Citation: Zhi LI, Xiao HUANG, Xiu-Quan GU, Zheng XING, Yu-Long ZHAO, Ying-Huai QIANG. Preparation and Electrochemical Performance of δ-MnO₂/Graphene Aerogels For Li-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1284-1294. doi: 10.11862/CJIC.2021.136 shu

Preparation and Electrochemical Performance of δ-MnO₂/Graphene Aerogels For Li-Ion Batteries

Zhi LI ¹ ,
Xiao HUANG ¹ ,
Xiu-Quan GU ^{1, 2,,} ,
Zheng XING ^{1, 2} ,
Yu-Long ZHAO ^{1, 2} ,
Ying-Huai QIANG ^{1, 2,,}

1.
School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipment, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: Xiu-Quan GU, xqgu@cumt.edu.cn Ying-Huai QIANG, yhqiang@cumt.edu.cn
Received Date: 21 January 2021
Revised Date: 11 May 2021

Figures(10)

In this work, the Li-ion batteries (LIB) made with 3D network structure anodes were fabricated through incorporating ultrathin δ-MnO₂ nanoparticles (NPs) into a reduced graphene oxide aerogel (RGOA), while KMnO₄ was employed as a raw for preparing δ-MnO₂. The influence of MnO₂ adding amounts on the electrochemical performance of the obtained RGOA/δ-MnO₂ composite electrode was investigated. As the MnO₂ adding amount increased, the electrochemical performance of RGOA/δ-MnO₂ was increased firstly and then decreased, reaching a maximum reversible capacity of 1 701.9 mA·g^-1 at a suitable loading amount of MnO₂, which is significantly higher than the theoretical capacity of δ-MnO₂ (1 230 mAh·g^-1). Besides, for the LIBs containing RGOA/δ-MnO₂ anodes, a high capacity of 210.5 mA·g^-1 remained even after 600 discharge-charge cycles at 5 A·g^-1. The excellent performance of RGOA/δ-MnO₂-160 mg can be attributed to the synergistic effect from large specific area and high conductivity of RGOA, as well as high theoretical capacity and small particle size of δ-MnO₂. Furthermore, the 3D framework porous structure provided by RGOA makes it possible to wrap δ-MnO₂ NPs, avoiding the volume expansion of δ-MnO₂ and suppressing the thickening of solid electrolyte interphase (SEI) layer. By calculating the contributions from pseudocapacitance and diffusion-controlled process, it was demonstrated that the charge/discharge mechanism of the RGOA/δ-MnO₂-160 mg anode was dominated by the pseudocapacitance process, which also facilitated achieving good rate performance and cyclic stability.
- graphene,
- aerogels,
- δ-MnO₂,
- pseudocapacitance,
- lithium-ion batteries
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performance of δ-MnO2/Graphene Aerogels For Li-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performance of δ-MnO₂/Graphene Aerogels For Li-Ion Batteries