Citation: Mei HE, Huan-Yun SUN, Shi-Kuo LI. Manipulating Electronic Structure of NiS by Mo Doping for Boosting Electrocatalytic Nitrogen Fixation[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1211-1217. doi: 10.11862/CJIC.2021.145 shu

Manipulating Electronic Structure of NiS by Mo Doping for Boosting Electrocatalytic Nitrogen Fixation

College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, China

Corresponding author: Shi-Kuo LI, lishikuo@ahu.edu.cn
Received Date: 1 February 2021
Revised Date: 21 April 2021

Figures(7)

Mo doped NiS (Mo-NiS) hierarchical nanoflowers were prepared on porous nickel foam substrates by hydrothermal method for high-efficient electrocatalytic nitrogen fixation. Within 2 h, the optimized Mo-NiS sample 0.83 Mo-NiS (the ratio of the amount of molybdenum and nickel during preparation was 0.83) exhibited a remarkable average NH₃ formation rate of 4.21 μg·cm^-2·h^-1 and an average Faraday efficiency of 18% at -0.7 V (vs RHE). XPS and DFT analysis revealed that Mo doping NiS nanoflower increased the electron cloud density of Ni atom, and reduced the energy barrier from *NNH₂ to *N in the rate-determining step for nitrogen fixation.
- NiS,
- nanoflower,
- Mo doping,
- charge transfer,
- electrocatalytic nitrogen fixation
1. [1]
  Tanabe Y, Nishibayashi Y. Coord. Chem. Rev. , 2013, 257: 2551-2564 doi: 10.1016/j.ccr.2013.02.010
2. [2]
  Guo C, Ran J, Vasileff, A, Qiao S Z. Energ Environ. Sci. , 2018, 11: 45-56 doi: 10.1039/C7EE02220D
3. [3]
  Cornelis J M V D H, Marc T M K, Dennis G H H. Chem. Soc. Rev. , 2014, 43: 5183-5191 doi: 10.1039/C4CS00085D
4. [4]
  Masaaki K, Yasunori I, Youhei Y, Fumitaka H, Shinji K, Satoru M, Toshiharu Y, Kim S W, Michikazu H, Hideo H. Nat. Chem. , 2012, 4: 934-940 doi: 10.1038/nchem.1476
5. [5]
  Guo W H, Zhang K X, Liang Z B, Zou R Q, Xu Q. Chem. Soc. Rev. , 2019, 48: 5658-5716 doi: 10.1039/C9CS00159J
6. [6]
  Zhao S L, Wang Y, Dong J C, He C T, Yin H J, An P F, Zhao K, Zhang X F, Gao C, Zhang L J, Lv J W, Wang J X, Zhang J Q, Abdul M K, Niaz A K, Wei Z X, Zhang J, Liu S Q, Zhao H J, Tang Z Y. Nat. Energy, 2016, 1: 16184 doi: 10.1038/nenergy.2016.184
7. [7]
  Fei B, Chen Z L, Liu J X, Xu H B, Yan X X, Qing H L, Chen M, Wu R B. Adv. Energy Mater. , 2020, 10(41): 2001963 doi: 10.1002/aenm.202001963
8. [8]
  Li H Y, Chen S M, Zhang Y, Zhang Q H, Jia X F, Zhang Q, Gu L, Sun X M, Song L, Wang X. Nat. Commun. , 2018, 9: 2452 doi: 10.1038/s41467-018-04888-0
9. [9]
  Chakadola P, Prashanth W M, Yao S L, Johannes S, Carsten W, Jan N H, Matthias D. J. Am. Chem. Soc. , 2019, 141: 13306-13310 doi: 10.1021/jacs.9b06530
10. [10]
  Guo M R, Abdul Q, Dong S, Jiao X L, Chen D R, Wang T. J. Mater. Chem. A, 2020, 8: 9239-9247 doi: 10.1039/D0TA02337J
11. [11]
  Cao N, Chen Z, Zang K T, Xu J, Zhong J, Luo J, Xu X, Zheng G F. Nat. Commun. , 2019, 10: 2877 doi: 10.1038/s41467-019-10888-5
12. [12]
  Wu T W, Kong W H, Zhang Y, Xing Z, Zhao J X, Wang T, Shi X F, Luo Y L, Sun X P. Small Methods, 2019: 1900356
13. [13]
