Citation: Liang ZHAO, Shao-Shuai CHU, Jun-Kai CAI, Jian-Wei WEI, Ya-Nan LI, Chun-Ying DUAN. Metal-Organic Triangles with NADH Mimics for Photocatalytic Hydrogen Production[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 769-777. doi: 10.11862/CJIC.2021.092 shu

Metal-Organic Triangles with NADH Mimics for Photocatalytic Hydrogen Production

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Liang ZHAO, zhaol@dlut.edu.cn
Received Date: 28 October 2020
Revised Date: 28 December 2020

Figures(7)

By incorporating two different reduced nicotinamide adenine dinucleotide (NADH) mimics within the ligand backbone, two positively charged cobalt-based metal-organic triangular hosts Co-L¹ and Co-L² (H₂L¹=5'-(benzo[d]thiazol-2-yl)-N'⁴, N'''''^4″-bis((E)-pyridin-2-ylmethylene)-[1, 1': 3', 1″-terphenyl]-4, 4″-dicarbohydrazide, H₂L²=5'(benzo[d]imidazol-2-yl)-N'⁴, N'''''^4″-bis((E)-pyridin-2-ylmethylene)-[1, 1': 3', 1″-terphenyl]-4, 4″-dicar bohydrazide) have been prepared in high yield and characterized as a redox vehicle for the construction of an artificial photosynthesis (AP) system. By taking advantage of electrostatic interaction to facilitate the formation of host-guest complexes, anionic ruthenium-based photosensitizer[Ru(dcbpy)₃]^4- (dcbpy=2, 2'-bipyridine-4, 4'-dicarboxylic acid) was encapsulated into the suitable cavity of hosts to improve photoinduced electron transfer (PET) processes and to promote photocatalytic hydrogen production. Compared with metal-organic triangular Co-L³ without NADH mimics (H₂L³=5'-methyl-N'⁴, N'''''^4″-bis((E)-pyridin-2-ylmethylene)-[1, 1': 3', 1″-terphenyl]-4, 4″-dicarbohydrazide) and mononuclear catalyst Co-L⁴ (HL⁴=(E)-N'-(pyridin-2-ylmethylene)benzohydrazide) containing the same coordination environment and without NADH mimics, photocatalytic hydrogen production efficiency of the host-guest supramolecular photosynthetic systems could increase 1.6 and 6 times, respectively. The higher catalytic activity is attributed to the formation of host-guest complex between catalyst Co-L¹ and Co-L² and photosensitizer[Ru(dcbpy)₃]^4- and the introduction of NADH mimics benefiting the PET process between the catalyst and photosensitizer.
- metal-organic macrocycle,
- NADH mimic,
- host-guest complex,
- photoinduced electron transfer,
- photocatalytic hydrogen production
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