Citation: Xiao-yan LIU, Kai-xue WANG. Synthesis of SSZ-13 Zeolite with High Molar Ratio of SiO₂ to Al₂O₃ by Crystal Transformation Method Using Tetraethyl Ammonium Hydroxide as Template[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 728-734. doi: 10.11862/CJIC.2021.077 shu

Synthesis of SSZ-13 Zeolite with High Molar Ratio of SiO₂ to Al₂O₃ by Crystal Transformation Method Using Tetraethyl Ammonium Hydroxide as Template

Xiao-yan LIU ^1,, ,
Kai-xue WANG ^2,,

1.
Shanghai Key Laboratory of Molecular Imaging, Shanghai University of Medicine and Health Sciences, Shanghai 201318, China
2.
Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Xiao-yan LIU, liuxy@sumhs.edu.cn Kai-xue WANG, k.wang@sjtu.edu.cn
Received Date: 13 December 2020
Revised Date: 7 January 2021

Figures(8)

SSZ-13 zeolite with good crystallinity was prepared by using tetraethyl ammonium hydroxide as organic template and Y zeolite with low molar ratio of SiO₂ to Al₂O₃(n_SiO₂/n_Al₂O₃) as aluminum source. The effect of different compositions of pre-gels on the synthesis of SSZ-13 was investigated, and the crystallinity, morphology and n_SiO₂/n_Al₂O₃ in the process of hydrothermal reaction were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM) and inductively coupled plasm(ICP) to reveal the synthesis mechanism of SSZ-13. NH₃ selective catalytic reduction(NH₃-SCR) of NO_x shows that the SSZ-13 catalysts with Cu loading(mass fraction of 3%) had excellent catalytic activity, which provides the possibility for its wide application in industry.
- SSZ-13 zeolite,
- tetraethyl ammonium hydroxide,
- Y zeolite,
- NH₃-SCR
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Synthesis of SSZ-13 Zeolite with High Molar Ratio of SiO2 to Al2O3 by Crystal Transformation Method Using Tetraethyl Ammonium Hydroxide as Template

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通讯作者: 陈斌, bchen63@163.com

Synthesis of SSZ-13 Zeolite with High Molar Ratio of SiO₂ to Al₂O₃ by Crystal Transformation Method Using Tetraethyl Ammonium Hydroxide as Template