Citation: Lan MA, Peng-Yuan QI, Lei MA, Shi-Yu DAI, Xiao-Chen XU, Yang LIU. Effect of Different Activation Energies of Crystal Growth on Luminescent Properties and Microstructure of SrZrO₃: Ce[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 968-976. doi: 10.11862/CJIC.2021.123 shu

Effect of Different Activation Energies of Crystal Growth on Luminescent Properties and Microstructure of SrZrO₃: Ce

Lan MA ¹ ,
Peng-Yuan QI ^2,, ,
Lei MA ³ ,
Shi-Yu DAI ² ,
Xiao-Chen XU ² ,
Yang LIU ²

1.
Shenyang Urban Planning & Design Institute Co., Ltd., Shenyang 110004, China
2.
School of Materials Science and Engineering, Yingkou Institute of Technology, Yingkou, Liaoning 115014, China
3.
School of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: Peng-Yuan QI, qipengyuan@126.com
Received Date: 5 August 2020
Revised Date: 16 March 2021

Figures(9)

SrZrO₃: Ce nanoparticles were prepared by reverse coprecipitation method with different precipitants. The phase, morphology, luminescence intensity and sintering densification of the samples were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry-differential thermal analysis (TG-DTA). The thermal analysis kinetics of different precursors were discussed. The results showed that the prismatic and nearly spherical SrZrO₃: Ce particles with good dispersion were obtained by calcining the precursors prepared with single phase and multiphase precipitants at 1 000℃ for 2 h, with the particle sizes of about 80 and 60 nm, respectively. Using Doyle Ozawa integral method and Kissinger differential method, the average apparent activation energies in different reaction stages of precursors prepared with single phase and multiphase precipitants were 94.18, 69.39, 255.72 kJ·mol^-1 and 90.46, 51.03, 232.35 kJ·mol^-1, respectively. The activation energies of crystal growth: E_{single phase}=27.97 kJ·mol^-1 and E_multiphase=22.53 kJ·mol^-1, respectively. The apparent activation energy and grain growth activation energy of the latter were lower than those of the former, which indicates that the sample prepared with multiphase precipitant reduces the synthesis energy and improves the particle activity, and its luminous intensity was obviously better than that of the sample prepared with single phase precipitant. After vacuum sintering at 1 760℃ for 4 h, the sample prepared with multiphase precipitant had uniform grain size and achieved densification.
- coprecipitation method,
- SrZrO₃: Ce particles,
- synthesis kinetics,
- activation energy,
- luminescent properties,
- microstructure
1. [1]
  Manish K M, Vikas D, Mishra P M, Isharat K. Mater. Today: Proc. , 2019, 18(7): 4392-4397
2. [2]
  Perumal R N, Athikesavan V. J. Mater. Sci. : Mater. Electron. , 2020, 31(5): 4092-4105 doi: 10.1007/s10854-020-02956-0
3. [3]
  Cheng K M, Xu H X, Zhang L J, Du Y, Zhou J X, Tang S Q, Chen M. J. Electron. Mater. , 2019, 48(9): 5510-5515 doi: 10.1007/s11664-019-07236-0
4. [4]
  Rai D P, Sandeep, Shankar A, Sakhya A P, Sinha T P, Merabet B, Musa S H M, Henata R K, Boochani A, Solaymani S. Mater. Chem. Phys. , 2017, 186: 620-626 doi: 10.1016/j.matchemphys.2016.11.045
5. [5]
  Fukushima H, Nakauchi D, Kawaguchi N, Yannagida T. Sens. Mater. , 2019, 31(4): 1273-1280
6. [6]
  Gu S, Zhang S, Jia Y, Li W, Yan J. J. Alloys Compd. , 2017, 728: 10-18 doi: 10.1016/j.jallcom.2017.08.279
7. [7]
  Chou J T, Inoue Y, Kawabata T, Matsuda J, Sasaki K. J. Electrochem. Soc. , 2018, 165(11): 959-965 doi: 10.1149/2.0551811jes
8. [8]
  Leonard K, Okuyama Y, Takamura Y, Lee Y S, Miyazaki K, Ivanova M, Meulenberg W, Matsumoto H. J. Mater. Chem. A, 2018, 6: 19113 doi: 10.1039/C8TA04019B
