Citation: Zi-hui ZHU, Huai-yuan ZHAO, Zhao-yin HOU, Ping CHEN. Bifunctional Catalysts Ni_x/Mg_yAl₂O_y+3 for Alkylation of Butanone[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 675-683. doi: 10.11862/CJIC.2021.062 shu

Bifunctional Catalysts Ni_x/Mg_yAl₂O_y+3 for Alkylation of Butanone

Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Corresponding author: Zhao-yin HOU, zyhou@zju.edu.cn Ping CHEN, c224@zju.edu.cn
Received Date: 27 October 2020
Revised Date: 10 January 2021

Figures(10)

A series of Ni_x/Mg_yAl₂O_y+3(x=0.2 or 1, 5≤y≤11.8) bifunctional catalysts were prepared by calcination and hydrogen reduction of Ni_x/zMg_y/zAl_2/z(OH)₂(CO₃)_1/z(z=x+y+2, x=0.2 or 1, 5≤y≤11.8) hydrotalcite precursors. The structure and morphology of these catalysts were characterized via X-ray diffraction(XRD), transmission electron microscope(TEM), temperature program reduction(TPR), temperature program desorption(TPD) and other technologies.It was found that Ni/Mg₉Al₂O₁₂ exhibited excellent activity for the alkylation of butanone(MEK) with methanol. The conversion of butanone reached 61.6%, with the 45.0% and 17.7% selectivity of 3-pentanone(DEK) and 3-methyl-2-butanone(MIPK) under atmospheric pressure, 280 ℃, and liquid hourly space velocity(LHSV) of 6.0 h^-1. The characterization results show that the appropriate active metal Ni and MgO contents in the catalyst play an important role on the selectivity of DEK and MIPK. The synergistic effect between Ni and the surface alkalinity may be the main factor affecting the activity and selectivity of the catalyst.
- layered compounds,
- alkylation,
- hydrotalcite,
- butanone,
- 3-methyl-2-butanone,
- 3-pentanone
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Bifunctional Catalysts Ni_x/Mg_yAl₂O_y+3 for Alkylation of Butanone