Citation: Rong-Ge GUO, Ying-Li LI, Ze-Yuan HU, Mei-Yu SHI, Yi-Dong MIAO, Yan-Wei SUI, Ji-Qiu QI, Fu-Xiang WEI, Yao-Jian REN, Zhen-Zhen ZHAN, Jin-Long LIU, Zhi SUN, Mei-Hua ZHOU, Dong-Mei MENG. In-Situ Growth of NiCo-Layered Double Hydroxides Nanosheets Deposited on Carbon Fiber Cloth for High-Performance Asymmetric Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 886-898. doi: 10.11862/CJIC.2021.078 shu

In-Situ Growth of NiCo-Layered Double Hydroxides Nanosheets Deposited on Carbon Fiber Cloth for High-Performance Asymmetric Supercapacitors

1.
Jiangsu Province High-Efficiency Energy Storage Technology and Equipment Engineering Laboratory, School of Materials and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
Jiangsu FERY Battery Technology Co., Ltd., Xuzhou, Jiangsu 221116, China

Corresponding author: Yan-Wei SUI, wyds123456@outlook.com Zhi SUN, sunzhi108@outlook.com
Received Date: 8 September 2020
Revised Date: 28 January 2021

Figures(10)

The NiCo-layered double hydroxide (LDH) was prepared directly on different carbon fiber substrates by potentiostatic deposition. This method did not need to add any binder, which can prevent the phenomenon of conductivity reduction due to the resistance of the binder. In the layered crystal structure of NiCo-LDH, the positively charged host layer and the interlayer charge compensating anion can promote ion diffusion between electrode materials, so that the active sites can be efficiently utilized. In this paper, an electrode material with a wrinkled structure was synthesized by a potentiostatic deposition technique. Benefiting from the folded lamellar structure features, this composite material (NiCo-LDH/carbon fiber cloth) had sterling specific capacitance (1 387.5 F·g^-1 at 1 A·g^-1). In addition, with the composite as the positive electrode and the rGO coated on the surface of nickel foam (NF) as negative material, the assembled asymmetric supercapacitor (ASC) presented superb electrochemical performance. ASC had an energy density of 26.6 Wh·kg^-1 and a power density of 850.4 W·kg^-1 at 1 A·g^-1. The energy density remained 14.9 Wh·kg^-1 as the maximum power density (8 500.3 W·kg^-1).
- layer double hydroxides,
- electrodeposition,
- current collector,
- asymmetric supercapacitor,
- nanostructures,
- energy conversion
1. [1]
  Yadav A A, Hunge Y M, Kulkarni S B. Ultrason Sonochem, 2019, 58: 104663 doi: 10.1016/j.ultsonch.2019.104663
2. [2]
  Daneshvar N, Khataee A R, Ghadim R A, Rasoulifard M H. J. Hazard. Mater. , 2007, 148(3): 566-572 doi: 10.1016/j.jhazmat.2007.03.028
3. [3]
  Alshahrie A, Ansari M O. Electron. Mater. Lett. , 2019, 15(2): 238-246 doi: 10.1007/s13391-018-00107-6
4. [4]
  Wen Y L, Kierzek K, Chen X C, Gong J, Liu J, Niu R. Waste Manage. , 2019, 87: 691-700 doi: 10.1016/j.wasman.2019.03.006
5. [5]
  Yu L P, Chen G Z. Front. Chem. , 2019, 7(15): 272
6. [6]
  Yadav A A, Lokhande A C, Kim J H, Lokhande C D. J. Colloid Interface Sci. , 2016, 473: 22-27 doi: 10.1016/j.jcis.2016.03.051
