Citation: Yang LU, Li SHANGGUAN, Hui ZHANG, Yan WANG, Yu-ye TAN, Jian-hua SUN, Guang-xiang LIU. Preparation of Carbon Self-Doping Graphic Carbon Nitride Nanosheets for Photocatalytic H₂ Evolution Performance under Visible-Light Irradiation[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 668-674. doi: 10.11862/CJIC.2021.090 shu

Preparation of Carbon Self-Doping Graphic Carbon Nitride Nanosheets for Photocatalytic H₂ Evolution Performance under Visible-Light Irradiation

Yang LU ¹ ,
Li SHANGGUAN ¹ ,
Hui ZHANG ¹ ,
Yan WANG ¹ ,
Yu-ye TAN ¹ ,
Jian-hua SUN ^1,, ,
Guang-xiang LIU ^2,,

1.
School of Chemistry and Environmental Engineering, Institute of Advanced Functional Materials for Energy, Jiangsu University of Technology, Changzhou, Suzhou 213001, China
2.
Nanjing Key Laboratory of Advanced Functional Materials, School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: Jian-hua SUN, sunjh@jsut.edu.cn Guang-xiang LIU, njuliugx@126.com
Received Date: 19 October 2020
Revised Date: 6 March 2021

Figures(8)

The photocatalytic activity of graphic carbon nitride(g-C₃N₄) was limited because of poor visible-light utilization and low photogenerated carriers separation. Herein, carbon self-doping g-C₃N₄(CNNS-x, x mg represents the mass of TAPD in precursor) was simply prepared by one-step thermal co-polymerization of the homogeneous mixture of urea and 2, 4, 6-triaminopyrimidine(TAPD). The as-prepared CNNS-x was carefully characterized by powder X-ray diffraction(XRD), elemental analysis(EA), and X-ray photoelectron spectroscopy(XPS), which indicated that the pyrimidine was incorporated into the π-conjugated graphic carbon nitride. Thus, the CNNS-x was endowed with narrower bandgap, higher electric conductivity, which are favorable for improving the efficiency of visible-light absorption and photogenerated carrier separation. As a consequence, all the CNNS-x show remarkably improved performance in photocatalytic hydrogen evolution activity under visible-light irradiation. The optimum sample(CNNS-30) showed an excellent hydrogen evolution rate(~57 μmol·h^-1), which was up to 4 times higher than that of g-C₃N₄ nanosheets(CNNS).
- carbon nitride,
- doping,
- photocatalytic water splitting,
- hydrogen evolution
1. [1]
  Wang Q, Domen K. Chem. Rev. , 2020, 120(2): 919-985 doi: 10.1021/acs.chemrev.9b00201
2. [2]
  Qi J, Zhang W, Cao R. Adv. Energy Mater. , 2018, 8(5): 1701620 doi: 10.1002/aenm.201701620
3. [3]
  Fujishima A, Honda K. Nature, 1972, 238(5358): 37-38 doi: 10.1038/238037a0
4. [4]
  Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson J M, Domen K, Antonietti M. Nat. Mater. , 2009, 8(1): 76-80 doi: 10.1038/nmat2317
5. [5]
  Ong W, Tan L, Ng Y H, Yong S, Chai S. Chem. Rev. , 2016, 116(12): 7159-7329 doi: 10.1021/acs.chemrev.6b00075
6. [6]
  Fu J W, Yu J G, Jiang C J, Cheng B. Adv. Energy Mater. , 2018, 8(3): 1701503 doi: 10.1002/aenm.201701503
7. [7]
  Yang Y L, Wang S C, Li Y L, Wang J S, Wang L Z. Chem. -Asian J. , 2017, 12(13): 1421-1434 doi: 10.1002/asia.201700540
8. [8]
  Wang X C, Blechert S, Antonietti M. ACS Catal. , 2012, 2(8): 1596-1606 doi: 10.1021/cs300240x
9. [9]
  Thomas A, Fischer A, Goettmann F, Antonietti M, Muller J O, Schlogl R, Carlsson J M. J. Mater. Chem. , 2008, 18(41): 4893-4908 doi: 10.1039/b800274f
10. [10]
  Zhang J S, Chen X F, Takanabe K, Maeda K, Domen K, Epping J D, Fu X Z, Antonietti M, Wang X C. Angew. Chem. Int. Ed. , 2010, 49(2): 441-444 doi: 10.1002/anie.200903886
