Citation: Jing-Yun MAO, Yi-Wei HUANG, Zhu-Quan HUANG, Xin-Ping LIU, Hun XUE, Li-Ren XIAO. Different Photocatalytic Performances for Tetracycline Hydrochloride Degradation of p-Block Metal Oxides Ga₂O₃ and Sb₂O₃[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 509-515. doi: 10.11862/CJIC.2021.063 shu

Different Photocatalytic Performances for Tetracycline Hydrochloride Degradation of p-Block Metal Oxides Ga₂O₃ and Sb₂O₃

1.
College of Environmental Science and Engineering, Fujian Normal University, Fuzhou 350007, China
2.
College of Life and Science, Fujian Normal University, Fuzhou 350007, China
3.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: Hun XUE, xuehun@fjnu.edu.cn Li-Ren XIAO, xlr1966@126.com
Received Date: 29 September 2020
Revised Date: 28 December 2020

Figures(11)

The UV light photocatalytic performances of p-block metal oxides Ga₂O₃ and Sb₂O₃ synthesized by a precipitation method for the degradation of tetracycline hydrochloride were explored. The effects of synthesis conditions on the photocatalytic activity were discussed. The Ga₂O₃-900 and Sb₂O₃-500 samples prepared under optimal conditions exhibited a remarkable photocatalytic activity difference, which were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, N₂ adsorption-desorption tests, fluorescence spectrum, Raman spectrum, electrochemical analysis and trapping experiment of active species. The photocatalytic degradation mechanisms of tetracycline hydrochloride over the photocatalysts were proposed and the essential factors influencing the difference of photocatalytic performance were revealed. The results show that the different photocatalytic activities observed for Ga₂O₃ and Sb₂O₃ can be attributed to their different electronic and crystal structures, the amount of hydroxyl group in the surface and the photocatalytic degradation mechanisms.
- p-block metal,
- Ga₂O₃,
- Sb₂O₃,
- photocatalysis,
- tetracycline hydrochloride
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沈阳化工大学材料科学与工程学院沈阳 110142

Different Photocatalytic Performances for Tetracycline Hydrochloride Degradation of p-Block Metal Oxides Ga2O3 and Sb2O3

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通讯作者: 陈斌, bchen63@163.com

Different Photocatalytic Performances for Tetracycline Hydrochloride Degradation of p-Block Metal Oxides Ga₂O₃ and Sb₂O₃