Phosphor Sr₈MgAl(PO₄)₇: xEu²⁺ for White Light-Emitting Diode[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1237-1244. doi: 10.11862/CJIC.2021.147 shu

Synthesis and Luminescence Properties of Broadband Emitting Yellow Phosphor Sr₈MgAl(PO₄)₇: xEu²⁺ for White Light-Emitting Diode

Jiang-Cong ZHOU ^{1, 2,,} ,
Meng-Ting CHEN ² ,
Yi-Qing LAI ² ,
Chen SHI ² ,
De-Wu WU ¹ ,
Quan-Sheng WU ^{1, 2}

1.
College of Chemistry & Materials Science, Longyan University, Longyan, Fujian 364012, China
2.
College of Material Science, Fuzhou University, Fuzhou 350001, China

Corresponding author: Jiang-Cong ZHOU, jiangcongzhou@163.com
Received Date: 15 February 2021
Revised Date: 8 May 2021

Figures(6)

In this study, a series of broadband emitting yellow phosphors Sr₈MgAl(PO₄)₇: xEu²⁺ (SMAP: xEu²⁺) were synthesized by high temperature solid-state reaction; and the structure, luminescent properties and potential application in white light-emitting diode (WLED) were investigated. The X-ray diffraction (XRD) results showed that the SMAP: xEu²⁺ phosphors had monoclinic system and C2/m space group; and the activator Eu²⁺ ions can enter into the SMAP matrix and occupy the lattice site of Sr²⁺ ions. Diffuse reflectance spectroscopy showed that SMAP host was a wide band-gap material with a band gap of 3.60 eV. In addition, SMAP: xEu²⁺ had a broad excitation range (280~ 500 nm), corresponding to the 4f⁷→4f⁶5d¹ transition of Eu²⁺ ions. Under the excitation of 380 nm near-ultraviolet light, there was an asymmetric yellow emission at the wavelength of 450~800 nm from multiple emission centers; and the emission peak was located at 590 nm. Based on Gaussian multi-peak fitting results, three emission centers were located at 528, 600 and 680 nm, respectively. Finally, the as-prepared yellow phosphor SMAP: 0.05Eu²⁺ and commercial blue phosphor BaMgAl₁₀O₁₇: Eu²⁺ were mixed and coated on the surface of 400 nm chip to fabricate WLED with good color temperature (3 344 K) and high color rendering index (90.1).
- broadband emission,
- Sr₈MgAl(PO₄)₇,
- yellow phosphor,
- white light-emitting diode,
- near ultraviolet excitation,
- high color rendering index
1. [1]
  Xia Z G, Liu Q. Prog. Mater Sci. , 2016, 84(12): 59-117
2. [2]
  Lin H, Hu T, Cheng Y, Chen M X, Wang Y S. Laser Photonics Rev. , 2018, 12(6): 1700344 doi: 10.1002/lpor.201700344
3. [3]
  Shao B Q, Huo J S, You H P. Adv. Opt. Mater. , 2019, 7(13): 1900319
4. [4]
  Pust P, Schmidt P J, Schnick W. Nat. Mater. , 2015, 14(5): 454-458 doi: 10.1038/nmat4270
5. [5]
  Wang L, Xie R J, Suehiro T, Takeda T, Hirosaki N. Chem. Rev. , 2018, 118(4): 1951-2009 doi: 10.1021/acs.chemrev.7b00284
6. [6]
  Wei Y, Gao Z Y, Liu S W, Chen S T, Xing G C, Wang W, Dang P P, Kheraif A A, Li G G, Lin J. Adv. Opt. Mater. , 2020, 8(6): 1901859 doi: 10.1002/adom.201901859
7. [7]
  JI C Y, XIAO S Y, HUANG Z S, HUANG Z, WEN J, PENG Y X. J. Lumin. , 2020, 41(5): 52-58
8. [8]
  Dai P P, Wang Q L, Xiang M, Chen T M, Zhang X T, Chiang Y W, Chan T S, Wang X J. Chem. Eng. J. , 2020, 380(1): 122508
9. [9]