  Zhang N, Abdul J, Wu D X, Chen S M, Liu Y F, Gao G, Ye W, Qi Z M, Ju H X, Wang C M, Wu X J, Song L, Zhu J F, Xiong Y J. J. Am. Chem. Soc. , 2018, 140: 9434-9443 doi: 10.1021/jacs.8b02076
14. [14]
  Tong Y Y, Guo H P, Liu D L, Yan X, Su P P, Liang J, Zhou S, Liu J, Lu G Q, Dou S X. Angew. Chem. Int. Ed. , 2020, 59: 7356-7361 doi: 10.1002/anie.202002029
15. [15]
  Chu K, Liu Y P, Li Y B, Guo Y L, Tian Y, Zhang H. Appl. Catal. B, 2020, 264: 118525 doi: 10.1016/j.apcatb.2019.118525
16. [16]
  Han L L, Liu X J, Chen J P, Lin R Q, Liu H X, Lv F, Seongmin B, Liang Z X, Zhao S Z, Eli S, Luo J, Radoslav R A, Xin H L. Angew. Chem. Int. Ed. , 2019, 58: 2321-2325 doi: 10.1002/anie.201811728
17. [17]
  Li J, Wang Y C, Zhou T, Zhang H, Sun X H, Tang J, Zhang L J, Abdullah M A, Yang Z Q, Zheng G F. J. Am. Chem. Soc. , 2015, 137: 14305-14312 doi: 10.1021/jacs.5b07756
18. [18]
  Franz S, Arab H, Chiarello G L, Bestetti M, Selli E. Adv. Energy Mater. , 2020, 10(23): 2000652 doi: 10.1002/aenm.202000652
19. [19]
  Ma J, Li P C, Lin K N, Chen Z Y, Chen N W, Liao K W, Yuan D X. Talanta, 2018, 179: 608-614 doi: 10.1016/j.talanta.2017.11.069
20. [20]
  Zhang L, Ji X Q, Ren X, Luo Y L, Shi X F, Abdullah M A, Zheng B Z, Sun X P. ACS Sustainable Chem. Eng. , 2018, 6: 9550-9554 doi: 10.1021/acssuschemeng.8b01438
21. [21]
  Matanovic I, Garzon F H. Phys. Chem. Chem. Phys. , 2018, 20: 14679-14687 doi: 10.1039/C8CP01643G
22. [22]
  Chen G F, Cao X R, Wu S Q, Zeng X Y, Ding L X, Zhu M, Wang H H. J. Am. Chem. Soc. , 2017, 139: 9771-9774 doi: 10.1021/jacs.7b04393
23. [23]
  Li X H, Li T S, Ma Y J, Wei Q, Qiu W B, Guo H R, Shi X F, Zhang P, Abdullah M. A, Chen L, Tang B, Sun X P. Adv. Energy Mater. , 2018, 8(30): 1801357
24. [24]
  Liu Y Y, Han M M, Xiong Q Z, Zhang S B, Zhao C J, Gong W B, Wang G Z, Zhang H M, Zhao H J. Adv. Energy Mater. , 2019, 9(14): 1803935 doi: 10.1002/aenm.201803935
25. [25]
  Bryan H R S, Wang D B, Luis M A, Moussab H, Luigi C, Rouhollah J, David R G M, Manjunath C, Douglas R M. ACS Energy Lett. , 2019, 4: 430-435 doi: 10.1021/acsenergylett.8b02257
26. [26]
  Zhang L, Ji X Q, Ren X, Ma Y J, Shi X F, Tian Z Q, Abdullah M A, Chen L, Tang B, Sun X P. Adv. Mater. , 2018, 30: 1800191 doi: 10.1002/adma.201800191
1. [1]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
2. [2]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
3. [3]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
4. [4]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
5. [5]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
6. [6]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
9. [9]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
10. [10]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
11. [11]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
14. [14]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
15. [15]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
18. [18]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
19. [19]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
20. [20]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1374)
HTML views(428)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142