Citation: Xiao-Xiang LU, Tian-Bao LI, Fei-Yue TU, Zhong-Liang LI, Xu-Kun ZHU, Can SUN, Ya-Chao JIN, Li SONG, Ming-Dao ZHANG, Hui CAO. Scale-Up Strategy to Develop Highly-Effective Co-N-C@KB Composites as Sulfur Host for Lithium-Sulfur Battery[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1125-1134. doi: 10.11862/CJIC.2021.105 shu

Scale-Up Strategy to Develop Highly-Effective Co-N-C@KB Composites as Sulfur Host for Lithium-Sulfur Battery

Xiao-Xiang LU ¹ ,
Tian-Bao LI ² ,
Fei-Yue TU ² ,
Zhong-Liang LI ² ,
Xu-Kun ZHU ¹ ,
Can SUN ¹ ,
Ya-Chao JIN ¹ ,
Li SONG ^1,, ,
Ming-Dao ZHANG ^1,, ,
Hui CAO ^1,,

1.
School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing 210044, China
2.
Changsha Research Institute of Mining and Metallurgy Co. Ltd, Changsha 410012, China

Corresponding author: Li SONG, songli@nuist.edu.cn Ming-Dao ZHANG, matchlessjimmy@163.com Hui CAO, jinyachao@nuist.edu.cn
Received Date: 17 January 2021
Revised Date: 20 March 2021

Figures(5)

The commercialization process of Li-S battery is seriously impeded by the poor performance of sulfur cathode, including the low conductivity and dissatisfactory activity for facilitating the polysulfide conversion. In this work, we developed a scale-up method to synthesize an efficient cathode material (Co-N-C@KB) with abundant Co-N-C active sites on the Ketjen Black (KB), through a ligand-mediated-synthesis and a low-temperature-pyrolysis strategy. The uniformly distributed Co-N-C active sites were proved to be favorable for the conversion of polysulfide at the cathode, hence improving the capacity and cyclic life of Li-S battery. As a result, the Co-N-C@KB cathode for the Li-S battery could deliver an initial discharge specific capacity as high as 1 442 mAh·g^-1, and have the excellent capability for capacity retention during the long-term stability test.
- Li-S battery,
- atomically dispersed catalyst,
- carbon materials,
- sulfur host,
- adsorption
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