Citation: Xin HE, Shun-Lin ZHANG, Tian-Yu XIAO, Dun-Ru ZHU. Two Metal-Organic Frameworks Built from 2, 2'-Dimethyl-4, 4'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 945-952. doi: 10.11862/CJIC.2021.079 shu

Two Metal-Organic Frameworks Built from 2, 2'-Dimethyl-4, 4'-biphenyldicarboxylic Acid

Xin HE ¹ ,
Shun-Lin ZHANG ¹ ,
Tian-Yu XIAO ¹ ,
Dun-Ru ZHU ^{1, 2,,}

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Dun-Ru ZHU, zhudr@njtech.edu.cn
Received Date: 6 December 2020
Revised Date: 24 December 2020

Figures(8)

Two metal-organic frameworks (MOFs), [Ni(μ₂-H₂O)(L)(DMF)(H₂O)]·0.5H₂O (1) and[Cd_2.5(L)(trz)₃(H₂O)₂]·2.5DMF (2) (L=2, 2'-dimethyl-4, 4'-biphenyldicarboxylic acid, DMF=N, N-dimethylformamide, Htrz=1, 2, 4-triazole), have been synthesized and characterized by FT-IR, thermogravimetric analysis (TGA), powder and single crystal X-ray diffraction. MOF 1 crystallizes in monoclinic system with a space group P2₁/c. Ni(Ⅱ) ion adopts an elongated[NiO₆] octahedron as a 4-connected node and is linked by μ₂-H₂O and L^2- ligands to generate a 2D sql topological network. MOF 2 crystallizes in monoclinic system with a space group C2/m and contains three crystallographically different Cd(Ⅱ) ions. Each Cd(Ⅱ) ion shows a distorted octahedral geometry and three Cd(Ⅱ) ions are connected by trz^- co-ligands in a μ_{1, 2, 4}-bridging mode to form a 2D kgd layer with (3, 6) topology in the ab plane. These layers are further pillared by the L^2- ligands along the c axis to produce a binodal (4, 8)-connected 3D flu framework. The TGA showed that 1 and 2 were stable below 390 and 230℃, respectively. CCDC: 2042076, 1; 2042077, 2.
- metal-organic frameworks,
- 2, 2'-dimethyl-4, 4'-biphenyldicarboxylic acid,
- crystal structure,
- topology
1. [1]
  Furukawa H, Cordova K E, O'Keeffe M, Yaghi O M. Science, 2013, 341: 1230444 doi: 10.1126/science.1230444
2. [2]
  Wang X, Qin T, Bao S S, Zhang Y C, Shen X, Zheng L M, Zhu D R. J. Mater. Chem. A, 2016, 4: 16484-16489 doi: 10.1039/C6TA06792A
3. [3]
  Zhu J, Usov P M, Xu W Q, Celis-Salazar P J, Lin S Y, Kessinger M C, Landaverde-Alvarado C, Cai M, May A M, Slebodnick C, Zhu D R, Senanayake S D, Morris A J. J. Am. Chem. Soc. , 2018, 140: 993-1003 doi: 10.1021/jacs.7b10643
4. [4]
  Chiong J A, Zhu J, Bailey J B, Kalaj M, Subramanian R H, Xu W, Cohen S M, Tezcan F A. J. Am. Chem. Soc. , 2020, 142: 6907-6912 doi: 10.1021/jacs.0c01626
5. [5]
  Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O'Keeffe M, Yaghi O M. Science, 2002, 295: 469-472 doi: 10.1126/science.1067208
6. [6]
  Deng H, Grunder S, Cordova K E, Valente C, Furukawa H, Hmadeh M, Gándara F, Whalley A C, Liu Z, Asahina S, Kazumori H, O'Keeffe M, Terasaki O, Stoddart J F, Yaghi O M. Science, 2012, 336: 1018-1023 doi: 10.1126/science.1220131
7. [7]
  XU H, GONG J, MA J H, XU Y, SHEN X, ZHU D R. Chinese J. Inorg. Chem. , 2012, 28(10): 2229-2235
8. [8]
  Wang X Z, Zhu D R, Xu Y, Yang J, Shen X, Zhou J, Fei N, Ke X K, Peng L M. Cryst. Growth Des. , 2010, 10: 887-894 doi: 10.1021/cg9012262
9. [9]
  Zhang H J, Wang X Z, Zhu D R, Song Y, Xu Y, Xu H, Shen X, Gao T, Huang M X. CrystEngComm, 2011, 13: 2586-2592 doi: 10.1039/c0ce00766h
10. [10]
  Gao T, Wang X Z, Gu H X, Xu Y, Shen X, Zhu D R. CrystEng-Comm, 2012, 14: 5905-5913 doi: 10.1039/c2ce25442e
11. [11]
  Xu H, Bao W W, Xu Y, Liu X L, Shen X, Zhu D R. CrystEngComm, 2012, 14: 5720-5722 doi: 10.1039/c2ce25739d
12. [12]
  Luo R, Xu H, Gu H X, Wang X, Xu Y, Shen X, Bao W W, Zhu D R. CrystEngComm, 2014, 16: 784-796 doi: 10.1039/C3CE41428K
13. [13]
  Liu X L, Wang X, Gao T, Xu Y, Shen X, Zhu D R. CrystEngComm, 2014, 16: 2779-2787 doi: 10.1039/c3ce42553c
14. [14]
