Citation: Ya-Feng BAI, Zi-Heng YANG, Yong FENG, Fu-Liang LIU, Xiao-Tao CHEN, Ji-Ying CHANG. Preparation and Electrocatalytic Performance of Zn/N Co-doped Carbon Catalyst Derived from MOF[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1055-1061. doi: 10.11862/CJIC.2021.122 shu

Preparation and Electrocatalytic Performance of Zn/N Co-doped Carbon Catalyst Derived from MOF

Ya-Feng BAI ^{1, 2,,} ,
Zi-Heng YANG ^{1, 2} ,
Yong FENG ^{1, 2} ,
Fu-Liang LIU ^{1, 2} ,
Xiao-Tao CHEN ^{1, 2} ,
Ji-Ying CHANG ^{1, 2}

1.
Guizhou Meiling Power Source Co. Ltd., Zunyi, Guizhou 563003, China
2.
State Key Laboratory of Advanced Chemical Power Sources, Zunyi, Guizhou 563003, China

Corresponding author: Ya-Feng BAI, gzmlbyf@163.com
Received Date: 13 January 2021
Revised Date: 14 April 2021

Figures(6)

In order to solve the high cost of fuel cell Pt-based catalysts, nitrogen-doped carbon non-noble metal oxygen reduction reaction (ORR) catalysts have been widely studied. The amorphous Zn(Ⅱ)-organic framework was prepared by solvothermal method and the Zn/N co-doped carbon catalyst was obtained by thermally processing. The results showed that the ZnN/C-900 catalyst (pyrolyzed at 900℃) had a uniform spherical structure. The N₂ adsorption-desorption isotherms of ZnN/C-900 catalyst showed that it had a specific surface area of up to 961 m² g^-1, and the atomic percentages of active N and Zn were 1.6% and 5.87%. The catalyst had high ORR catalytic activity and stability. In alkaline medium, the initial potential, half-wave potential and limiting current density of ZnN/C-900 were 0.955 V, 0.855 V and 7.10 mA·cm^-2, respectively. In acid medium, the initial potential, half-wave potential and limiting current density of ZnN/C-900 were 0.882 V, 0.649 V and 6.01 mA·cm^-2, respectively. ZnN/C-900 exhibited high stability and resistance to methanol poisoning.
- fuel cell,
- oxygen reduction reaction catalyst,
- metal organic framework,
- Zn/N co-doping,
- carbon sphere
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沈阳化工大学材料科学与工程学院沈阳 110142