Citation: Lan ZHANG, Xi-gui WANG. Effect of TiO₂ on Luminescent Properties of ZnO/ZnS: Eu³⁺ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 601-607. doi: 10.11862/CJIC.2021.071 shu

Effect of TiO₂ on Luminescent Properties of ZnO/ZnS: Eu³⁺ Phosphor

Lan ZHANG ^{1, 2,,} ,
Xi-gui WANG ²

1.
Wulanchabu Medical College, Inner Mongolia 012000, China
2.
Inner Mongolia Normal University, College of Chemistry and Environment Science, Hohhot 010022, China

Corresponding author: Lan ZHANG, 15848421119@139.com
Received Date: 7 July 2020
Revised Date: 13 January 2021

Figures(10)

ZnO/ZnS/2TiO₂: Eu³⁺ phosphor was prepared by sol-gel-precipitation method. The structure, composition, morphology and luminescent properties were characterized by used X-ray diffraction(XRD), infrared spectroscopy(IR), transmission electron microscope(TEM) and fluorescence spectrum. The mechanism of luminescence was investigated. The results showed that phosphor changed into a stable structure when the temperature was above 600 ℃, and structure of the irregular shape. The phosphor mainly composed of ZnO, TiO₂ and ZnS. IR spectra show that the structure of Ti—O—Ti bridge oxygen bond network is conducive to pass energy among the Eu³⁺. Fluorescence spectra show that the addition of TiO₂ can remove the inhibition of Eu³⁺ spectral melody and improve the luminescence properties of phosphor. And the best luminescence performance was obtained in the phosphor prepared with n_Zn(NO₃)₂: n_TiO₂=1:2. The strongest emission peak was ⁵D₀→⁷F₂ electric dipole transition at 612 nm, and the optimum annealing temperature was 600 ℃.
- sol-gel-precipitation,
- Eu³⁺ doped ZnO/ZnS/2TiO₂,
- luminescent properties,
- luminescent mechanism
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Effect of TiO2 on Luminescent Properties of ZnO/ZnS: Eu3+ Phosphor

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通讯作者: 陈斌, bchen63@163.com

Effect of TiO₂ on Luminescent Properties of ZnO/ZnS: Eu³⁺ Phosphor