  ZHANG Y, LU J J, LIU J Q, LI Y, WANG L X, ZHANG Q T. Chinese J. Inorg. Chem. , 2012, 28(10): 2036-2042
10. [10]
  LI S, GUO N, LIANG Q M, DENG H X. Chinese J. Inorg. Chem. , 2017, 33(4): 543-549
11. [11]
  CHENG S W, ZHANG N, ZHUO N Z, ZHU Y H, CHEN Y H, JIANG P, DU W H, YE E G, WANG H B. Chinese J. Inorg. Chem. , 2019, 35(2): 35-42
12. [12]
  Qiao J W, Xia Z G, Zhang Z C, Hu B T, Liu Q L. Sci. China Mater. , 2018, 61: 985-992 doi: 10.1007/s40843-017-9207-2
13. [13]
  Qiao J W, Zhao J, Xia Z G. Opt. Mater. : X, 2019, 1: 100019
14. [14]
  Chen M Y, Xia Z G, Molokeev M S, Wang T, Liu Q L. Chem. Mater. , 2017, 29(3): 1430-1438 doi: 10.1021/acs.chemmater.7b00006
15. [15]
  Chen M Y, Xia Z G, Molokeev M S, Lin C C, Su C C, Chuang Y C, Liu Q L. Chem. Mater. , 2017, 29(17): 7563-7570 doi: 10.1021/acs.chemmater.7b02724
16. [16]
  Cui M, Wang J D, Shang M M, Li J H, Wei Q, Dang P P, Jang H S, Lin J. J. Mater. Chem. C, 2019, 7(12): 3644-3655 doi: 10.1039/C9TC00109C
17. [17]
  Leng Z H, Li R F, Li L P, Xue D K, Zhang D, Li G S, Chen X Y, Zhang Y. ACS Appl. Mater. Interfaces, 2018, 10: 33322-33334 doi: 10.1021/acsami.8b11879
18. [18]
  Qiao J W, Zhang Z C, Zhao J, Xia Z G. Inorg. Chem. , 2019, 58(8): 5006-5012 doi: 10.1021/acs.inorgchem.9b00028
19. [19]
  Wen D W, Dong Z Y, Shi J X, Gong M L, Wu M M. ECS J. Solid State Sci. Technol. , 2013, 2(9): R178-R185 doi: 10.1149/2.019309jss
20. [20]
  Yan J, Zhang Z W, Wen D W, Zhou J B, Xu Y Q, Li J H, Ma C G, Shi J X, Wu M M. J. Mater. Chem. C, 2019, 7(27): 8374-8382 doi: 10.1039/C9TC02494H
21. [21]
  Zhang J, Hua Z H, Wen S Z. J. Alloys Compd. , 2015, 637: 70-76 doi: 10.1016/j.jallcom.2015.02.117
22. [22]
  Huang C H, Chen T M. Inorg. Chem. , 2011, 50(12): 5725-5730 doi: 10.1021/ic200515w
23. [23]
  Huang C H, Wang D Y, Chiu Y C, Yeh Y T, Chen T M. RSC Adv. , 2012, 2(24): 9130-9134 doi: 10.1039/c2ra20646c
24. [24]
  Huang C H, Chen Y C, Chen T M, Chan T S, Sheu H S. J. Mater. Chem. , 2011, 21(15): 5645-5649 doi: 10.1039/c0jm04524a
25. [25]
  Belik A A, Izumi F, Ikeda T, Okui M, Malakho A P, Morozov V A, Lazoryak B I. J. Solid State Chem. , 2002, 168(1): 237-244 doi: 10.1006/jssc.2002.9716
26. [26]
  Tang W J, Zhang F, Hu S S. ECS J. Solid State Sci. Technol. , 2014, 3(4): R65-R69 doi: 10.1149/2.009404jss
27. [27]
  Liu Y F, Silver J, Xie R J, Zhang J H, Xu H W, Shao H Z, Jiang J, Jiang H C. J. Mater. Chem. C, 2017, 5(2): 12365-12377
28. [28]
  Zhang H L, Yuan D W, Mi X Y, Liu X L, Lin J. Dalton Trans. , 2020, 49(26): 8949-8958 doi: 10.1039/D0DT01130D
29. [29]
  Wang J D, Shang M M, Cui M, Dang P P, Liu D J, Huang D Y, Lian H Z, Lin J. J. Mater. Chem. C, 2020, 8(1): 285-295 doi: 10.1039/C9TC05768D
30. [30]
  Zhang S A, Li Y, Lv Y, Fan L M, Hu Y H, He M. Chem. Eng. J. , 2017, 322: 314-327 doi: 10.1016/j.cej.2017.04.032
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Synthesis and Luminescence Properties of Broadband Emitting Yellow Phosphor Sr8MgAl(PO4)7: xEu2+ for White Light-Emitting Diode

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Luminescence Properties of Broadband Emitting Yellow Phosphor Sr₈MgAl(PO₄)₇: xEu²⁺ for White Light-Emitting Diode