Citation: Hao CHEN, Shi-Biao REN, Ping ZHANG, Zhi-Cai WANG, Zhi-Ping LEI, Shi-Gang KANG, Chun-Xiu PANG, Jing-Chong YAN, Zhan-Ku LI, Heng-Fu SHUI. Highly Dispersed Ni/MCM-41 Catalyst: Solvent-Free Preparation and Performance for Hydrogenation of Naphthalene[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 817-823. doi: 10.11862/CJIC.2021.097 shu

Highly Dispersed Ni/MCM-41 Catalyst: Solvent-Free Preparation and Performance for Hydrogenation of Naphthalene

Anhui Province Key Laboratory of Coal Clean Conversion and High Valued Utilization, School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China

Corresponding author: Shi-Biao REN, rensb@ahut.edu.cn Heng-Fu SHUI, shhf@ahut.edu.cn
Received Date: 5 November 2020
Revised Date: 9 January 2021

Figures(6)

Ni/MCM-41 catalysts were prepared with a solvent-free method of mechanical grinding. Furtherly, Ni/MCM-41(CA) catalyst was also prepared by adding citric acid during preparation of Ni/MCM-41. Compared with Ni/MCM-41(IM) catalyst prepared with the conventional impregnation method, the physical properties of the catalyst with the solvent-free method were almost unchanged. And the dispersion of metallic nickel and the performance of naphthalene hydrogenation were slightly improved. After adding citric acid during preparation of Ni/MCM-41, the dispersion of metallic nickel in Ni/MCM-41(CA) catalyst was greatly increased from 6.9% to 67.9%, and the performance of naphthalene hydrogenation was nearly enhanced 100%. Through infrared spectroscopy, UV spectra and thermogravimetric analysis, the promotion mechanism for adding citric acid in the solvent-free method was attributed to forming a kind of nickel citrate by adding citric acid during preparation of Ni/MCM-41.
- Ni/MCM-41,
- solvent free,
- catalyst preparation,
- dispersion,
- hydrogenation of naphthalene,
- citric acid
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沈阳化工大学材料科学与工程学院沈阳 110142