Citation: Xiao-Li CHEN, Lu SHANG, Meng-Ping HUANG, Yu-Qing TONG, Jia-nan ZHANG, Wan-Nian XUE. Two Complexes Based on Terpyridine/Benzotricarboxylic Acid Ligands: Synthesis, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 340-350. doi: 10.11862/CJIC.2021.037 shu

Two Complexes Based on Terpyridine/Benzotricarboxylic Acid Ligands: Synthesis, Structures and Properties

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yanan University, Yan′an, Shaanxi 716000, China

Corresponding author: Xiao-Li CHEN, chenxiaoli003@163.com
Received Date: 20 May 2020
Revised Date: 2 November 2020

Figures(11)

A coordination polymer (CP) and a complex based on H₃tbtd/H₃bbta and bpy ligands, namely {[Co₃(tbtd)₂ (bpy)₂(H₂O)]·5H₂O}_n (1) and[Cd₂(Hbbta)(bpy)₃(C₂O₄)(H₂O)] (2) (H₃tbtd=4-(2, 4, 6-tricarboxylphenyl)-2, 2', 6', 2″-terpyridine, H₃bbta=1-fluoro-2, 4, 6-phenyltriacid, bpy=2, 2'-dipyridine), have been hydrothermal synthesized and structurally characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analyses. 1 shows 2D network structure, which is linked into 3D supramolecular network through intermolecular hydrogen bonding interactions. 2 is binuclear structure, which is linked by π…π stack interactions and hydrogen bonding interactions to form 2D supramolecular network. CP 1 exhibited photocatalytic activities for degradation of methyl orange (MO) under UV light irradiation and showed good stabilities toward UV-light photocatalysis. In addition, luminescence property of 2 and thermal stabilities of 1~2 were also studied.CCDC: 1986403, 1, 2004223, 2.
- 4-(2, 4, 6-tricarboxylphenyl)-2, 2', 6', 2″-terpyridine,
- 1-fluoro-2, 4, 6-phenyltriacid,
- crystal structure,
- luminescence,
- photocatalysis
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