Citation: Lang-Lang YANG, Fan-Hui MENG, Peng ZHANG, Xiao-Tong LIANG, Zhong LI. Catalytic Performance for CO₂ Hydrogenation to Light Olefins over ZrCdO_x/SAPO-18 Bifunctional Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 448-456. doi: 10.11862/CJIC.2021.067 shu

Catalytic Performance for CO₂ Hydrogenation to Light Olefins over ZrCdO_x/SAPO-18 Bifunctional Catalyst

Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Chin

Corresponding author: Fan-Hui MENG, mengfanhui@tyut.edu.cn Zhong LI, lizhong@tyut.edu.cn
Received Date: 10 September 2020
Revised Date: 18 December 2020

Figures(7)

ZrCdO_x metal oxides with various Zr/Cd atomic ratios (n_Zr/n_Cd) were prepared by parallel coprecipitation method, the sheet-like SAPO-18 zeolites with molar ratio of SiO₂ to Al₂O₃ (n_SiO₂/n_Al₂O₃) of 0.1 and 0.01 were hydrothermally synthesized. The metal oxide and SAPO-18 were physically mixed to prepare ZrCdO_x/SAPO-18 bifunctional catalyst, and to study the catalytic performance for CO₂ hydrogenation to light olefins. Transmission electron microscopy (TEM), X-ray diffraction (XRD), N₂ adsorption-desorption, temperature-programmed desorption of CO₂ (CO₂TPD), temperature programmed desorption of ammonia (NH₃-TPD) and X-ray photoelectron spectroscopy (XPS) were applied to analyze the catalysts. Compared with the sole ZrO₂, the introduction of CdO decreased the BET (Brunauer Emmett Teller) surface area of ZrCdO_x. The Zr₈Cd₁ oxide prepared with n_Zr/n_Cd=8 exhibited the small amorphous particles, the strong synergetic effect between Zr and Cd led to the generation of more oxygen vacancies in ZrCdO_xoxide, which was beneficial to the adsorption and activation of CO₂. The effect of mass ratio of Zr₈Cd₁ oxide to SAPO-18 (n_SiO₂/n_Al₂O₃=0.1), and the reaction temperature, pressure and space velocity on catalytic performance were investigated, and the optimal reaction conditions were obtained. Moreover, it is also found that when the ratio of n_SiO₂/n_Al₂O₃ decreased from 0.1 to 0.01, the content of Brønsted acid reduced, the molar ratio of olefins to paraffin increased from 18.6 to 37.2; however, the content of by-product CO increased rapidly, and the space-time yield of light olefins decreased remarkably.
- carbon dioxide,
- hydrogenation,
- light olefins,
- ZrCdO_x metal oxides,
- zeolites
1. [1]
  Guo L S, Sun J, Ge Q J, Tsubaki N. J. Mater. Chem. A, 2018, 6(46): 23244-23262 doi: 10.1039/C8TA05377D
2. [2]
  Ye R P, Ding J, Gong W B, Argyle M D, Zhong Q, Wang Y J, Russell C K, Xu Z H, Russell A G, Li Q H, Fan M H, Yao Y G. Nat. Commun. , 2019, 10(1): 5698-5713 doi: 10.1038/s41467-019-13638-9
3. [3]
  Ma Z Q, Porosoff M D. ACS Catal. , 2019, 9(3): 2639-2656 doi: 10.1021/acscatal.8b05060
4. [4]
  Ronda-Lloret M, Rothenberg G, Shiju N R. ChemSusChem, 2019, 12(17): 3896-3914 doi: 10.1002/cssc.201900915
5. [5]
  Gao J J, Jia C, Liu B. Catal. Sci. Technol. , 2017, 7(23): 5602-5607 doi: 10.1039/C7CY01549F
6. [6]
  Sedighi M, Mohammadi M. J. CO₂ Util. , 2019, 35: 236-244
7. [7]
  Tan L, Zhang P P, Cui Y, Suzuki Y, Li H J, Guo Li S, Yang G H, Tsubaki N. Fuel Process. Technol. , 2019, 196: 106174-106179 doi: 10.1016/j.fuproc.2019.106174
8. [8]
  Hu S, Liu M, Ding F S, Song C S, Zhang G L, Guo X W. J. CO₂ Util. , 2016, 15: 89-95 doi: 10.1016/j.jcou.2016.02.009
9. [9]
  Numpilai T, Witoon T, Chanlek N, Limphirat W, Bonura G, Chareonpanich M, Limtrakul J. Appl. Catal. A, 2017, 547: 219-229 doi: 10.1016/j.apcata.2017.09.006
10. [10]
  Liu X L, Wang M H, Zhou C, Zhou W, Cheng K, Kang J C, Zhang Q H, Deng W P, Wang Y. Chem. Commun. , 2018, 54(2): 140-143 doi: 10.1039/C7CC08642C
11. [11]
  Li Z L, Wang J J, Qu Y Z, Liu H L, Tang C Z, Miao S, Feng Z C, An H Y, Li C. ACS Catal. , 2017, 7(12): 8544-8548 doi: 10.1021/acscatal.7b03251
12. [12]
  Liu X L, Wang M H, Yin H R, Hu J T, Cheng K, Kang J C, Zhang Q H, Wang Y. ACS Catal. , 2020, 10(15): 8303-8314 doi: 10.1021/acscatal.0c01579
