Citation: Meng-Fan ZHANG, Fang LI, Zhen-Min ZHANG, Wan-Qing ZHOU, Zhen LIU, Chang-Lin YU. Flower-like SnO₂/Sn₃O₄ Microspheres with Heterojunction: Fabrication by Ti⁴⁺-Doping and Photocatalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1227-1236. doi: 10.11862/CJIC.2021.135 shu

Flower-like SnO₂/Sn₃O₄ Microspheres with Heterojunction: Fabrication by Ti⁴⁺-Doping and Photocatalytic Performance

Meng-Fan ZHANG ^{1, 2} ,
Fang LI ¹ ,
Zhen-Min ZHANG ^{1, 2} ,
Wan-Qing ZHOU ¹ ,
Zhen LIU ¹ ,
Chang-Lin YU ^1,,

1.
School of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, China
2.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: Chang-Lin YU, yuchanglinjx@163.com
Received Date: 5 February 2021
Revised Date: 30 April 2021

Figures(12)

The flower-like Sn₃O₄ and x%Ti-SnO₂/Sn₃O₄ (x% was the molar ratio of Ti to Sn) microspheres stacked by the layered nanosheets were prepared by the hydrothermal method. The synthesized samples were analyzed by physical and chemical methods, e. g., X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, infrared spectroscopy, and photocurrent response. The results show that because ion radius of Ti⁴⁺ is similar to Sn⁴⁺, it can enter the Sn₃O₄ lattice instead of Sn⁴⁺ to form alternative dopants. At the same time, the doping of Ti⁴⁺ makes a part of Sn⁴⁺ directly combine with oxygen to form nano-spherical SnO₂ dispersed over the surface of Sn₃O₄, forming a SnO₂/Sn₃O₄ heterojunction. The photocatalytic activity test shows that x%Ti-SnO₂/Sn₃O₄ not only has the ability to reduce Cr⁶⁺, but also has the ability to degrade methyl orange and acid orange Ⅱ. The enhanced catalytic activity is attributed to the surface area and light absorption of x%Ti-SnO₂/Sn₃O₄. Moreover, the produced SnO₂/Sn₃O₄ heterojunction can effectively promote the separation efficiency of photo-generated electrons and holes.
- Ti⁴⁺ doping,
- SnO₂/Sn₃O₄ heterojunction,
- reduction of Cr⁶⁺,
- degradation of dyes
1. [1]
  Guo Q, Wang G X, Kumar A, Pandey R. Nanotechnology, 2017, 28(47): 475708 doi: 10.1088/1361-6528/aa92ab
2. [2]
  Miller S A, Gorai P, Aydemir U, Mason T O, Stevanović V, Toberer E S, Snyder G J. J. Mater. Chem. C, 2017, 5: 8854-8861 doi: 10.1039/C7TC01623A
3. [3]
  Wei Y J, Zheng H, Hu S S, Pu S Z, Peng H Y, Li L, Sheng H P, Zhou S Y, Wang J B, Jia S F. CrystEngComm, 2018, 20: 7114-7119 doi: 10.1039/C8CE01507D
4. [4]
  Matussin S, Harunsani M H, Tan A L, Khan M M. ACS Sustainable Chem. Eng. , 2020, 8(8): 3040-3054 doi: 10.1021/acssuschemeng.9b06398
5. [5]
  Song H, Son S, Kim S K, Jung G Y. Nano Res. , 2015, 8(11): 3553-3561 doi: 10.1007/s12274-015-0855-2
6. [6]
  Liu J Y, Wang C, Yang Q Y, Gao Y, Zhou X, Liang X S, Sun P, Lu G Y. Sens. Actuators B Chem. , 2016, 224: 128-133 doi: 10.1016/j.snb.2015.09.089
7. [7]
  Manikandan M, Tanabe T, Li P, Ueda S, V. Ramesh G, Kodiyath R, Wang J, Hara T, Dakshanamoorthy A, Ishihara S, Ariga K, Ye J, Umezawa N, Abe H. ACS Appl. Mater. Interfaces, 2014, 6(6): 3790-3793 doi: 10.1021/am500157u
8. [8]
  Xu W, Li M, Chen X B, Zhao J H, Tan R Q, Li R, Li J, Song W J. Mater. Lett. , 2014, 120: 140-142 doi: 10.1016/j.matlet.2014.01.075
9. [9]
  Berengue O M, Simon R A, Chiquito A J, Dalmaschio C J, Leite E R, Guerreiro H A, Guimarães F E G. J. Appl. Phys. , 2010, 107(3): 033717-033717 doi: 10.1063/1.3294613
10. [10]
  Ma X H, Shen J L, Hu D X, Sun L, Chen Y, Liu M, Li C N, Ruan S P. J. Alloys Compd. , 2017, 726: 1092-1100 doi: 10.1016/j.jallcom.2017.08.079
11. [11]
  Ji L J, Zhang Y H, Miao S Y, Gong M D, Liu X. Carbon, 2017, 125: 544-550 doi: 10.1016/j.carbon.2017.09.094
12. [12]
  Xia W W, Qian H Y, Zeng X, Dong J, Wang J, Xu Q. J. Phys. Chem. C, 2017, 121(35): 19036-19043 doi: 10.1021/acs.jpcc.7b05520
13. [13]
  Zeng D B, Yu C L, Fan Q Z, Zeng J L, Wei L F, Li Z S, Yang K, Ji H B. Chem. Eng. J. , 2020, 391: 123607 doi: 10.1016/j.cej.2019.123607
14. [14]
  Yu C L, Zeng D B, Fan Q Z, Yang K, Zeng J L, Wei L F, Yi J H, Ji H B. Environ. Sci. : Nano, 2020, 7: 286-303 doi: 10.1039/C9EN00899C
15. [15]
  Niu P, Qiao M, Li Y F, Huang L, Zhai T Y. Nano Energy, 2018, 44: 73-81 doi: 10.1016/j.nanoen.2017.11.059
16. [16]
  Chen X F, Huang Y, Zhang K C, Feng X, Wang M. Electrochim. Acta, 2018, 259: 131-142 doi: 10.1016/j.electacta.2017.10.180
17. [17]
  ZHAI C Y, SUN M J, DU Y K, ZHU M S. J. Inorg. Mater. , 2017, 32(9): 897-903
18. [18]
