Citation: Yan-li WU, Xian-zhu XU, Qiang XIAO. Synthesis and Properties of Bifunctional Gd₂O₃: Eu@mSiO₂ Core-Shell Naonorods[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 638-644. doi: 10.11862/CJIC.2021.070 shu

Synthesis and Properties of Bifunctional Gd₂O₃: Eu@mSiO₂ Core-Shell Naonorods

1.
Jiangxi Key Laboratory ofOrganic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China
2.
College of Life Science, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: Qiang XIAO, xiaoqiang@tsinghua.org.cn
Received Date: 12 October 2020
Revised Date: 25 January 2021

Figures(13)

A novel Gd₂O₃: Eu@mSiO₂ core-shell bifunctional nanorods were prepared by hydrothermal and tetraethyl orthosilicate hydrolysis methods. The morphology and phase structure of the samples were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray powder diffraction(XRD), infrared spectroscopy(FTIR). The results shows that the core-shell nanomaterial was composed of Gd₂O₃: Eu nanorods(length ~400 nm, diameter ~100 nm) as the core and mesoporous SiO₂ as the shell, and had uniform size and good dispersion. And the core-shell structured nanorod obtained strong red luminescence, giving the function of cell imaging upon incubation with the NCI-H460 lung cancer cells. The drug loading capacity and releasing behavior of the as-prepared Gd₂O₃: Eu@mSiO₂ were studied by using ibuprofen(IBU) as model drug. The results show that the IBU loading capacity of the Gd₂O₃: Eu@mSiO₂ core-shell nanorods could reach 10.25%, and the core-shell nanorods had obvious slow-release effect. Furthermore, IBU-loaded Gd₂O₃: Eu@mSiO₂ core-shell nanorod still showed red luminescence of Eu³⁺ under UV irradiation, and the emission intensity of Eu³⁺ in the drug-carrier system varied with the released amount of IBU, so that the drug together with its release situation can be easily tracked and monitored by the change in luminescence intensity.
- nanostructures,
- mesoporous material,
- drug delivery,
- luminescence,
- hydrothermal synthesis
1. [1]
  Yu H L, Lv X F, Wu L L, Li B Q, Huang K C, Huang Y Q, Zhang Q Q, Mei C M, Ren X S, Zhou R, Luo H, Pang P F, Shan H. Nanoscale, 2020, 12: 17222-17237 doi: 10.1039/D0NR01236J
2. [2]
  Hu Y, Niemeyer C M. J. Mater. Chem. B, 2020, 8: 2250-2255 doi: 10.1039/C9TB02861G
3. [3]
  Luo M, Xu L L, Xia J L, Zhao H Y, Du Y P, Lei B. Mater. Lett. , 2020, 265: 127375 doi: 10.1016/j.matlet.2020.127375
4. [4]
  Yang P P, Gai S L, Lin J. Chem. Soc. Rev. , 2012, 41(9): 3679-3698 doi: 10.1039/c2cs15308d
5. [5]
  Manzano M, Vallet-Regí M. Adv. Funct. Mater. , 2020, 30: 1902634 doi: 10.1002/adfm.201902634
6. [6]
  Teng Y F, Jiang Y Q, Zhang Y N, Xu X Z, Lin K F. J. Porous Mater. , 2017, 24(1): 241-248 doi: 10.1007/s10934-016-0257-1
7. [7]
  GAO L, SUN J H, LI Y Z, Ren B. J. Inorg. Mater. , 2012, 27(4): 337-342
8. [8]
  Wan L, Jiao J, Cui Y, Guo J W, Han N, Di D H, Chang D, Wang P, Jiang T Y, Wang S L. Nanotechnology, 2016, 27(13): 135102 doi: 10.1088/0957-4484/27/13/135102
9. [9]
  Zhang Q, Liu F, Nguyen K T, Ma X, Wang X J, Xing B G, Zhao Y L. Adv. Funct. Mater. , 2012, 22(24): 5144-5156 doi: 10.1002/adfm.201201316
10. [10]
  Chang Y T, Liao P Y, Sheu H S, Tseng Y J, Cheng F Y, Yeh C S. Adv. Mater. , 2012, 24(25): 3309-3314 doi: 10.1002/adma.201200785
11. [11]
  Wu Y L, Xu X Z, Chen X, Yang R C, Xiao Q. RSC Adv. , 2016, 6(67): 62320-62326 doi: 10.1039/C6RA07444H
12. [12]
  Wu Y L, Xu X Z, You X L, Xiao Q. J. Rare Earths, 2020, 38(10): 1086-1092 doi: 10.1016/j.jre.2020.01.008
13. [13]
  GAO Y, CAO T Y, LI F Y. Chinese J. Inorg. Chem. , 2012, 28(10): 2043-2049
14. [14]
  WU Y L, XU X Z, WEN J, XIAO Q, LI Y X. Chinese J. Inorg. Chem. , 2015, 31(6): 1125-1130
15. [15]
  DENG J, LI H F, LIU Y, TANG N, SUN K, TAO K. Chinese J. Inorg. Chem. , 2019, 35(3): 393-402
16. [16]
  Xu X Z, Zhang X Z, Wu Y L. J. Nanopart. Res. , 2016, 18(11): 334 doi: 10.1007/s11051-016-3649-x
17. [17]
  Wu Y L, Tang Q, Li Y X, Li Y X. Nanotechnology, 2012, 23(20): 205103 doi: 10.1088/0957-4484/23/20/205103
18. [18]
  Zhou C H, Wu H, Huang C S, Wang M L, Jia N Q. Part. Part. Syst. Char. , 2014, 31(6): 675-684 doi: 10.1002/ppsc.201300342
19. [19]
