Citation: Dong-Xu JIA, Xiang-Xiang HUANG, Chun-Kui HU, Ling-Yan FEI, Lang-Lang YOU, Chun-Xin Lü, Wei ZHONG. Synthesis of Magnetic Fe₃O₄-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1080-1088. doi: 10.11862/CJIC.2021.117 shu

Synthesis of Magnetic Fe₃O₄-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)

1.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
2.
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Beijing 100190, China

Corresponding author: Chun-Xin Lü, chunxin.lu@mail.zjxu.edu.cn Wei ZHONG, weizhong@mail.zjxu.edu.cn
Received Date: 27 January 2021
Revised Date: 6 April 2021

Figures(10)

The magnetic Fe₃O₄-supported Schiff base adsorption material was synthesized via the reaction with activated silica gel silane and salicylaldehyde or its derivatives by homogeneous method and heterogeneous method, respectively. The prepared materials were fully characterized by infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and so on. The adsorption performance of these materials on Cu(Ⅱ), Pb (Ⅱ) and Cd(Ⅱ) in water was studied at 30℃. The effects of synthesis method, pH value, ion concentration and material structures on the adsorption properties were examined. Finally, the regeneration property of the adsorbent was evaluated. The results showed that the obtained materials exhibited good adsorption performance for Cu (Ⅱ), Pb(Ⅱ) and Cd(Ⅱ) ions, and the adsorption capacity increased with the increase of pH value in the range of 1~6. The adsorption capacity of the adsorbents obtained by heterogeneous method was better than those of homogeneous method. In addition, the materials bearing electron-donating groups on the Schiff base showed better adsorption properties. This type of adsorbent exhibited good regeneration property with 89.4% regeneration rate after 4 cycles.
- magnetic material,
- Schiff base,
- regeneration,
- heavy metal ions,
- adsorption
1. [1]
  GUO M, HUANG F Q, LIU M M, LI M H. Chinese J. Inorg. Chem. , 2013, 29(5): 1037-1044
2. [2]
  Wang Y Y, Liu Y X, Lu H H, Yang R Q, Yang S M. J. Solid State Chem. , 2018, 261: 53-61 doi: 10.1016/j.jssc.2018.02.010
3. [3]
  Surgutskaia N S, Martino A D, Zednik J, Ozaltin K, Lovecká L, Bergerová E D, Kimmer D, Svoboda J, Sedlarik V. Sep. Purif. Technol. , 2020, 247: 116914 doi: 10.1016/j.seppur.2020.116914
4. [4]
  FAN X J, LI J, WANG R F, YUN L Q, LI X, DENG L G. Applied Chemical Industry, 2020, 49(11): 2912-2915 doi: 10.3969/j.issn.1671-3206.2020.11.051
5. [5]
  Song X T, Niu Y Z, Zhang P P, Zhang C Y, Zhang Z, Zhu Y, Qu R J. Fuel, 2017, 199: 91-101 doi: 10.1016/j.fuel.2017.02.076
6. [6]
  Ma L F, Zhang X Y, Ikram M, Ullah M, Wu H Y, Shi K Y. Chem. Eng. J. , 2020, 395: 125216 doi: 10.1016/j.cej.2020.125216
7. [7]
  Song Y, Lei S, Zhou J, Tian Y H. J. Chem. Technol. Biotechnol. , 2016, 91(9): 2539-2544 doi: 10.1002/jctb.4859
8. [8]
  ZHANG T, MA S J, PAN Y, GUAN J B, ZHANG M, ZHU H, DU M L. Chinese J. Inorg. Chem. , 2019, 35(4): 674-686
9. [9]
  WANG J L, CHEN C. Acta Scientiae Circumstantiae, 2010, 30(4): 673-701
10. [10]
  ZOU X Y, ZHAO Y B, ZHANG Z J. Chinese J. Inorg. Chem. , 2020, 36(4): 747-754
11. [11]
  Song X T, Niu Y Z, Qiu Z M, Zhang Z X, Zhou Y Z, Zhao J J, Chen H. Fuel, 2017, 206: 80-88 doi: 10.1016/j.fuel.2017.05.086
12. [12]
  Liu Y, Fu R Q, Sun Y, Zhou X X, Baig S A, Xu X H. Appl. Surf. Sci. , 2016, 369: 267-276 doi: 10.1016/j.apsusc.2016.02.043
13. [13]
  LIU J, ZHANG W M, WU Z S, QIN L H, SUN R G, SUN Z X. Chinese J. Inorg. Chem. , 2010, 26(11): 1967-1974
14. [14]
  DUAN Z Y, LIU S L, XU X J, XIE D L, HE C H, WANG Y. Chem. Ind. End. Prog. , 2017, 36(5): 1791-1801
15. [15]
  Xu J S, Zhu Y J. J. Colloid Interface Sci. , 2012, 385(1): 58-65 doi: 10.1016/j.jcis.2012.06.082