13. [13]
  Gao P, Dang S H, Li S G, Bu X N, Liu Z Y, Qiu M H, Yang C G, Wang H, Zhong L S, Han Y, Liu Q, Wei W, Sun Y H. ACS Catal. , 2018, 8(1): 571-578 doi: 10.1021/acscatal.7b02649
14. [14]
  Dang S S, Li S G, Yang C G, Chen X Q, Li X P, Zhong L S, Gao P, Sun Y H. ChemSusChem, 2019, 12: 1-11 doi: 10.1002/cssc.201802948
15. [15]
  LIU R, ZHA F, YANG A M, CHANG Y. Chem. J. Chinese Universities, 2016, 37(5): 964-971
16. [16]
  Dang S S, Gao P, Liu Z Y, Chen X Q, Yang C G, Wang H, Zhong L S, Li S G, Sun Y H. J. Catal. , 2018, 364: 382-393 doi: 10.1016/j.jcat.2018.06.010
17. [17]
  Wang J J, Tang C Z, Li G N, Han Z, Li Z L, Liu H L, Cheng F, Li C. ACS Catal. , 2019, 9(11): 10253-10259 doi: 10.1021/acscatal.9b03449
18. [18]
  Jiao F, Li J J, Pan X L, Xiao J P, Li H B, Ma H, Wei M M, Pan Y, Zhou Z Y, Li M R, Miao S, Li J, Zhu Y F, Xiao D, He T, Yang J H, Qi F, Fu Q, Bao X H. Science, 2016, 351(6277): 1065-1068 doi: 10.1126/science.aaf1835
19. [19]
  Zhang P, Meng F H, Li X J, Yang L L, Ma P C, Li Z. Catal. Sci. Technol. , 2019, 9(20): 5577-5581 doi: 10.1039/C9CY01348B
20. [20]
  Sun Q M, Xie Z K, Yu J H. Natl. Sci. Rev. , 2018, 5(4): 542-558 doi: 10.1093/nsr/nwx103
21. [21]
  LI J F, FAN W B, DONG M, HE Y, QIN Z F, WANG J G. Chem. J. Chinese Universities, 2011, 32(3): 765-771
22. [22]
  CUI X Y, WANG J J, PAN M, NING W W, YAN L L, ZHENG J J, LI R F. Chinese J. Inorg. Chem. , 2018, 34(2): 300-308
23. [23]
  Wang P F, Zha F, Yao L, Chang Y. Appl. Clay Sci. , 2018, 163: 249256
24. [24]
  Huang Y X, Ma H F, Xu Z Q, Qian W X, Zhang H T, Ying W Y. Fuel, 2020, 273: 117771 doi: 10.1016/j.fuel.2020.117771
25. [25]
  GUO Y Y, LIANG G H, ZHANG Y T, HE Z G, LIANG Y N, LI N, LI X F, DOU T. Chinese J. Inorg. Chem. , 2019, 35(2): 185-193
26. [26]
  Zhong J W, Han J F, Wei Y X, Xu S T, Sun T T, Zeng S, Guo X W, Song C S, Liu Z M. Chinese J. Catal. , 2019, 40(4): 477-485 doi: 10.1016/S1872-2067(19)63281-X
27. [27]
  ZHAO D P, ZHAO Q S, ZHANG Y, SHI T, YAO H G, YU J Q. Chem. J. Chinese Universities, 2016, 37(2): 342-348
28. [28]
  Su J J, Zhou H B, Liu S, Wang C M, Jiao W Q, Wang Y D, Liu C, Ye Y C, Zhang L, Zhao Y, Liu H X, Wang D, Yang W M, Xie Z K, He M Y. Nat. Commun. , 2019, 10(1): 1297-1305 doi: 10.1038/s41467-019-09336-1
29. [29]
  Zhang G C, Fan G L, Yang L, Li F. Appl. Catal. A, 2020, 605: 117805117817
30. [30]
  Eskizeybek V, Avcı A, Chhowalla M. Cryst. Res. Technol. , 2011, 46(10): 1093-1100 doi: 10.1002/crat.201100221
31. [31]
  Barad C, Kimmel G, Hayun H, Shamir D, Shandalov M, Shekel G, Gelbstein Y. J. Mater. Sci. , 2018, 53(18): 12741-12749 doi: 10.1007/s10853-018-2556-1
32. [32]
  Zhao D P, Zhang Y, Peng Y H, Yu J Q. Catal. Lett. , 2016, 146(11): 2261-2267 doi: 10.1007/s10562-016-1854-y
33. [33]
  Bai B, Guan W S, Li Z Y, Li Puma G. Mater. Res. Bull. , 2011, 46(1): 26-31 doi: 10.1016/j.materresbull.2010.10.002
34. [34]
  Raveendra G, Li C M, Cheng Y, Meng F H, Li Z. New J. Chem. , 2018, 42(6): 4419-4431 doi: 10.1039/C7NJ04734G
35. [35]
  Cheng K, Gu B, Liu X L, Kang J C, Zhang Q H, Wang Y. Angew. Chem. Int. Ed. , 2016, 55(15): 4725-4728 doi: 10.1002/anie.201601208
36. [36]
  Chen J S, Thomas J M, Wright P A, Townsend R P. Catal. Lett. , 1994, 28(2): 241-248
37. [37]
  King P D C, Veal T D, Schleife A, Zúñiga-Pérez J, Martel B, Jefferson P. H, Fuchs F, Muñoz Sanjosé V, Bechstedt F, Mcconville C F. Phys. Rev. B, 2009, 79(20): 205205-205211 doi: 10.1103/PhysRevB.79.205205
38. [38]
  Liu X L, Zhou W, Yang Y D, Cheng K, Kang J C, Zhang L, Zhang G Q, Min X J, Zhang Q H, Wang Y. Chem. Sci. , 2018, 9(20): 4708-4718 doi: 10.1039/C8SC01597J
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Catalytic Performance for CO2 Hydrogenation to Light Olefins over ZrCdOx/SAPO-18 Bifunctional Catalyst

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Catalytic Performance for CO₂ Hydrogenation to Light Olefins over ZrCdO_x/SAPO-18 Bifunctional Catalyst