Citation: Lang-Lang YANG, Fan-Hui MENG, Peng ZHANG, Xiao-Tong LIANG, Zhong LI. Catalytic Performance for CO₂ Hydrogenation to Light Olefins over ZrCdO_x/SAPO-18 Bifunctional Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 448-456. doi: 10.11862/CJIC.2021.067 shu

Catalytic Performance for CO₂ Hydrogenation to Light Olefins over ZrCdO_x/SAPO-18 Bifunctional Catalyst

Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Chin

Corresponding author: Fan-Hui MENG, mengfanhui@tyut.edu.cn Zhong LI, lizhong@tyut.edu.cn
Received Date: 10 September 2020
Revised Date: 18 December 2020

Figures(7)

ZrCdO_x metal oxides with various Zr/Cd atomic ratios (n_Zr/n_Cd) were prepared by parallel coprecipitation method, the sheet-like SAPO-18 zeolites with molar ratio of SiO₂ to Al₂O₃ (n_SiO₂/n_Al₂O₃) of 0.1 and 0.01 were hydrothermally synthesized. The metal oxide and SAPO-18 were physically mixed to prepare ZrCdO_x/SAPO-18 bifunctional catalyst, and to study the catalytic performance for CO₂ hydrogenation to light olefins. Transmission electron microscopy (TEM), X-ray diffraction (XRD), N₂ adsorption-desorption, temperature-programmed desorption of CO₂ (CO₂TPD), temperature programmed desorption of ammonia (NH₃-TPD) and X-ray photoelectron spectroscopy (XPS) were applied to analyze the catalysts. Compared with the sole ZrO₂, the introduction of CdO decreased the BET (Brunauer Emmett Teller) surface area of ZrCdO_x. The Zr₈Cd₁ oxide prepared with n_Zr/n_Cd=8 exhibited the small amorphous particles, the strong synergetic effect between Zr and Cd led to the generation of more oxygen vacancies in ZrCdO_xoxide, which was beneficial to the adsorption and activation of CO₂. The effect of mass ratio of Zr₈Cd₁ oxide to SAPO-18 (n_SiO₂/n_Al₂O₃=0.1), and the reaction temperature, pressure and space velocity on catalytic performance were investigated, and the optimal reaction conditions were obtained. Moreover, it is also found that when the ratio of n_SiO₂/n_Al₂O₃ decreased from 0.1 to 0.01, the content of Brønsted acid reduced, the molar ratio of olefins to paraffin increased from 18.6 to 37.2; however, the content of by-product CO increased rapidly, and the space-time yield of light olefins decreased remarkably.
- carbon dioxide,
- hydrogenation,
- light olefins,
- ZrCdO_x metal oxides,
- zeolites
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Catalytic Performance for CO₂ Hydrogenation to Light Olefins over ZrCdO_x/SAPO-18 Bifunctional Catalyst