Citation: Yu CHEN, Zhao-Dong WANG. Synthesis and Magnetic Characterization of Mononuclear Co(Ⅱ) Complex Based on Pyrazine-Containing Hydrazone Schiff Base Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 525-530. doi: 10.11862/CJIC.2021.050 shu

Synthesis and Magnetic Characterization of Mononuclear Co(Ⅱ) Complex Based on Pyrazine-Containing Hydrazone Schiff Base Ligand

Yu CHEN ,
Zhao-Dong WANG ^,

College of Chemistry and Environmental Engineering, Chongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and Sciences, Chongqing 402160, China

Corresponding author: Zhao-Dong WANG, ouwzdong@qq.com
Received Date: 10 August 2020
Revised Date: 16 November 2020

Figures(6)

A mononuclear Co(Ⅱ)complex (NHEt₃)[Co(HL)₂] ·3H₂O (1) based on a pyrazine-containing hydrazone Schiff base ligand H₂L was synthesized and characterized by IR, thermogravimetric analysis, X-ray single diffraction and magnetic susceptibility measurements. X-ray single crystal analysis reveals that it consists of a Co(Ⅱ)ion, two deprotonated HL- ligands, three uncoordinated H₂O and a protonated triethylamine. The central Co(Ⅱ)ion is six- coordinated with N₂O₄ donor sets to form distorted octahedral geometry. Magnetic susceptibility measurement of both complex 1 and the dehydrated 1 showed a gradual high spin to low spin transition, and the differences can be attributed to the hydrogen bonding effects on the magnetic properties. CCDC: 1973542, 1 (298 K); 20274281, 1 (100 K).
- hydrazone ligand,
- single crystal structure,
- spin transition,
- mononuclear Co complex
1. [1]
  Halcrow M A. Chem. Soc. Rev. , 2011, 40: 4119-4142 doi: 10.1039/c1cs15046d
2. [2]
  Sato O. Nat. Chem. , 2016, 8: 644-656 doi: 10.1038/nchem.2547
3. [3]
  Feltham H L C, Barltrop A S, Brooker S. Coord. Chem. Rev. , 2017, 344: 26-53 doi: 10.1016/j.ccr.2016.10.006
4. [4]
  Hogue R W, Singh S, Brooker S. Chem. Soc. Rev. , 2018, 47: 7303-7338 doi: 10.1039/C7CS00835J
5. [5]
  Harding D J, Harding P, Phonsri W. Coord. Chem. Rev. , 2016, 313: 38-61 doi: 10.1016/j.ccr.2016.01.006
6. [6]
  WANG K J, LI H Q, SUN Y C, WANG X Y. Chinese J. Inorg. Chem. , 2020, 35(6): 1143-1148
7. [7]
  Hayami S, Komatsu Y, Shimizu T, Kamihata H, Lee Y H. Coord. Chem. Rev. , 2011, 255: 1981-1990 doi: 10.1016/j.ccr.2011.05.016
8. [8]
  Kumar K S, Bayeh Y, Gebretsadik T, Elemo F, Gebrezgiabher M, Thomas M, Ruben M. Dalton Trans. , 2019, 48: 15321-15337 doi: 10.1039/C9DT02085C
9. [9]
  Shao D, Shi L, Shen F X, Wei X Q, Sato O, Wang X Y. Inorg. Chem. , 2019, 58(17): 11589-11598 doi: 10.1021/acs.inorgchem.9b01436
10. [10]
  Cowan M G, Olgurin J, Narayanaswamy S, Tallon J L, Brooker S. J. Am. Chem. Soc. , 2012, 134(6): 2892-2894 doi: 10.1021/ja208429u
11. [11]
  Olguín J. Coord. Chem. Rev. , 2020, 407: 213148 doi: 10.1016/j.ccr.2019.213148
12. [12]
  Su X, Aprahamian I. Chem. Soc. Rev. , 2014, 43: 1963-1981 doi: 10.1039/c3cs60385g
13. [13]
  Tian H Q, Zhao L, Guo Y N, Guo Y, Tang J K, Liu Z L. Chem. Commun. , 2012, 48: 708-710 doi: 10.1039/C1CC15814G
14. [14]
  Tian H Q, Wang B L, Lu J, Liu H T, Su J H, Li D C, Dou J M. Chem. Commun. , 2018, 54: 12105-12108 doi: 10.1039/C8CC06699J
15. [15]
  Tian H Q, Bao S S, Zheng L M. Chem. Commun. , 2016, 52: 2314-2317 doi: 10.1039/C5CC08740F
16. [16]
  Tian H Q, Zhao L, Tang J K. Cryst. Growth Des. , 2018, 18(2): 1173-1181 doi: 10.1021/acs.cgd.7b01612
17. [17]
  Tian H Q, Zhao L, Lin H F, Tang J K, Li G S. Chem. -Eur. J. , 2013, 19(39): 13235-13241 doi: 10.1002/chem.201301313
18. [18]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71: 3-8
19. [19]
  Dolomanov O V, Bourhis L J, Gildea R J, Howard J A K, Puschamann H. J. Appl. Crystallogr. , 2009, 42: 339-341 doi: 10.1107/S0021889808042726
20. [20]
  Chandrasekhar V, Dey A, Mota A J, Colacio E. Inorg. Chem. , 2013, 52(8): 4554-4561 doi: 10.1021/ic400073y
21. [21]
  Hayami S, Kato K, Komatsu Y, Fuyuhiro A, Ohba M. Dalton Trans. , 2011, 40: 2167-2169 doi: 10.1039/C0DT01052A
22. [22]
  Hayami S, Nakaya M, Ohmagari H, Alao A S, Nakamura M, Ohtani R, Yamaguchi R, Kuroda-Sowa T, Clegg J K. Dalton Trans. , 2015, 44: 9345-9348 doi: 10.1039/C4DT03743J
23. [23]
  Weselski M, Ksiażek M, Mess P, Kusz J, Bronisz R. Chem. Commun. , 2019, 55: 7033-7036 doi: 10.1039/C9CC02755F
24. [24]
  Shao D, Shi L, Yin L, Wang B L, Wang Z X, Zhang Y Q, Wang X Y. Chem. Sci. , 2018, 9: 7986-7991 doi: 10.1039/C8SC02774A
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
3. [3]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
4. [4]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
5. [5]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
6. [6]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
7. [7]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
8. [8]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
9. [9]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211
10. [10]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
11. [11]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
12. [12]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
13. [13]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
14. [14]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
15. [15]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
16. [16]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
17. [17]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
18. [18]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
19. [19]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
20. [20]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(501)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142