Citation: Yu CHEN, Yang-Fan WEI, Jia-Xin LI, Wen-Qi LUO, Chuan-Ming JIN. Crystal Structure and Properties of Metal-Organic Macrocycles and Metal-Organic Gels Based on Rigid Bis-imidazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 235-242. doi: 10.11862/CJIC.2021.035 shu

Crystal Structure and Properties of Metal-Organic Macrocycles and Metal-Organic Gels Based on Rigid Bis-imidazole Ligand

Hubei Collaborative Innovation Center for Rare Metal Chemistry, Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Institute for Advanced Materials, Hubei Normal University, Huangshi, Hubei 435002, China

Corresponding author: Chuan-Ming JIN, cmjin@hbnu.edu.cn
Received Date: 26 July 2020
Revised Date: 1 November 2020

Figures(9)

Complexes[Ag(4-PIM)]ClO₄ (1) and[Zn(IPI)]Cl₂·H₂O (2) were synthesized by the reaction of ligand 2-(4pyridinyl)-imidazole (4-PIM) and 2-(4-(1-imidazolylphenyl))-imidazole (IPI) with AgClO₄ and ZnCl₂, respectively. Xray crystallography analysis reveals that complexes 1 and 2 have metal-organic macrocyclic structure of M₄L₄ and M₂L₂ type, respectively. And there are stronger intermolecular forces, π-π stacking effect and hydrogen-bonding interactions in the crystal structures of complexes. Metal-organic gels were formed by using rigid ligand IPI to react with AgNO₃ and Zn(NO₃)₂ in methanol, ethanol, dimethyl sulfoxide, ethylene glycol, tetrahydrofuran and acetonitrile, respectively. Supramolecular metal-organic gels were also self-assemblied through ligand IPI reacting with AgNO₃, AgClO₄, AgBF₄, AgPF₆, AgOSO₂CF₃, Zn(NO₃)₂, Zn(BF₄)₂, Zn(ClO₄)² and Co(NO₃)₂ in ethanol solvent, respectively. The hydrogen-bonding interactions between solvent molecules and N-H in the imidazole rings of ligand IPI may be the key factor to form gels. Scanning electron microscopy (SEM) images showed that metal-organic supramolecular gels based on silver salts or zinic salts had fluffy cotton-like and loose bread-like structure, respectively. CCDC: 2017307, 1; 2017308, 2.
- metal-organic gels,
- metal-organic macrocycles,
- rigid ligand,
- self-assembly
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