7. [7]
  Natarajan S, Lee Y S, Aravindan V. Chem Asian J. , 2019, 14(7): 936-951 doi: 10.1002/asia.201900030
8. [8]
  Wang W, Chen L J, Qi J Q, Sui Y, He Y, Meng Q. J. Mater. Sci. Mater. Electron. , 2018, 29(3): 2120-2130 doi: 10.1007/s10854-017-8124-7
9. [9]
  Chen H, Zhang H, Zhang Y, Wang Y, Su X T, Zhang L J. Chem. Eng. J. , 2019, 375: 121926 doi: 10.1016/j.cej.2019.121926
10. [10]
  Guo J Z, Gu Z Y, Zhao X X, Wang M Y, Yang X, Yang Y, Li W H, Wu X L. Adv. Energy Mater. , 2019, 9(38): 1902056 doi: 10.1002/aenm.201902056
11. [11]
  Cheng Y H, Van M J, Lataire P. International Review of Electrical Engineering (IREE), 2008, 3(1): 198-207
12. [12]
  Ma Y Y, Yuan W Y, Bai Y H, Wu H, Cheng L F. Carbon, 2019, 154: 292-300 doi: 10.1016/j.carbon.2019.07.095
13. [13]
  Chen Y J, Qu B H, Hu L L, Xu Z, Li Q H, Wang T H. Nanoscale, 2013, 5(20): 9812-9820 doi: 10.1039/c3nr02972g
14. [14]
  Jiao Z M, Wu Q Q, Cardon L, Qiu J. J. Nanosci. Nanotechnol. , 2020, 20(4): 2316-2323 doi: 10.1166/jnn.2020.17363
15. [15]
  Chen W Q, Wang J, Ma K Y, Li M, Guo S H, Liu F. Appl. Surf. Sci. , 2018, 451: 280-288 doi: 10.1016/j.apsusc.2018.04.254
16. [16]
  Meng Q F, Cai K F, Chen Y X, Chen L D. Nano Energy, 2017, 36: 268-285 doi: 10.1016/j.nanoen.2017.04.040
17. [17]
  Huang C H, Hu Y Z, Jiang S P, Chen H C. Electrochim. Acta, 2019, 325: 134936 doi: 10.1016/j.electacta.2019.134936
18. [18]
  Liu L L, Guan T, Fang L, Wu F, Lu Y, Luo H J. J. Alloys Compd. , 2018, 763: 926-934 doi: 10.1016/j.jallcom.2018.05.358
19. [19]
  Gao Zan, Wang J, Li Z S, Yang W L, Wang B, Hou M J. Chem. Mater. , 2011, 23(15): 3509-3516 doi: 10.1021/cm200975x
20. [20]
  Jagadale A D, Guan G Q, Li X M, Du X, Ma X L, Hao X G. J. Power Sources, 2016, 306: 526-534 doi: 10.1016/j.jpowsour.2015.12.097
21. [21]
  Feng Y Y, Li Y J, Yang W, Huang H B. J. Nanosci. Nanotechnol. , 2020, 20(2): 1260-1268 doi: 10.1166/jnn.2020.16983
22. [22]
  Memon J, Sun J H, Meng D L, Ouyang W Z, Memon M A, Huang Y. J. Mater. Chem. A, 2014, 2(14): 5060-5067 doi: 10.1039/c3ta14613h
23. [23]
  Li T, Li R, Luo H. J. Mater. Chem. A, 2016, 4(48): 18922-18930 doi: 10.1039/C6TA08032D
24. [24]
  Zardkhoshoui A M, Davarani S H. J. Alloys Compd. , 2018, 750: 515-522 doi: 10.1016/j.jallcom.2018.04.027
25. [25]
  Cao J M, Li L, Xi Y D, Li J Z, Pan X X, Chen D. Sustain. Energy Fuels, 2018, 2(6): 1350-1355 doi: 10.1039/C8SE00123E
26. [26]
  Hu H H, Qi J Q, Sui Y W, Zhou Y, Wei F, He Y. J. Mater. Sci. Mater. Electron. , 2017, 28(14): 10720-10729 doi: 10.1007/s10854-017-6848-z
27. [27]
  Yin Q, Li D P, Zhang J, Zhao Y J, Wang C, Han J B. Appl. Surf. Sci. , 2019, 487: 1-8 doi: 10.1016/j.apsusc.2019.04.253
28. [28]
  Li Y L, Shan L N, Sui Y W, Qi J Q, Wei F X, He Y Z. J. Mater. Sci. Mater. Electron. , 2019, 30(14): 13360-13371 doi: 10.1007/s10854-019-01703-4
29. [29]
  Nagaraju G, Raju G R, Ko Y H, Yu J S. Nanoscale, 2016, 8(2): 812-825 doi: 10.1039/C5NR05643H
30. [30]