9. [9]
  Venugopal M, Kumar H P, Jayakrishnan R. J. Electroceram. , 2020, 44: 163-172 doi: 10.1007/s10832-020-00207-6
10. [10]
  Liu C Y, Tseung Y T. J. Phys. D: Appl. Phys. , 2007, 40(7): 2157-2161 doi: 10.1088/0022-3727/40/7/045
11. [11]
  Aminzare M, Amoozegar Z, Sadrnezhaad S K. Mater. Res. Bull. , 2012, 47(11): 3586-3591 doi: 10.1016/j.materresbull.2012.06.060
12. [12]
  QIU Y P, ZHANG X W, HAN G R. Rare Metal Materials and Engineering, 2006, 35(2): 190-193
13. [13]
  Laloue N, Couenne F, Gorrec Y L, Kohl M, Tanguy D, Tayakout M. Chem. Eng. Sci. , 2007, 62(23): 6604-6614 doi: 10.1016/j.ces.2007.07.039
14. [14]
  Ji Y M, Jiang D Y, Wu Z H, Fen T, Shi J L. Mater. Res. Bull. , 2005, 40(9): 1521-1526 doi: 10.1016/j.materresbull.2005.04.026
15. [15]
  Loef E V V, Wang Y, Miller S R, Brecher C, Rhodes W H, Baldoni G, Topping S, Lingertat H, Sarin V K, Shah K S. Opt. Mater. , 2010, 33(1): 84-90 doi: 10.1016/j.optmat.2010.08.013
16. [16]
  Tadao S. Monodispersed P. Monodispersed Particle. Japan: Tohoku University, 2000: 75-82
17. [17]
  Shi Y, Chen J Y, Shi J L. Mater. Sci. Forum, 2005, 492: 101-108
18. [18]
  Zoraga M, Kahruman C, Yusufoglu I. Hydrometallurgy, 2016, 163: 120-129 doi: 10.1016/j.hydromet.2016.03.021
19. [19]
  Tong Y P, Zhao S B, Feng W F. J. Alloys Compd. , 2013, 550: 268-272 doi: 10.1016/j.jallcom.2012.09.004
20. [20]
  Tiwari N, Kuraria R K, Kuraria S R, Tamrakar R K. J. Radiat. Res. Appl. Sci. , 2015, 8(1): 68-76 doi: 10.1016/j.jrras.2014.11.002
21. [21]
  Gillani S S A, Ahmad R, Zeba I, Islah U D, Siddique M. Philos. Mag. , 2019, 23: 1-13
22. [22]
  Zhang J, Wang W Z, Wang T L, Jiang L L, Wang N, Sun D, Zhao X M, Wang M G, Qi Y. J. Alloys Compd. , 2020, 858: 157650
23. [23]
  Farooq U, Naz F, Phul R, Pandit N A, Jain S K, Ahmad T. J. Nanosci. Nanotechnol. , 2020, 20(6): 3770-3779 doi: 10.1166/jnn.2020.17516
24. [24]
  Lim H, Lim J, Jang S, Lee Y S. J. Adv. Ceram. , 2020, 9(4): 413-423 doi: 10.1007/s40145-020-0381-x
25. [25]
  Hsu Y W, Yang K H, Yeh S W, Wang M C. J. Alloys Compd. , 2013, 555(5): 82-87
1. [1]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
2. [2]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
3. [3]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
4. [4]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
5. [5]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
6. [6]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
7. [7]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
8. [8]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
9. [9]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
10. [10]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
11. [11]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
12. [12]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
13. [13]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
14. [14]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
15. [15]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
16. [16]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
17. [17]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
18. [18]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, 2024, 39(11): 384-387. doi: 10.12461/PKU.DXHX202402039
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(596)
HTML views(92)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Different Activation Energies of Crystal Growth on Luminescent Properties and Microstructure of SrZrO3: Ce

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Different Activation Energies of Crystal Growth on Luminescent Properties and Microstructure of SrZrO₃: Ce