  Sun M, He Z L, Yuan C, Wang X D, Zhai C Y, Zhu M S. Ind. Eng. Chem. Res. , 2020, 60(1): 762-770
19. [19]
  Wang X D, Gao H F, Zhai C Y, He Z L, Yuan C, Zhu M S. Ind. Eng. Chem. Res. , 2020, 59(43): 19252-19259 doi: 10.1021/acs.iecr.0c03436
20. [20]
  Li C M, Yu S Y, Dong H J, Liu C B, Wu H J, Che H N, Chen G. Appl. Catal. B, 2018, 238: 284-293 doi: 10.1016/j.apcatb.2018.07.049
21. [21]
  Yu X, Zhao Z H, Sun D H, Ren N, Yu J G, Yang R Q, Liu H. Appl. Catal. B, 2018, 227: 470-476 doi: 10.1016/j.apcatb.2018.01.055
22. [22]
  Wang W, Moses O T, Shao Z. Prog. Mater Sci. , 2018, 92: 33-63 doi: 10.1016/j.pmatsci.2017.09.002
23. [23]
  CHEN F Y, ZHANG M D, MA X S, LI J D, YU C L. Chinese J. Inorg. Chem. , 2019, 35(6): 1034-1040
24. [24]
  MA X S, CHEN F Y, YU C L, YANG K, HUANG W Y, LI S Y. Chi-nese J. Inorg. Chem. , 2020, 36(2): 217-225
25. [25]
  HE H B, ZHANG M F, LIU Z, FAN Q Z, YANG K, YU C L. Chinese J. Inorg. Chem. , 2020, 36(8): 1413-1420
26. [26]
  Yao X J, Tang C J, Ji Z Y, Dai Y, Cao Y, Gao F, Dong L, Chen Y. Catal. Sci. Technol, 2013, 3: 688-698 doi: 10.1039/C2CY20610B
27. [27]
  Han C F, Liu Q, Ivey D G. Electrochim. Acta, 2008, 53(28): 8332-8340 doi: 10.1016/j.electacta.2008.06.037
28. [28]
  Tanabe T, Hashimoto M, Mibu K, Tanikawa T, Gunji T, Kaneko S, Abe H, Miyauchi M, Matsumoto F. J. Nanosci. Nanotechnol. , 2017, 17(5): 3454-3459 doi: 10.1166/jnn.2017.13060
29. [29]
  WEI Z R, LUO X P, FU S L, LI Z, HU Z P, GAO P, WANG W W, DONG G Y. Journal of Synthetic Crystals, 2007, 36(6): 1301-1304 doi: 10.3969/j.issn.1000-985X.2007.06.021
30. [30]
  Xiang Q J, Yu J G, Mietek J. J. Phys. Chem. C, 2011, 115(15): 7355-7363 doi: 10.1021/jp200953k
31. [31]
  Liu R Y, Wu Z, Tian J, Yu C L, Li S Y, Yang K, Liu X Q, Liu M C, New J. Chem. , 2018, 42: 137-149
32. [32]
  LIU S X, LIU H. Basic and Application of Photocatalysis and Photocatalysis. Beijing: Chemical Industry Press, 2005: 51-58
33. [33]
  ZHAO J, ZHAO J G, GAO S, HUO L H. The Journal of Light Scattering, 2004, 3: 234-236 doi: 10.3969/j.issn.1004-5929.2004.03.009
34. [34]
  Saranya M, Ramachandran R, Samuel E J J, Jeong S K, Grace A N. Powder Technol. , 2015, 279: 209-220 doi: 10.1016/j.powtec.2015.03.041
35. [35]
  Li C M, Yu S Y, Dong H J, Liu H J, Che H N, Chen G. Appl. Catal. B, 2018, 238: 284-293 doi: 10.1016/j.apcatb.2018.07.049
36. [36]
  Moses P R, Larry M W, John C L, Flnklea H O, Lenhard J R, Murray R W. Anal. Chem. , 1978, 50(4): 576-585 doi: 10.1021/ac50026a010
37. [37]
  Cho S, Ahn C, Park J, Jeon S. Nanoscale, 2018, 10: 9747-9751 doi: 10.1039/C8NR02330A
38. [38]
  Kumar M R, Murugadoss G, Venkatesh N, Sakthivel P. ChemistrySelect, 2020, 5(23): 6946-6953 doi: 10.1002/slct.202001227
39. [39]
  Pearson, Ralph G. Inorg. Chem. , 1988, 27(4): 734-740 doi: 10.1021/ic00277a030
1. [1]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
2. [2]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
3. [3]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
4. [4]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
5. [5]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
6. [6]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
7. [7]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
8. [8]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
9. [9]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
10. [10]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
11. [11]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
12. [12]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
13. [13]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
14. [14]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
15. [15]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
16. [16]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
17. [17]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
18. [18]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
19. [19]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
20. [20]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1009)
HTML views(259)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Flower-like SnO2/Sn3O4 Microspheres with Heterojunction: Fabrication by Ti4+-Doping and Photocatalytic Performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Flower-like SnO₂/Sn₃O₄ Microspheres with Heterojunction: Fabrication by Ti⁴⁺-Doping and Photocatalytic Performance