  Liang X, Long G H, Fu C W, Pang M J, Xi Y L, Li J Z. Chem. Eng. J. , 2018, 345: 186-195 doi: 10.1016/j.cej.2018.03.104
31. [31]
  Hou B H, Wang Y Y, Ning Q L, Li W H, Xi X T, Yang Y, Liang H J, Feng X, Wu X L. Adv. Mater. , 2019, 31(40): 1903125 doi: 10.1002/adma.201903125
32. [32]
  Li H G, Wang S B, Feng M J. Chin. Chem. Lett. , 2019, 30(2): 529-532 doi: 10.1016/j.cclet.2018.06.024
33. [33]
  Sekhar S C, Nagaraju G, Yu J S. Nano Energy, 2017, 36: 58-67 doi: 10.1016/j.nanoen.2017.04.019
34. [34]
  Ke Q Q, Guan C, Zhang X, Zheng M R, Zhang Y W, Cai Y Q, Zhang H, Wang J. Adv. Mater. , 2017, 29(5): 1604164 doi: 10.1002/adma.201604164
35. [35]
  Kulkarni S B, Jagadale A D, Kumbhar V S, Bulakhe R N, Joshi S S. Int. J. Hydrogen Energy, 2013, 38(10): 4046-4053 doi: 10.1016/j.ijhydene.2013.01.047
36. [36]
  Zhang L J, Hui K N, Hui K S. Electrochim. Acta, 2015, 186: 522-529 doi: 10.1016/j.electacta.2015.11.024
37. [37]
  Chen H, Hu L F, Chen M, Yan Y, Wu L M. Adv. Funct. Mater. , 2014, 24(7): 934-942 doi: 10.1002/adfm.201301747
38. [38]
  Jia H A, Wang Z Y, Zheng X H, Lin J H, Liang H Y, Cai Y F, Qi J L, Cao J, Feng J C, Fei W D. Chem. Eng. J. , 2018, 351: 348-355 doi: 10.1016/j.cej.2018.06.113
39. [39]
  Shahrokhian S, Rahimi S, Mohammadi R. Int. J. Hydrogen Energy, 2018, 43(4): 2256-2267 doi: 10.1016/j.ijhydene.2017.12.019
40. [40]
  Zhao J W, Chen J L, Xu S, Shao M F, Zhang Q, Wei F, Ma J, Wei M, Evans D G, Duan X. Adv. Funct. Mater. , 2014, 24(20): 2938-2946 doi: 10.1002/adfm.201303638
41. [41]
  Dai C S, Chien P Y, Lin J Y, Chou S W, Wu W K, Li P H, Wu K Y, Lin T W. ACS Appl. Mater. Interfaces, 2013, 5(22): 12168-12174 doi: 10.1021/am404196s
42. [42]
  Tang Y F, Liu Y Y, Yu S X, Guo W C, Mu S C, Wang H C, Zhao Y F, Hou L, Fan Y Q, Gao F M. Electrochim. Acta, 2015, 161: 279-289 doi: 10.1016/j.electacta.2015.02.095
43. [43]
  Wang G R, Li Y B, Jin Z L. New J. Chem. , 2020, 44(18): 7528-7540 doi: 10.1039/D0NJ00611D
44. [44]
  Li S B, P J, Li F B, Zhang L, Chai D F, Zhang Z F, Xin J J. Dalton Trans. , 2020, 49(29): 10203-10211 doi: 10.1039/D0DT00251H
45. [45]
  Kulandaivalu S, Hussein M Z, Jaafar A M, Abdah M, Azman M, Sulaiman Y. RSC Adv. , 2019, 9(69): 40478-40486 doi: 10.1039/C9RA08134H
46. [46]
  Verma S, Gupta V, Khosla A, Kumar S, Arya S. Nanotechnology, 2020, 31(24): 245401 doi: 10.1088/1361-6528/ab7b07
47. [47]
  Liu L, Hu X, Zeng H Y, Yi M Y, Shen S G, Xu S, Cao Y, Du J Z. J. Mater. Sci. Technol. , 2019, 35(8): 1691-1699 doi: 10.1016/j.jmst.2019.04.003
1. [1]
  Shuo Zhang , Haitao Liao , Zhi-Qun Liu , Chong Yan , Jia-Qi Huang . Re-evaluating the nano-sized inorganic protective layer on Cu current collector for anode free lithium metal batteries. Chinese Chemical Letters, 2024, 35(7): 109284-. doi: 10.1016/j.cclet.2023.109284
2. [2]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
3. [3]