11. [11]
  Zhou Z X, Zhang Y Y, Shen Y F, Liu S Q, Zhang Y J. Chem. Soc. Rev. , 2018, 47(7): 2298-2321 doi: 10.1039/C7CS00840F
12. [12]
  Jiang L B, Yuan X Z, Pan Y, Liang J, Zeng G M, Wu Z B, Wang H. Appl. Catal. B, 2017, 217: 388-406 doi: 10.1016/j.apcatb.2017.06.003
13. [13]
  Zhang J S, Sun J H, Maeda K, Domen K, Liu P, Antonietti M, Fu X Z, Wang X C. Energy Environ. Sci. , 2011, 4(3): 675-678 doi: 10.1039/C0EE00418A
14. [14]
  Dong G H, Zhao K, Zhang L Z. Chem. Commun. , 2012, 48(49): 6178-6180 doi: 10.1039/c2cc32181e
15. [15]
  Su F Y, Xu C Q, Yu Y X, Zhang W D. ChemCatChem, 2016, 8(22): 3527-3535 doi: 10.1002/cctc.201600928
16. [16]
  Fang J W, Fan H Q, Li M M, Long C B. J. Mater. Chem. A, 2015, 3(26): 13819-13826 doi: 10.1039/C5TA02257F
17. [17]
  Vu N N, Nguyen C C, Kaliaguine S, Do T O. ChemSusChem, 2019, 12(1): 291-302 doi: 10.1002/cssc.201802394
18. [18]
  Jun Y, Lee E Z, Wang X, Hong W H, Stucky G D, Thomas A. Adv. Funct. Mater. , 2013, 23(29): 3661-3667 doi: 10.1002/adfm.201203732
19. [19]
  Shalom M, Inal S, Fettkenhauer C, Neher D, Antonietti M. J. Am. Chem. Soc. , 2013, 135(19): 7118-7121 doi: 10.1021/ja402521s
20. [20]
  Zhang G, Li G, Lan Z, Lin L, Savateev A, Heil T, Zafeiratos S, Wang X, Antonietti M. Angew. Chem. Int. Ed. , 2017, 56(43): 13445-13449 doi: 10.1002/anie.201706870
21. [21]
  Sun J H, Zhang J S, Zhang M W, Antonietti M, Fu X Z, Wang X C. Nat. Commun. , 2012, 3: 1139 doi: 10.1038/ncomms2152
22. [22]
  Qiu Y, Xin L, Jia F, Xie J, Li W Z. Langmuir, 2016, 32(48): 12569-12578 doi: 10.1021/acs.langmuir.6b02498
23. [23]
  Yu H J, Shi R, Zhao Y X, Bian T, Zhao Y F, Zhou C, Waterhouse G I N, Wu L Z, Tung C H, Zhang T R. Adv. Mater. , 2017, 29(16): 1605148 doi: 10.1002/adma.201605148
24. [24]
  Li K, Zhang W D. Small, 2018, 14(12): 1703599 doi: 10.1002/smll.201703599
1. [1]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
2. [2]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
3. [3]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
4. [4]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
7. [7]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
8. [8]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
9. [9]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
10. [10]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
11. [11]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
12. [12]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
13. [13]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
14. [14]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
15. [15]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
16. [16]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
17. [17]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
18. [18]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
19. [19]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
20. [20]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064

Get Citation

PDF

XML

Metrics

PDF Downloads(33)
Abstract views(2159)
HTML views(923)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Carbon Self-Doping Graphic Carbon Nitride Nanosheets for Photocatalytic H2 Evolution Performance under Visible-Light Irradiation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Carbon Self-Doping Graphic Carbon Nitride Nanosheets for Photocatalytic H₂ Evolution Performance under Visible-Light Irradiation