Citation: Lian-Yang ZHANG, Jun-Jie WU, Yue MENG, Sheng-Jie XIA. Direct Z-scheme Heterojunction CeO₂@NiAl-LDHs for Photodegradation of Rhodamine B and Photocatalytic Hydrogen Evolution: Performance and Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 316-326. doi: 10.11862/CJIC.2021.053 shu

Direct Z-scheme Heterojunction CeO₂@NiAl-LDHs for Photodegradation of Rhodamine B and Photocatalytic Hydrogen Evolution: Performance and Mechanism

Lian-Yang ZHANG ¹ ,
Jun-Jie WU ^{2, 3} ,
Yue MENG ^4,, ,
Sheng-Jie XIA ^5,,

1.
Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, College of Textiles and Garment, Shaoxing University, Shaoxing, Zhejiang 312000, China
2.
Hangzhou Binjiang Real Estate Group Co., Ltd, Hangzhou 310018, China
3.
Hangzhou Xinda Aoti Real Estate Co., Ltd, Hangzhou 310016, China
4.
School of Life Sciences, Huzhou University, Huzhou, Zhejiang 313000, China
5.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Yue MENG, mengyue911@126.com Sheng-Jie XIA, xiasj@zjut.edu.cn
Received Date: 11 October 2020
Revised Date: 24 December 2020

Figures(8)

Herein, a direct Z-scheme heterojunction CeO₂@NiAl-LDHs (LDHs=layered double hydroxides) with core-shell structure was constructed. It shows high oxidative degradation of rhodamine B (36.91 mg·g^-1·h^-1) and hydrogen production by photoreduction (14.08 mmol·g^-1·h^-1). Density functional theory (DFT) calculation shows that there was a built-in electric field in the heterojunction, which promotes the electron transfer from LDHs to CeO₂. Surface photovoltage spectroscopy (SPV) and transient photovoltage spectra (TPV) confirmed that the presence of heterojunction accelerated the number of electron transfer, and the recombination of electron and hole was obviously inhibited, so as to participate in oxidation and reduction more. Thus, it makes CeO₂@NiAl LDHs heterojunction photocatalyst have high photocatalytic activity for photodegradation of rhodamine B and hydrogen production from water.
- layered double hydroxides,
- photocatalysis,
- heterojunction,
- build-in electronic field,
- rhodamine B,
- hydrogen evolution
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Direct Z-scheme Heterojunction CeO2@NiAl-LDHs for Photodegradation of Rhodamine B and Photocatalytic Hydrogen Evolution: Performance and Mechanism

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Direct Z-scheme Heterojunction CeO₂@NiAl-LDHs for Photodegradation of Rhodamine B and Photocatalytic Hydrogen Evolution: Performance and Mechanism