Citation: Wen-Jun LI, Cheng-Hao FANG, Peng LÜ, Ke-Han YU, Zhong-Yue WANG, Wei WEI. Hydrothermal Synthesis and Electrochemical Properties of Na₃V₂(PO₄)₂O₂F Cathode for Sodium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1204-1210. doi: 10.11862/CJIC.2021.141 shu

Hydrothermal Synthesis and Electrochemical Properties of Na₃V₂(PO₄)₂O₂F Cathode for Sodium-Ion Batteries

College of Electronic and Optical Engineering & College of Microelectronics, Nanjing University of Posts and Telecommunications, Nanjing 210023, China

Corresponding author: Zhong-Yue WANG, zywang@njupt.edu.cn Wei WEI, weiwei@njupt.edu.cn
Received Date: 22 January 2021
Revised Date: 23 April 2021

Figures(6)

Na₃V₂(PO₄)₂O₂F (NVPOF) sodium ion battery cathode materials were prepared by hydrothermal method, and the morphology, structure and electrochemical properties were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and galvanostatic charge/discharge (GCD). The results showed that as-prepared pure phase NVPOF had regular tetraprisms morphology, which was 1~3 μm in length, 300 nm~1 μm in width, and the ratio of length to width was 2~3. NVPOF showed two pairs of stable charging and discharging platforms, the discharge specific capacities of NVPOF were 124.2 and 70.5 mAh·g^-1 at 0.2C and 2C at room temperature, and decreased to 105.8 and 59.6 mAh·g^-1 after 100 cycles, the capacity retention rate were about 85.2% and 84.5% while the Coulombic efficiency was more than 97%. In addition, NVPOF also had good electrochemical performance at low temperature (0 ℃). By coating reduced graphene oxide (rGO) to increase the electrical conductivity, NVPOF@rGO presented high specific discharge capacities of 124.4 and 88.4 mAh·g^-1 at 0.2C and 2C at room temperature. The specific capacity was still 78.7 mAh·g^-1 after 200 cycles at 2C, and the capacity retention rate was as high as 89% while the Coulomb efficiency was always about 99%, showing excellent rate and cycling performance.
- Na₃V₂(PO₄)₂O₂F,
- hydrothermal method,
- sodium ion battery,
- cycle performance
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Hydrothermal Synthesis and Electrochemical Properties of Na₃V₂(PO₄)₂O₂F Cathode for Sodium-Ion Batteries