  Yin J C, Li C R, Chen D Q, Yang J J, Liu H, Hu W Y, Shao Y Z. Phys. Chem. Chem. Phys. , 2017, 19(7): 5366-5376 doi: 10.1039/C6CP06712C
20. [20]
  Wu Z, Huang Z B, Yin G F, Cai B Y, Wang L, Gao F B. J. Mater. Chem. B, 2017, 5: 4863-4875 doi: 10.1039/C7TB00833C
21. [21]
  Wu Y L, Xu X Z, Li Q L, Yang R C, Ding H X, Xiao Q. J. Rare Earths, 2015, 33(5): 529-534 doi: 10.1016/S1002-0721(14)60452-X
22. [22]
  Peng L L, Liu B T, Han T. J. Rare Earths, 2013, 31: 650-654 doi: 10.1016/S1002-0721(12)60336-6
23. [23]
  Li G G, Liang Y J, Zhang M F, Yu D Y. CrystEngComm, 2014, 16: 6670-6679 doi: 10.1039/C4CE00482E
24. [24]
  Luo N Q, Yang C, Tian X M, Xiao J, Liu J, Chen F, Zhang D H, Xu D K, Zhang Y L, Yang G W, Chen D H, Li L. J. Mater. Chem. B, 2014, 2: 5891-5897 doi: 10.1039/C4TB00695J
25. [25]
  Majeed S, Shivashankar S A. J. Mater. Chem. B, 2014, 2: 5585-5593 doi: 10.1039/C4TB00763H
26. [26]
  Xu Z H, Li C X, Ma P A, Hou Z Y, Yang D M, Kang X J, Lin J. Nanoscale, 2011, 3(2): 661-667 doi: 10.1039/C0NR00695E
27. [27]
  Pavitra E, Raju, G S R, Nagaraju G P, Nagaraju G, Han Y K, Huh Y S, Yu J S. Chem. Comm. , 2018, 54: 747-750 doi: 10.1039/C7CC07975C
28. [28]
  Eurov D A, Kurdyukov D A, Kirilenko D A, Kirilenko J A, Kukushkina A V, Smirnov A N, Golubev V G. J. Nanopart. Res. , 2015, 17(2): 82 doi: 10.1007/s11051-015-2891-y
29. [29]
  He K W, Li J J, Shen Y X, Yu Y Q. J. Mater. Chem. B, 2019, 7: 6840-6854
30. [30]
  Yang G X, Lv R C, Gai S L, Dai Y L, He F, Yang P P. Inorg. Chem. , 2014, 53(20): 10917-10927 doi: 10.1021/ic501121t
31. [31]
  Song W Y, Di W H, Qin W P. Dalton. Trans. , 2016, 45: 7443-7449 doi: 10.1039/C5DT04908C
32. [32]
  Dai W B, Lei Y F, Ye S, Song E H, Chen Z, Zhang Q Y. J. Mater. Chem. B, 2016, 4: 1842-1852 doi: 10.1039/C5TB02619A
33. [33]
  Huang X L, Li L L, Liu T L, Hao N J, Liu H Y, Chen D, Tang F Q. ACS Nano, 2011, 5: 5390-5399 doi: 10.1021/nn200365a
34. [34]
  Chen Y, Chen H R, Zeng D P, Tian Y B, Chen F, Shi J L. ACS Nano, 2010, 4: 6001-6013 doi: 10.1021/nn1015117
35. [35]
  Tian J Y, Zhang F B, Han Y, Zhao X, Chen C Y, Zhang C M, Jia G. Appl. Surf. Sci. , 2019, 475: 264-272 doi: 10.1016/j.apsusc.2018.12.262
36. [36]
  Xu Z H, Cao Y, Li C X, Ma P A, Zhai X F, Huang S S, Kang X J, Shang M M. J. Mater. Chem. , 2011, 21: 3686-3694 doi: 10.1039/c0jm03333b
1. [1]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
2. [2]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
3. [3]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
4. [4]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
5. [5]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
6. [6]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
7. [7]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
8. [8]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
9. [9]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
10. [10]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
11. [11]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
12. [12]
  Zhilian Liu , Wengui Wang , Hongxiao Yang , Yu Cui , Shoufeng Wang . Ideological and Political Education Design for the Synthesis of Irinotecan Drug Intermediate 7-Ethyl Camptothecin. University Chemistry, 2024, 39(2): 89-93. doi: 10.3866/PKU.DXHX202306012
13. [13]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
14. [14]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
15. [15]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
16. [16]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
17. [17]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
18. [18]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
19. [19]
  Borong Yu , Huijiao Zhang , Xinyu Zhang , Xiaoying Li , Shuming Chen , Zhangang Han . The Blue Elf in the Dark: Gradient Science Popularization Experiments on Chemiluminescence. University Chemistry, 2024, 39(9): 295-303. doi: 10.12461/PKU.DXHX202403107
20. [20]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(873)
HTML views(242)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Properties of Bifunctional Gd2O3: Eu@mSiO2 Core-Shell Naonorods

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Properties of Bifunctional Gd₂O₃: Eu@mSiO₂ Core-Shell Naonorods