  Zhao Li , Huimin Yang , Wenjing Cheng , Lin Tian . Recent progress of in situ/operando characterization techniques for electrocatalytic energy conversion reaction. Chinese Chemical Letters, 2024, 35(9): 109237-. doi: 10.1016/j.cclet.2023.109237
4. [4]
  Ningxiang Wu , Huaping Zhao , Yong Lei . Nanomaterials with highly ordered nanostructures: Definition, influence and future challenge. Chinese Journal of Structural Chemistry, 2024, 43(11): 100392-100392. doi: 10.1016/j.cjsc.2024.100392
5. [5]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
6. [6]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
7. [7]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
8. [8]
  Zhirong Yang , Shan Wang , Ming Jiang , Gengchen Li , Long Li , Fangzhi Peng , Zhihui Shao . One stone three birds: Ni-catalyzed asymmetric allenylic substitution of allenic ethers, hydroalkylation of 1,3-enynes and double alkylation of enynyl ethers. Chinese Chemical Letters, 2024, 35(8): 109518-. doi: 10.1016/j.cclet.2024.109518
9. [9]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
10. [10]
  Yu Pang , Min Wang , Ning-Hua Yang , Min Xue , Yong Yang . One-pot synthesis of a giant twisted double-layer chiral macrocycle via [4 + 8] imine condensation and its X-ray structure. Chinese Chemical Letters, 2024, 35(10): 109575-. doi: 10.1016/j.cclet.2024.109575
11. [11]
  Long Jin , Jian Han , Dongmei Fang , Min Wang , Jian Liao . Pd-catalyzed asymmetric carbonyl alkynylation: Synthesis of axial chiral ynones. Chinese Chemical Letters, 2024, 35(6): 109212-. doi: 10.1016/j.cclet.2023.109212
12. [12]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
13. [13]
  Xinyu Huai , Jingxuan Liu , Xiang Wu . Cobalt-Doped NiMoO4 Nanosheet for High-performance Flexible Supercapacitor. Chinese Journal of Structural Chemistry, 2023, 42(10): 100158-100158. doi: 10.1016/j.cjsc.2023.100158
14. [14]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
15. [15]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
16. [16]
  Yunfei Shen , Long Chen . Gradient imprinted Zn metal anodes assist dendrites-free at high current density/capacity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100321-100321. doi: 10.1016/j.cjsc.2024.100321
17. [17]
  Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C₆F₅)₃/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
18. [18]
  Yu-Hang Miao , Zheng-Xu Zhang , Xu-Yi Huang , Yuan-Zhao Hua , Shi-Kun Jia , Xiao Xiao , Min-Can Wang , Li-Ping Xu , Guang-Jian Mei . Catalytic asymmetric dearomative azo-Diels–Alder reaction of 2-vinlyindoles. Chinese Chemical Letters, 2024, 35(4): 108830-. doi: 10.1016/j.cclet.2023.108830
19. [19]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
20. [20]
  Huipeng Zhao , Xiaoqiang Du . Polyoxometalates as the redox anolyte for efficient conversion of biomass to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(2): 100246-100246. doi: 10.1016/j.cjsc.2024.100246

Get Citation

PDF

XML

Metrics

PDF Downloads(16)
Abstract views(1233)
HTML views(358)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142