Citation: Yan-Ping DONG, Guang-Ming LI. Syntheses, Structures and Magnetic Properties of β-diketone Dy(Ⅲ) Complexes Tuned by Bond Length and Electronic Effect[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 213-220. doi: 10.11862/CJIC.2021.041 shu

Syntheses, Structures and Magnetic Properties of β-diketone Dy(Ⅲ) Complexes Tuned by Bond Length and Electronic Effect

Yan-Ping DONG ^{1, 2} ,
Guang-Ming LI ^1,,

1.
Key Laboratory of Functional Inorganic Material Chemistry(MOE), Heilongjiang University, Harbin 150080, China
2.
Department of Food and Pharmaceutical Engineering, Suihua University, Suihua, Heilongjiang 152061, China

Corresponding author: Guang-Ming LI, gmli_2000@163.com
Received Date: 20 June 2020
Revised Date: 1 November 2020

Figures(11)

A series of 1-(1-ethyl-1H-indol-3-yl)-4, 4, 4-trifluorobutane-1, 3-dione (EIFD) dysprosium complexes, namely[Dy(EIFD)₃(EM)]·CH₂Cl₂ (1), [Dy(EIFD)₃(EDM)]·CH₂Cl₂ (2) and[Dy(EIFD)₃(TEG)] (3) (EM=CH₃OCH₂CH₂OH, EDM=CH₃OCH₂CH₂OCH₃, TEG=HOCH₂CH₂OCH₂CH₂OCH₂CH₂OH), have been isolated by reactions of EIFD, DyCl₃·6H₂O and corresponding oxygen-containing auxiliary ligands, respectively. X-ray crystallographic analysis reveals that complexes 1~3 are all eight coordinated mononuclear structures. The coordination geometry for Dy(Ⅲ) ion in complexes 1 and 3 are suggested closer to the biaugmented trigonal prismatic (8-BTP, C_2v), in contrast, it is closer to the triangular dodecahedron (8-TDH, D_2d) for complex 2. Magnetic studies indicate that all complexes 1~3 exhibit slowed magnetic relaxation with anisotropy energy barriers of 95.1 K for 1, 40.5 K for 2 as well as 53.8 and 13.4 K for 3, respectively. Complexes 1 and 3 showed butterfly-loop. In view of the β-diketone ligand of EIFD, Dy (Ⅲ) complexes with oxygen containing auxiliary ligands displayed higher energy barriers than those of complexes with nitrogen containing auxiliary ligands. The Dy-O bond length and electronic effect of oxygen containing auxiliary ligands in the complexes have been investigated in terms of their anisotropy energy barriers. CCDC: 1893554, 1; 1893555, 2; 1893556, 3.
- β-diketone,
- Dy(Ⅲ) complex,
- oxygen-containing auxiliary ligand,
- electronic effect,
- bond length
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