Citation: Zhan-Xin WU, Ya-Song QU, Xiao-Hua YU, Gang XIE, Wen-Zhi ZHANG, Peng-Yuan CUI, Yong-Gang LI. La(OH)₃ Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 778-784. doi: 10.11862/CJIC.2021.096 shu

La(OH)₃ Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery

Zhan-Xin WU ¹ ,
Ya-Song QU ¹ ,
Xiao-Hua YU ^1,, ,
Gang XIE ^{1, 2, 3} ,
Wen-Zhi ZHANG ¹ ,
Peng-Yuan CUI ¹ ,
Yong-Gang LI ⁴

1.
Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Kunming Metallurgical Research Institute Co., Ltd., Kunming 650503, China
3.
State Key Laboratory of Common Associated Non-ferrous Metal Resources Pressure Hydrometallurgy Technology, Kunming 650503, China
4.
Yunnan Copper Technology Development Co., Ltd., Kunming 650033, China

Corresponding author: Xiao-Hua YU, yxhyxh1978@aliyun.com
Received Date: 17 July 2020
Revised Date: 16 March 2021

Figures(7)

Lanthanum hydroxide (La(OH)₃) was loaded on the surface of zinc-aluminum hydrotalcite (Zn-Al LDHs) by co precipitation method. The X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images reveal that the La(OH)₃ was successfully loaded on the surface of the Zn-Al LDHs, and the loaded Zn-Al LDHs still showed hexagonal plate-like crystals with uniform particle size and good dispersion; 5%La(OH)₃@Zn-Al LDHs had the best electrochemical performance. Cyclic voltammetry (CV), Tafel polarization curves and electrochemical impedance spectroscope (EIS) showed that it had better reversibility, larger positive corrosion potential and lower resistance. 5%La(OH)₃@Zn-Al LDHs showed the cycle retention of 94.84% after 80 cycles.
- load,
- Zn-Al LDHs,
- Zn-Ni secondary battery,
- La(OH)₃
1. [1]
  Yang J L, Yuan Y F, Wu H M, Li Y, Chen Y B, Guo S Y. Electrochim. Acta, 2010, 55: 7050-7054 doi: 10.1016/j.electacta.2010.06.075
2. [2]
  Zhang Z, Yang Z H, Wang R J, Feng Z B, Xie X E, Liao Q F. Electrochim. Acta, 2014, 134: 287-292 doi: 10.1016/j.electacta.2014.04.127
3. [3]
  Jiang Y A, Yang Z H, Liu L L, Meng J L, Cui F. Mater. Lett. , 2019, 255: 126558 doi: 10.1016/j.matlet.2019.126558
4. [4]
  Wu J Z, Tu J P, Yuan Y F, Ma M, Wang X L, Zhang L, Li R L, Zhang J. J. Alloys Compd. , 2009, 479: 624-628 doi: 10.1016/j.jallcom.2009.01.013
5. [5]
  Yang H, Yang Z H, Wen X, Liu L L. Electrochim. Acta, 2017, 252: 507-515 doi: 10.1016/j.electacta.2017.09.014
6. [6]
  Yan X Y, Chen Z X, Wang Y, Zhang J J, Zhou Z Y, Lv H F. J. Power Sources, 2020, 448: 227412 doi: 10.1016/j.jpowsour.2019.227412
7. [7]
  Zeng D Q, Yang Z H, Wang S W, Ni X, Ai D J, Zhang Q Q. Electrochim. Acta, 2011, 56(11): 4075-4080 doi: 10.1016/j.electacta.2011.01.119
8. [8]
  Fan X M, Yang Z H, Long W, Yang B, Jing J, Wang R J. Electrochim. Acta, 2013, 108: 741-748 doi: 10.1016/j.electacta.2013.07.031
9. [9]
  Wang T T, Yang Z H, Yang B, Wang R J, Huang J H. J. Power Sources, 2014, 257: 174-180 doi: 10.1016/j.jpowsour.2014.02.006
10. [10]
  Wang R J, Yang Z H, Yang B, Wang T T, Chu Z H. J. Power Sources, 2014, 251: 344-350 doi: 10.1016/j.jpowsour.2013.11.071
11. [11]
  Fan X M, Yang Z H, Xie X E, Long W, Wang R J, Hou Z L. J. Power Sources, 2013, 241: 404-409 doi: 10.1016/j.jpowsour.2013.04.136
12. [12]
  Liu H L, Yu T T, Su D Q, Tang Z H, Zhang J H, Liu Y J, Yuan A H, Kong Q H. Ceram. Int. , 2017, 43(16): 14395-14400 doi: 10.1016/j.ceramint.2017.07.207
13. [13]
  Zhang Z, Yang Z H, Huang J H, Feng Z B, Xie X E. Electrochim. Acta, 2015, 155: 61-68 doi: 10.1016/j.electacta.2014.12.145
14. [14]
  Fan X M, Yang Z H, Long W, Zhao Z Y, Yang B. Electrochim. Acta, 2013, 92: 365-370 doi: 10.1016/j.electacta.2013.01.035
15. [15]
  YANG J L, YUAN Y F, CHEN Y B, GUO S Y. Chinese J. Inorg. Chem. , 2010, 26(11): 2063-2068
16. [16]
  YU S L, YU X H, LÜ X, WANG Y, FENG P, BIE H B, XIE G. Chinese J. Inorg. Chem. , 2017, 33(9): 1573-1578
17. [17]
  Xie X E, Yang Z H, Feng Z B, Zhang Z, Huang J H. Electrochim. Acta, 2015, 154: 308-314 doi: 10.1016/j.electacta.2014.12.101
18. [18]
  Yang B, Yang Z H, Wen R J, Wang T T. Electrochim. Acta, 2013, 111: 581-587 doi: 10.1016/j.electacta.2013.08.052
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
3. [3]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
4. [4]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
5. [5]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
6. [6]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
9. [9]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
10. [10]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
11. [11]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
12. [12]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143
13. [13]
  Xinxiu Yan , Xizhe Huang , Yangyang Liu , Weishang Jia , Hualin Chen , Qi Yao , Tao Chen . Hyperbranched polyamidoamine protective layer with phosphate and carboxyl groups for dendrite-free Zn metal anodes. Chinese Chemical Letters, 2024, 35(10): 109426-. doi: 10.1016/j.cclet.2023.109426
14. [14]
  Yunfei Shen , Long Chen . Gradient imprinted Zn metal anodes assist dendrites-free at high current density/capacity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100321-100321. doi: 10.1016/j.cjsc.2024.100321
15. [15]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
16. [16]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
17. [17]
  Yufeng Wu , Mingjun Jing , Juan Li , Wenhui Deng , Mingguang Yi , Zhanpeng Chen , Meixia Yang , Jinyang Wu , Xinkai Xu , Yanson Bai , Xiaoqing Zou , Tianjing Wu , Xianyou Wang . Collaborative integration of Fe-N_x active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries. Chinese Chemical Letters, 2024, 35(9): 109269-. doi: 10.1016/j.cclet.2023.109269
18. [18]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
19. [19]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
20. [20]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1069)
HTML views(237)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

La(OH)3 Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery

Metrics

通讯作者: 陈斌, bchen63@163.com

La(OH)₃ Loaded Zinc Aluminum Hydrotalcite: Preparation and Performance for Zinc Nickel Secondary Battery