Citation: Yu-Fang ZHANG, Pei ZHANG, Jian-Hua GAO. Synthesis, Crystal Structure and Electrochemical Properties of NASICON-Type Na₄FeV(PO₄)₃[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1301-1306. doi: 10.11862/CJIC.2021.119 shu

Synthesis, Crystal Structure and Electrochemical Properties of NASICON-Type Na₄FeV(PO₄)₃

School of Physics, Northwest University, Xi'an 710069, China

Corresponding author: Jian-Hua GAO, gaojh@nwu.edu.cn
Received Date: 14 January 2021
Revised Date: 14 April 2021

Figures(6)

Herein, the NASICON-type Na₄FeV(PO₄)₃ single crystal was successfully synthesized by high temperature molten salt method. The analysis of single crystal X-ray diffraction data shows that Na₄FeV(PO₄)₃ crystallizes in hexagonal R3c space group with a=b=0.878 17(4) nm, c=2.17 01(2) nm, Z=6 and V=1.449 31(18) nm³. The crystal structure of this phosphate belongs to the typical NASICON structure, which is built up from corner-sharing PO₄ tetrahedra and Fe/VO₆ octahedra, providing a three-dimensional Na⁺ transmission channel with two different types of Na⁺ located in the gap of the frame. Additionally, the electrochemical tests of the as-synthesized Na₄FeV(PO₄)₃/C as cathode material of sodium-ion battery showed a high capacity. CCDC: 2048805.
- NASICON,
- crystal structure,
- sodium-ion battery
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Synthesis, Crystal Structure and Electrochemical Properties of NASICON-Type Na₄FeV(PO₄)₃