Citation: Jin-Jian LIU, Na LIU, Yi-Wei LU, Guo-Zheng ZHAO. Three Photochromic Co-crystals Based on Viologen Moiety[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 937-944. doi: 10.11862/CJIC.2021.100 shu

Three Photochromic Co-crystals Based on Viologen Moiety

Jin-Jian LIU ^{1, 2,,} ,
Na LIU ² ,
Yi-Wei LU ² ,
Guo-Zheng ZHAO ²

1.
Modern College of Humanities and Science, Shanxi Normal University, Linfen, Shanxi 041000, China
2.
School of Chemistry and Material Science, Shanxi Normal University, Linfen, Shanxi 041004, China

Corresponding author: Jin-Jian LIU, liujj@sxnu.edu.cn
Received Date: 25 November 2020
Revised Date: 5 January 2021

Figures(4)

The reactions of 1, 2, 4, 5-benzenetetracarboxylic acid (H₄BTEC) with the transition metal ions in the presence of neutral viologen moiety, 1-carboxyethyl-4, 4'-bipyridine (CEbpy), led to three isostructural co-crystals[M(H₂O)₅(BTEC)_0.5]·(CEbpy) (M=Mn (1), Zn (2), Co (3)) in an alkaline environment. Upon UV irradiation, these three compounds exhibited obvious photochromic behaviors owing to the formation of viologen radicals through photo-induced electron transfer. Meanwhile, compound 3 exhibited irreversible hydrochromic behavior upon heating, while compounds 1 and 2 did not. The influence of metal ions on their chromic behaviors has been discussed. CCDC: 1953749, 1; 1954911, 2; 2032783, 3.
- 1-carboxyethyl-4, 4'-bipyridine (CEbpy),
- co-crystals,
- photochromism,
- hydrochromism
1. [1]
  (a) Shi H Y, Lu X C, Liu Y H, Song J, Deng K, Zeng Q D, Wang C. ACS Nano, 2018, 12: 8781-8790
  (b) Gao H Y, Shen Q J, Zhao X R, Yan X Q, Pang X, Jin W J. J. Mater. Chem., 2012, 22: 5336-5343
  (c) Wang Y, Zhu W G, Du W N, Liu X F, Zhang X T, Dong H L, Hu W P. Angew. Chem. Int. Ed., 2018, 57: 3963-3967
2. [2]
  (a) Ji L, Yang Z, Zhao Y, Sun M, Cao L, Yang X J, Wang Y Y, Wu B. Chem. Commun., 2016, 52: 7310-7313
  (b) Zhao J, Yang D, Zhao Y, Yang X J, Wang Y Y, Wu B. Angew. Chem. Int. Ed., 2014, 53: 6632-6636
3. [3]
  (a) Zhang J, Liu G F, Zhou Y C, Long G K, Gu P Y, Zhang Q C. ACS Appl. Mater. Interfaces, 2017, 9: 1183-1188
  (b) Zhang J, Gu P Y, Long G K, Ganguly R, Li Y X, Zhang Q C. Chem. Sci., 2016, 7: 3851-3856
4. [4]
  (a) Wang L, Zhao L, Xue R Y, Lu X F, Wen Y H, Yang Y. Sci. China Chem., 2012, 55: 2515-2522
  (b) Kobatake S, Takami S, Muto H, Ishikawa T, Irie M. Nature, 2007, 446: 778-781
  (c) Li S Z, Yan D P. Sci. China Chem., 2018, 61: 215-221
5. [5]
  (a) Hao P F, Wang W P, Zhang L F, Shen J J, Fu Y L. Inorg. Chem. Front., 2019, 6: 287-292
  (b) Zhu M Q, Zhu L, Han J J, Wu W, Hurst J K, Li A D Q. J. Am. Chem. Soc., 2006, 12: 4303-4309
  (c) Lin F Y, Morokuma K. J. Am. Chem. Soc., 2013, 135: 10693-10702
6. [6]
  (a) Li S, Jia C, Wu B, Luo Q, Huang X, Yang Z, Li Q S, Yang X J. Angew. Chem. Int. Ed., 2011, 50: 5721-5724
  (b) Wu B, Cui F, Lei Y, Li S, Amadeu N S, Janiak C, Lin Y J, Weng L H, Wang Y Y, Yang X J. Angew. Chem. Int. Ed., 2013, 5: 5096-5100
  (c) Yang D, Zhao J, Yu L, Lin X, Zhang W, Ma H, Gogoll A, Zhang Z, Wang Y, Yang X J, Wu B. J. Am. Chem. Soc., 2017, 13: 5946-5951
7. [7]
  (a) Sun J K, Wang P, Yao Q X, Chen Y J, Li Z H, Zhang Y F, Wu L M, Zhang J. J. Mater. Chem., 2012, 22: 12212-12219
