Citation: Wei PAN, Chi-Xiao MA, Chuan-Jiang ZHOU, Lu ZHANG, Jun-Yong ZHANG, Yan-Bo SHI, Hao XU, Dun-Ru ZHU, Jing-Li XIE. Synthesis and Characterization of Metal-Organic Framework Based on 2, 6-Bis(4-carboxybenzylidene)cyclohexanone[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 953-960. doi: 10.11862/CJIC.2021.106 shu

Synthesis and Characterization of Metal-Organic Framework Based on 2, 6-Bis(4-carboxybenzylidene)cyclohexanone

Wei PAN ^{1, 2} ,
Chi-Xiao MA ^{1, 2} ,
Chuan-Jiang ZHOU ¹ ,
Lu ZHANG ¹ ,
Jun-Yong ZHANG ^1,, ,
Yan-Bo SHI ^3,, ,
Hao XU ¹ ,
Dun-Ru ZHU ^2,, ,
Jing-Li XIE ^{1, 4,,}

1.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
2.
College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
3.
Central Laboratory of Jiaxing Traditional Chinese Medicine Hospital, Jiaxing Key Laboratory of Diabetic Angiopathy Research, Jiaxing, Zhejiang 314000, China
4.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: Jun-Yong ZHANG, zhangjy@mail.zjxu.edu.cn Yan-Bo SHI, shiyanbocas@163.com Dun-Ru ZHU, zhudr@njtech.edu.cn Jing-Li XIE, jlxie@mail.zjxu.edu.cn
Received Date: 7 December 2020
Revised Date: 21 January 2021

Figures(9)

By virtue of 2, 6-bis(4-carboxybenzylidene)cyclohexanone (H₂L) as the ligand, metal-organic framework [MnL]_n has been successfully fabricated. This compound has been characterized by FT-IR, powder X-ray diffraction, cyclic voltammogram, solid UV, X-ray photoelectron spectroscopy and single-crystal X-ray diffraction. It crystalizes in triclinic system with space group P1, and the asymmetric unit is composed of one Mn(Ⅱ) ion and one ligand. The carboxyl groups at both ends of the ligand are monodentate coordination, and the oxygen on the carbonyl group in the middle of the ligand coordinate with the central ion as well. Each ligand is coordinated with three Mn(Ⅱ) ions and consequently, achieving a relatively stable triangular coordination configuration. The Mn (Ⅱ) ion forms a six-coordinated configuration with oxygen atoms from six different ligands, i. e., those four O atoms in the equatorial plane derived from four different ligands' carboxyl groups, the other two O atoms on the two vertices from the different ligands' carbonyl groups, respectively. As a consequence, the octahedral configuration[MnO₆] unit is formed. Based on the topological analysis, its two-dimensional (2D) kgd structural character could be observed. The cyclic voltammogram showed that the half-wave potential, E_1/2=(E_cp+E_ap)/2, was 171 mV when the sweep speed was 30 mV·s^-1. The solid UV absorption spectra showed the band gap was ~1.76 eV. Photocatalytic activity has been observed in the process of degrading of dye molecules such as methylene blue and methyl orange. CCDC: 2045728.
- 2, 6-bis(4-carboxybenzylidene)cyclohexanone,
- manganese compound,
- crystal structure,
- topology structure
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