Citation: Hao CHEN, Shi-Biao REN, Ping ZHANG, Zhi-Cai WANG, Zhi-Ping LEI, Shi-Gang KANG, Chun-Xiu PANG, Jing-Chong YAN, Zhan-Ku LI, Heng-Fu SHUI. Highly Dispersed Ni/MCM-41 Catalyst: Solvent-Free Preparation and Performance for Hydrogenation of Naphthalene[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 817-823. doi: 10.11862/CJIC.2021.097 shu

Highly Dispersed Ni/MCM-41 Catalyst: Solvent-Free Preparation and Performance for Hydrogenation of Naphthalene

Anhui Province Key Laboratory of Coal Clean Conversion and High Valued Utilization, School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China

Corresponding author: Shi-Biao REN, rensb@ahut.edu.cn Heng-Fu SHUI, shhf@ahut.edu.cn
Received Date: 5 November 2020
Revised Date: 9 January 2021

Figures(6)

Ni/MCM-41 catalysts were prepared with a solvent-free method of mechanical grinding. Furtherly, Ni/MCM-41(CA) catalyst was also prepared by adding citric acid during preparation of Ni/MCM-41. Compared with Ni/MCM-41(IM) catalyst prepared with the conventional impregnation method, the physical properties of the catalyst with the solvent-free method were almost unchanged. And the dispersion of metallic nickel and the performance of naphthalene hydrogenation were slightly improved. After adding citric acid during preparation of Ni/MCM-41, the dispersion of metallic nickel in Ni/MCM-41(CA) catalyst was greatly increased from 6.9% to 67.9%, and the performance of naphthalene hydrogenation was nearly enhanced 100%. Through infrared spectroscopy, UV spectra and thermogravimetric analysis, the promotion mechanism for adding citric acid in the solvent-free method was attributed to forming a kind of nickel citrate by adding citric acid during preparation of Ni/MCM-41.
- Ni/MCM-41,
- solvent free,
- catalyst preparation,
- dispersion,
- hydrogenation of naphthalene,
- citric acid
1. [1]
  Dillen A J V, Robert J A M, Lensveld D J. J. Catal. , 2003, 216(1/2): 257-264
2. [2]
  Ren S B, Zhang P, Shui H F, Lei Z P, Kang S G. Catal. Commun. , 2010, 12(2): 132-136 doi: 10.1016/j.catcom.2010.08.022
3. [3]
  Ren S B, Zhao R, Zhang P, Lei Z P, Wang Z C, Kang S G, Pan C X, Shui H F. React. Kinet. Mech. Catal. , 2014, 111(1): 247-257 doi: 10.1007/s11144-013-0629-3
4. [4]
  Ren S B, Shen Z, Zhang P, Lei Z P, Wang Z C, Kang S G, Pan C X, Shui H F. J. Fuel Chem. Technol. , 2014, 42(5): 591-596 doi: 10.1016/S1872-5813(14)60029-3
5. [5]
  Li X, Quek X Y, Ligthart D A J M, Guo M, Zhang Y, Li C, Yang Q, Hensen E J M. Appl Catal. B, 2012, 123-124: 424-432 doi: 10.1016/j.apcatb.2012.05.009
6. [6]
  Wang Y M, Wu Z Y, Shi L Y, Zhu J H. Adv. Mater. , 2005, 17(3): 323-327 doi: 10.1002/adma.200400860
7. [7]
  Wang Y M, Wu Z Y, Zhu J H. J. Solid State Chem. , 2004, 177(10): 3815-3823 doi: 10.1016/j.jssc.2004.07.013
8. [8]
  SUN J F, GE C Y, YAO X J, CAO Y, ZHANG L, TANG C J, DONG L. Acta Phys. -Chim. Sin. , 2013, 29(11): 505-532
9. [9]
  Yue W B, Zhou W Z. Chem. Mater. , 2007, 19(9): 2359-2363 doi: 10.1021/cm070124b
10. [10]
  Eggenhuisen T M, Steenbergen M J V, Talsma H, Jongh P E D, Jong K P D. J. Phys. Chem. C, 2009, 113(38): 16785-16791 doi: 10.1021/jp905410d
11. [11]
  Anedda R, Cannas C, Musinu A, Pinna G, Piccaluga G, Casu M. J. Nanopart. Res. , 2008, 10(1): 107-120 doi: 10.1007/s11051-007-9235-5
12. [12]
  Kim D W, Oh S G. Mater. Lett. , 2005, 59(8/9): 976-980
13. [13]
  Takahashi R, Sato S, Sodesawa T, Suzuki M, Ichikuni N. Microporous Mesoporous Mater. , 2003, 66(2/3): 197-208
14. [14]
  Takahashi R, Sato S, Sodesawa T, Kato M, Takenaka S, Yoshida S. J. Catal. , 2001, 204(2): 259-271 doi: 10.1006/jcat.2001.3400
15. [15]
  Chen F C, Zhao X S, Liu S L, Zhang J T, Xie S J, Xun L Y, Wang Q X. Ind. Catal. , 2006, 14(7): 14-17
16. [16]
  Valencia D, García-Cruz I, Klimova T. Stud. Surf. Sci. Catal. , 2010, 175: 529-532
17. [17]
  Marban G, Fuertes A B. Appl Catal. B, 2005, 57(1): 43-53 doi: 10.1016/j.apcatb.2004.10.011
18. [18]
  Sun M, Ma X X, Lv B, Dai X M, Yao Y, Liu Y Y, He M, Zhao X L. Fuel, 2015, 160: 16-23 doi: 10.1016/j.fuel.2015.07.029
19. [19]
  Lin S D, Vannice M A. J. Catal. , 1993, 143(2): 563-572 doi: 10.1006/jcat.1993.1299
20. [20]
  XUE Y B, LING K C, ZOU G M. Coal Conversion, 1999, 22(4): 1-4 doi: 10.3969/j.issn.1004-4248.1999.04.001
1. [1]
  Hui Zhang , Zijian Zhao , Yajing Wang , Kai Ni , Yanfei Wang , Liang Zhu , Jianyun Liu , Xiaoyu Zhao . Structurally engineered solvent-free LiFePO₄ electrodes via hot-pressing with efficient ion transport pathways for lithium extraction from brine. Acta Physico-Chimica Sinica, 2026, 42(2): 100130-0. doi: 10.1016/j.actphy.2025.100130
2. [2]
  Haiqiang Lin , Weizheng Weng , Jingdong Lin , Mingshu Chen , Xueming Fang , Lefu Yang . Diverse Variables-Driven Catalytic Optimization: Experimental Enhancement and Instructional Design for Selective Methane Oxidation on Supported Nickel-based Catalysts. University Chemistry, 2025, 40(11): 327-336. doi: 10.12461/PKU.DXHX202505106
3. [3]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
4. [4]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
7. [7]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
8. [8]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
9. [9]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
10. [10]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-0. doi: 10.3866/PKU.WHXB202408004
11. [11]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
12. [12]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
13. [13]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
14. [14]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
15. [15]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
16. [16]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
17. [17]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
18. [18]
  Hailang JIA , Yujie LU , Pengcheng JI . Preparation and properties of nitrogen and phosphorus co-doped graphene carbon aerogel supported ruthenium electrocatalyst for hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2327-2336. doi: 10.11862/CJIC.20250021
19. [19]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
20. [20]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(2249)
HTML views(663)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142