  (b) Sui Q, Yuan Y, Yang N N, Li X, Gong T, Gao E Q. J. Mater. Chem. C, 2017, 5: 1240-12408
  (c) Bockman T M, Kochi J K. J. Org. Chem., 1990, 55: 4127-4135
  (d) Yang X, Zhang Y, Zhang B, Zhang S, Liu X, Li G, Chu D, Zhao Y, He G. J. Mater. Chem. C, 2020, 8: 126326-16332
  (e) Li G, Xu L, Zhang W, Zhou K, Ding Y, Liu F, He X, He G. Angew. Chem. Int. Ed., 2018, 57: 4897-4901
8. [8]
  (a) Zhang Q W, Sun H Q, Wang X S, Hao X H, An S L. ACS Appl. Mater. Interfaces, 2015, 7: 25289-25297
  (b) Leblanc N, Bi W H, Mercier N, Auban-Senzier P, Pasquier C. Inorg. Chem., 2010, 49: 5824-5833
  (c) Chen H J, Li M, Zheng G M, Wang Y F, Song Y, Han C H, Fu Z Y, Liao S J, Dai J C. RSC Adv., 2014, 4: 42983-42990
9. [9]
  (a) Liu J J, Li J, Lu W B. Dyes Pigm., 2020, 172: 107792
  (b) Liu J J, Li J, Lu Y W, Lu W B. Dyes Pigm., 2020, 177: 108266
  (c) Liu J J, Lu Y W, Lu W B. Dalton Trans., 2020, 49: 4044-4049
10. [10]
  (a) Shi Q, Wu S Y, Qiu X T, Sun Y Q, Zheng S T. Dalton Trans., 2019, 48: 954-963
  (b) Qiu X T, Shi Q, Zhang D Q, Lin Q F, Sun Y Q. ChemstrySelect, 2018, 3: 6611-6616
  (c) Li P X, Wang M S, Cai L Z, Wang G E, Guo G C. J. Mater. Chem. C, 2015, 3: 253-256
11. [11]
  Phillips A D, Fei Z, Ang W H, Scopelliti R, Dyson P J. Cryst. Growth Des. , 2009, 9: 1966-1978 doi: 10.1021/cg801285u
12. [12]
  CrysAlisPro, Ver. 1.171.33.56, Oxford diffraction Ltd., Oxfordshire, UK, 2010.
13. [13]
  (a) Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64: 112-122
  (b) Sheldrick G M. SHELX 97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
14. [14]
  (a) Yao Q X, Pan L, Jin X H, Li J, Li J, Ju Z F, Zhang J. Chem. Eur. J., 2009, 15: 11890-11897
  (b) Li W B, Yao Q W, Sun L, Yang X D, Guo R Y, Zhang J. CrystEngComm, 2017, 19: 722-726
15. [15]
  (a) Wan F, Qiu L X, Zhou L L, Sun Y Q, You Y. Dalton Trans., 2015, 44: 18320-18323
  (b) Ni A Y, Mu Y, Pan J, Han S D, Shang M M, Wang G M. Chem. Commun., 2018, 54: 3712-3714
16. [16]
  (a) Gong T, Yang X, Fang J J, Sui Q, Xi, F G, Gao E Q. ACS Appl. Mater. Interfaces, 2017, 9: 5503-5512
  (b) Zhang C H, Sun L B, Yan Y, Shi H Z, Wang B L, Liang Z Q. J. Mater. Chem. C, 2017, 5: 8999-9004
17. [17]
  (a) Song Y M, Luo F, Luo M B, Liao Z W, Sun G W, Tian X Z, Zhu Y, Yuan Z J, Liu S J, Xu, W Y, Feng X F. Chem. Commun., 2012, 4: 1006-1008
  (b) Zhou H, Qin L, Wu M K, Han L. Cryst. Growth Des., 2018, 18: 5738-5744
  (c) Sui Q, Yang N N, Gong T, Li P, Yuan Y, Gao E Q, Wang L. J. Phys. Chem. Lett., 2017, 8: 5450-5455
18. [18]
  (a) Liu J J, Guan Y F, Lin M J, Huang C C, Dai W X. Cryst. Growth Des., 2016, 16: 2836-2842
  (b) Li S L, Han M, Wu B, Wang J, Zhang X M. Cryst. Growth Des., 2018, 18: 3883-3889
19. [19]
  (a) Yang X D, Chen C, Zhang Y J, Cai L X, Tan B, Zhang J. Dalton Trans., 2016, 45: 4522-4527
  (b) Jin X H, Sun J K, Xu X M, Li Z H, Zhang J. Chem. Commun., 2010, 46: 4695-4697
20. [20]
  (a) Toma O, Mercier N, Allain M, Kassiba A A, Bellat J P, Weber G, Bezverkhyy I. Inorg. Chem., 2015, 54: 8923-8930
  (b) Wang J, Li S L, Zhang X M. ACS Appl. Mater. Interfaces, 2016, 8: 24862-24869
  (c) Aulakh D, Varghese J R, Wriedt M. Inorg. Chem., 2015, 54: 1756-1764