16. [16]
  Wang J H, Zheng S R, Shao Y, Liu J L, Xu Z Y, Zhu D Q. J. Colloid Interface Sci. , 2010, 349: 293-299 doi: 10.1016/j.jcis.2010.05.010
17. [17]
  Zhou Y Z, Luan L P, Tang B T, Niu Y Z, Qu R J, Liu Y, Xu W L. Chem. Eng. J. , 2020, 398: 125651 doi: 10.1016/j.cej.2020.125651
18. [18]
  GUAN X H, QING Y C, WANG L W, YIN R, LU M, YANG Y J. En-vironmental Science, 2007, 28(2): 436-440
19. [19]
  Cheng M, Wang Z K, Qiang L, Li C L, Sun S Q, Hu S Q. J. Hazard. Mater. , 2018, 341: 198-206 doi: 10.1016/j.jhazmat.2017.07.062
20. [20]
  Zhao D L, Gao X, Wu C N, Xie R, Feng S J, Chen C L. Appl. Surf. Sci. , 2016, 384(5): 1-9
21. [21]
  Habila M A, Alothman Z A, El-Toni A M, Al-Tamrah S A, Soylak M, Labis J P. Microchim. Acta, 2017, 184: 2645-2651 doi: 10.1007/s00604-017-2283-3
22. [22]
  Niu Y Z, Qu R J, Chen H, Lei M, Liu X G, Zhang Y, Sun C M. J. Hazard. Mater. , 2014, 278(6): 267-278
23. [23]
  Masjedi A, Askarizadeh E, Baniyaghoob S. Mater. Chem. Phys. , 2020, 249: 122917 doi: 10.1016/j.matchemphys.2020.122917
24. [24]
  Monier M, Abdel-Latif D A, El-Reash Y G. J. Colloid Interface Sci. , 2016, 469: 344-354 doi: 10.1016/j.jcis.2016.01.074
25. [25]
  Awual M R, Eldesoky G E, Yaita T, Naushad M, Shiwaku H, AlOthman Z A, Suzuki S. Chem. Eng. J. , 2015, 279: 639-647 doi: 10.1016/j.cej.2015.05.049
26. [26]
  Moradinasab S, Behzad M. Desalin. Water Treat. , 2016, 57(9): 4028-4036 doi: 10.1080/19443994.2014.991760
27. [27]
  Zhao J J, Niu Y Z, Ren B, Chen H, Zhang S X, Jin J, Zhang Y. Chem. Eng. J. , 2018, 347: 574-584 doi: 10.1016/j.cej.2018.04.151
28. [28]
  Zhao J J, Luan L P, Li Z W, Duan Z F, Li Y F, Zheng S B, Xue Z X, Xu W L, Niu Y Z. J. Alloys Compd. , 2020, 825: 154051 doi: 10.1016/j.jallcom.2020.154051
29. [29]
  Setoodehkhah M, Momeni S. J. Inorg. Organomet. Polym. Mater. , 2018, 28: 1098-1106 doi: 10.1007/s10904-017-0770-y
30. [30]
  Fan S, Dong X B, Gao H Y, Wang J J, Jin Z K, Tang J, Wang G. ACS Catal. , 2017, 7(1): 243-249 doi: 10.1021/acscatal.6b02614
31. [31]
  JIANG Y Z, ZHAO G C, SHI Y Q, XU H Y. Acta Scientiae Circumstantiae, 2016, 36(3): 893-899
32. [32]
  Guo S Z, Jiao P P, Dan Z G, Duan N, Chen G Y, Zhang J. Chem. Eng. J. , 2017, 317: 999-1011 doi: 10.1016/j.cej.2017.02.136
33. [33]
  Niu Y Z, Qu R J, Sun C M, Wang C H, Chen H, Ji C N, Zhang Y, Shao X, Bu F L. J. Hazard. Mater. , 2013, 244-245: 276-286 doi: 10.1016/j.jhazmat.2012.11.042
1. [1]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
5. [5]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
6. [6]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
7. [7]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
8. [8]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
9. [9]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
10. [10]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
11. [11]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
12. [12]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
13. [13]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
14. [14]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
15. [15]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
16. [16]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
17. [17]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
18. [18]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
19. [19]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
20. [20]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(591)
HTML views(120)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Magnetic Fe3O4-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Magnetic Fe₃O₄-Supported Schiff Base Materials and Adsorption Properties of Cu(Ⅱ), Pb(Ⅱ) and Cd(Ⅱ)