  Qin T, Gong J, Ma J H, Wang X, Wang Y H, Xu Y, Shen X, Zhu D R. Chem. Commun. , 2014, 50: 15886-15889 doi: 10.1039/C4CC06588C
15. [15]
  Wang X, Zhao J, Zhao Y, Xu H, Shen X, Zhu D R, Jing S. Dalton Trans. , 2015, 44: 9281-9288 doi: 10.1039/C5DT00602C
16. [16]
  Zhao J, Wang X, Zhao J, Luo R, Shen X, Zhu D R, Jing S. CrystEngComm, 2016, 18: 863-867 doi: 10.1039/C5CE02417J
17. [17]
  Zhao J, He X, Zhang Y C, Zhu J, Shen X, Zhu D R. Cryst. Growth Des. , 2017, 17: 5524-5532 doi: 10.1021/acs.cgd.7b01061
18. [18]
  FENG S F, HE X, QIN T, ZHANG S L, ZHU D R. Chinese J. Inorg. Chem. , 2017, 33(11): 2095-2102 doi: 10.11862/CJIC.2017.241
19. [19]
  Zhang Y C, Wu Y H, He X, Ma J H, Shen X, Zhu D R. Acta Crystallogr. Sect. C, 2018, C74: 256-262
20. [20]
  Zhang S L, Gao S, Wang X, He X, Zhao J, Zhu D R. Acta Crystallogr. Sect. B, 2019, B75: 1060-1068
21. [21]
  Furukawa H, Kim J, Ockwig N W, O'Keeffe M, Yaghi O M. J. Am. Chem. Soc. , 2008, 130: 11650-11661 doi: 10.1021/ja803783c
22. [22]
  Xie Y, Wang T T, Zeng H P. Z. Anorg. Allg. Chem. , 2014, 640: 1741-1744 doi: 10.1002/zaac.201300680
23. [23]
  Yuan S, Chen Y P, Qin J, Lu W, Wang X, Zhang Q, Bosch M, Liu T F, Lian X, Zhou H C. Angew. Chem. Int. Ed. , 2015, 54: 14696-14700 doi: 10.1002/anie.201505625
24. [24]
  Yuan S, Zou L, Li H, Chen Y P, Qin J, Zhang Q, Lu W, Hall M B, Zhou H C. Angew. Chem. , 2016, 128: 10934-10938 doi: 10.1002/ange.201604313
25. [25]
  Song T, Yu J C, Cui Y J, Yang Y, Qian G D. Dalton Trans. , 2016, 45: 4218-4223 doi: 10.1039/C5DT03466C
26. [26]
  Chen C X, Qiu Q F, Cao C C, Pan M, Wang H P, Jiang J J, Wei Z W, Zhu K, Li G Q, Su C Y. Chem. Commun. , 2017, 53: 11403-11406 doi: 10.1039/C7CC06352K
27. [27]
  Pang J, Yuan S, Du D, Lollar C, Zhang L, Wu M, Yuan D, Zhou H C, Hong M C. Angew. Chem. Int. Ed. , 2017, 56: 14622-14626 doi: 10.1002/anie.201709186
28. [28]
  Dolgopolova E A, Ejegbavwo O A, Martin C R, Smith M D, Setyawan W, Karakalos S G, Henager C H, Loye H C, Shustova N B. J. Am. Chem. Soc. , 2017, 139: 16852-16861 doi: 10.1021/jacs.7b09496
29. [29]
  Pang J D, Yuan S, Qin J S, Wu M, Lollar C T, Li J, Huang N, Li B, Zhang P, Zhou H C. J. Am. Chem. Soc. , 2018, 140: 12328-12332 doi: 10.1021/jacs.8b07411
30. [30]
  Ejegbavwo O A, Martin C R, Olorunfemi O A, Leith G A, Ly R T, Rice A M, Dolgopolova E A, Smith M D, Karakalos S G, Birkner N, Powell B A, Pandey S, Koch R J, Misture S T, Loye H C, Phillpot S R, Brinkman K S, Shustova N B. J. Am. Chem. Soc. , 2019, 141: 11628-11640 doi: 10.1021/jacs.9b04737
31. [31]
  Berseneva A A, Martin C R, Galitskiy V A, Ejegbavwo O A, Leith G A, Ly R T, Rice A M, Dolgopolova E A, Smith M D, Loye H C, Diprete D P, Jake W, Amoroso J W, Shustova N B. Inorg. Chem. , 2020, 59: 179-183 doi: 10.1021/acs.inorgchem.9b01310
32. [32]
  He X, Wang X, Xiao T Y, Zhang S L, Zhu D R. Inorg. Chem. , 2021, 60: 9-13 doi: 10.1021/acs.inorgchem.0c02913
33. [33]
  Blaszykowski C, Aktoudianakis E, Bressy C, Alberico D, Lautens M. Org. Lett. , 2006, 8: 2043-2045 doi: 10.1021/ol060447y
34. [34]
  Burrows A D, Frost C G, Mahon M F, Richardson C. Chem. Commun. , 2009, 45: 4218-4220
35. [35]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64: 112-122
36. [36]
  Spek A L. Acta Crystallogr. Sect. C, 2015, C71: 9-18
37. [37]
  Spek A L. Acta Crystallogr. Sect. D, 2009, D65: 148-155
38. [38]
  Alvarez S, Alemany P, Casanova D, Cirera J, Llunell M, Avnir D. Coord. Chem. Rev. , 2005, 249: 1693-1708 doi: 10.1016/j.ccr.2005.03.031
39. [39]
  Lin Z J, Han L W, Wu D S, Huang Y B, Cao R. Cryst. Growth Des. , 2013, 13: 255-263 doi: 10.1021/cg301405r
40. [40]
  Xu Y C, Chen Y, Qiu H J, Zeng X S, Xu H L, Li J, Zeng Y F, Xiao D R. CrystEngComm, 2016, 18: 8182-8193 doi: 10.1039/C6CE01287F
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