21. [21]
  (a) Wang H Y, Liu S, Fu C, Zhang H. CrystEngComm, 2019, 21: 1635-1641
  (b) Ma Y J, Hu J X, Han S D, Pan J, Li J H, Wang G M. J. Am. Chem. Soc., 2020, 142: 2682-2689
22. [22]
  Sun Y N, Li L, Fu C, Wang H Y, Zhang H. Inorg. Chem. Commun. , 2018, 96: 119-123 doi: 10.1016/j.inoche.2018.08.006
23. [23]
  FENG Y B, ZHANG F B, XUAN L H, ZHU Y Y. Journal of Dalian Institute of Light Industry, 1998, 17(2): 70-76
24. [24]
  (a) Zheng T, Clemente-Juan J M, Ma J, Dong L, Bao S S, Huang J, Coronado E, Zheng L M. Chem. Eur. J., 2013, 19: 16394-16402
  (b) Yang X D, Zhu R, Yin J P, Sun L, Guo R Y, Zhang J. Cryst. Growth Des., 2018, 18: 3236-3243
25. [25]
  Uemura K, kitagawa S, Kondo M, Fukui K, Kitaura R, Chang H C. Chem. Eur. J. , 2020, 8: 3586-3600
26. [26]
  (a) Bommakanti S, Das S K. Front. Mater., 2019, 6: 170
  (b) Liu J J. Dyes Pigm., 2018, 154: 92-99
1. [1]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
2. [2]
  Yong-Fang Shi , Sheng-Hua Zhou , Zuju Ma , Xin-Tao Wu , Hua Lin , Qi-Long Zhu . From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation. Chinese Journal of Structural Chemistry, 2025, 44(1): 100455-100455. doi: 10.1016/j.cjsc.2024.100455
3. [3]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
4. [4]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
5. [5]
  Xiangyu Chen , Aihao Xu , Dong Wei , Fang Huang , Junjie Ma , Huibing He , Jing Xu . Atomic cerium-doped CuO_x catalysts for efficient electrocatalytic CO₂ reduction to CH₄. Chinese Chemical Letters, 2025, 36(1): 110175-. doi: 10.1016/j.cclet.2024.110175
6. [6]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
7. [7]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
8. [8]
  Longsheng Zhan , Yuchao Wang , Mengjie Liu , Xin Zhao , Danni Deng , Xinran Zheng , Jiabi Jiang , Xiang Xiong , Yongpeng Lei . BiVO₄ as a precatalyst for CO₂ electroreduction to formate at large current density. Chinese Chemical Letters, 2025, 36(3): 109695-. doi: 10.1016/j.cclet.2024.109695
9. [9]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
10. [10]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
11. [11]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
12. [12]
  Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM₂@g-C₉N₄ electrocatalysts for enhanced CO reduction toward C₂ products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
13. [13]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
14. [14]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
15. [15]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
16. [16]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
17. [17]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
18. [18]
  Qingyun Hu , Wei Wang , Junyuan Lu , He Zhu , Qi Liu , Yang Ren , Hong Wang , Jian Hui . High-throughput screening of high energy density LiMn_1-xFe_xPO₄ via active learning. Chinese Chemical Letters, 2025, 36(2): 110344-. doi: 10.1016/j.cclet.2024.110344
19. [19]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
20. [20]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1175)
HTML views(322)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142