Citation: Jia-Xin TONG, Juan WANG, Hui-Xing HUANG. Surfactant-Assisted Synthesis of LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 835-843. doi: 10.11862/CJIC.2021.094 shu

Surfactant-Assisted Synthesis of LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Material

Jia-Xin TONG ^{1, 2} ,
Juan WANG ^{1, 2,,} ,
Hui-Xing HUANG ^{1, 2}

1.
School of Mechanical and Electrical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
2.
Shaanxi Provincial Key Laboratory of Nanomaterials and Technology, Xi'an 710055, China

Corresponding author: Juan WANG, juanwang618@126.com
Received Date: 30 November 2020
Revised Date: 6 March 2021

Figures(11)

Herein, a modification method was proposed to control the morphology and particle size of materials by adding alkyl quaternary ammonium salt surfactant. In the synthesis process of LiNi_0.8Co_0.1Mn_0.1O₂ precursor, the surfactant dodecyl trimethyl bromide (DTAB) and hexadecyl trimethyl bromide (CTAB) were added; the LiNi_0.8Co_0.1Mn_0.1O₂ precursor was synthesized by using urea as compounding agent and precipitation agent and the solvent heat method as the synthesis method. Finally, hollow porous materials with ellipsoidal shape were synthesized by high temperature calcination of mixed lithium. Compared with blank samples without surfactant, the materials modified by surfactant had smaller particle size and more regular morphology. Electrochemical test showed that the initial charging capacity reached 223 and 251 mAh·g^-1 respectively after adding DTAB and CTAB. Among them, the initial discharge capacity of adding CTAB reached 216 mAh·g^-1 (0.1C), and the capacity retention rate was 85.1% after 100 cycles, higher than 81.7% (0.1C) of LNCM811. The modification of surfactants significantly improves the electrochemical properties of the materials and provides a new perspective for the modification of high nickel ternary anode materials.
- LiNi_0.8Co_0.1Mn_0.1O₂,
- surfactant,
- solvothermal method,
- precursor,
- morphology,
- cycle stability
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Surfactant-Assisted Synthesis of LiNi0.8Co0.1Mn0.1O2 Cathode Material

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通讯作者: 陈斌, bchen63@163.com

Surfactant-Assisted Synthesis of LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Material