Citation: Shi-Lin LI, Ran LI, Zi-Qiu Lu, Hong-Zhi WANG, Ce LI. Electrochromic Properties of Ni₃(HITP)₂ Films Assembled at Gas-Liquid Interface[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 798-808. doi: 10.11862/CJIC.2021.098 shu

Electrochromic Properties of Ni₃(HITP)₂ Films Assembled at Gas-Liquid Interface

Shi-Lin LI ¹ ,
Ran LI ¹ ,
Zi-Qiu Lu ¹ ,
Hong-Zhi WANG ^{1, 2,,} ,
Ce LI ³

1.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
2.
Engineering Research Center of Advanced Glass Manufacturing Technology, Ministry of Education, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
3.
College of Mechanical Engineering, Donghua University, Shanghai 201620, China

Corresponding author: Hong-Zhi WANG, wanghz@dhu.edu.cn
Received Date: 27 October 2020
Revised Date: 25 February 2021

Figures(13)

The lack of controllable film-forming technology limits the further application of triphenylene-based metal-organic frameworks (MOFs). In this work, the gas-liquid interface assembled Ni₃(HITP)₂ films (HITP^3-=2, 3, 6, 7, 10, 11 hexaiminotriphenylene) with different thicknesses were transferred on the conductive glass. X-ray diffraction (XRD), field emission transmission electron microscope (FETEM), field emission scanning electron microscope (FESEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy were used to characterize the crystal structure, element composition and microscopic morphology of the samples. The electrochemical and electrochromic properties of Ni₃(HITP)₂ thin film were further studied and characterized. The results show that the Ni₃(HITP)₂ electrochromic film with porous structure and large specific surface area can increase the contact area with the electrolyte. Thus, the obtained film N-20 had short coloring/bleaching time (0.6/0.7 s) and high coloration efficiency (530 cm²·C^-1), while N-50 had a large optical modulation range (70% at 740 nm).
- metal-organic frameworks,
- gas-liquid interface assembly,
- electrochromic,
- coloration efficiency
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Electrochromic Properties of Ni₃(HITP)₂ Films Assembled at Gas-Liquid Interface