Citation: Zi-Yu ZHANG, Liu-Lei QIN, Yang LIU, Hui LI, Hong-Zhi HU, Zun-Qi LIU. Synthesis, Reversible Phase Transition and Dielectric Properties of Molybdenum-Based Pyridines Organic-Inorganic Hybrid Crystalline Materials[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 305-315. doi: 10.11862/CJIC.2021.034 shu

Synthesis, Reversible Phase Transition and Dielectric Properties of Molybdenum-Based Pyridines Organic-Inorganic Hybrid Crystalline Materials

Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China

Corresponding author: Yang LIU, liuyangxj85@163.com Zun-Qi LIU, zunqi85@163.com
Received Date: 8 September 2020
Revised Date: 28 October 2020

Figures(13)

The organic - inorganic hybrid crystalline material (C₇H₁₁N₂)₄[MoOBr₄(H₂O)]₂Br₂ (1) was synthesized by solvent evaporation method in the mixed solution of methanol, ethanol, water and hydrobromic acid using 4-dimethylaminopyridine and ammonium molybdate as raw materials. The crystal structure, thermal and electrical properties were characterized by infrared spectroscopy, single crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and dielectric measurements and differential thermal analysis. Single crystal X-ray diffraction displayed one dimensional chain and multi dimensional hydrogen bonding network structure through anions and cations forming π-π stacking in space. When the temperature changed, the structural cavity deformation with molybdenum complex ion[MoOBr₄(H₂O)]^- as the vertex caused the hydrogen-bonding dihedral angles of tetramer[MoOBr₄(H₂O)]₂Br₂ to occur obvious folding oscillation, which results in the distinct thermal energy with structural phase transition and reversible dielectric anomaly observed at around 238 K. CCDC: 2024338, 1-LT; 2024339, 1-RT.
- hydrogen bond,
- organic-inorganic hybrid,
- reversible phase transition,
- dielectric properties
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